Phase Transformation Behavior of C60 Fullerene under Atmospheric Pressure
Wen-Hwa Chen1,2, Chun-Hung Wu1, Hsien-Chie Cheng3,4
Structural Longevity, Vol.4, No.3, pp. 137-144, 2010, DOI:10.3970/sl.2010.004.137
Abstract The phase transformation behaviors of C60 fullerene under atmospheric
pressure are reported using a proposed thermostat molecular dynamics method designed for a solid system. We find that C60 fullerene directly undergoes a solidvapor phase transformation, instead of a solid-liquid phase transition, at a specific
threshold temperature. It reveals that C60 fullerene will sublimate when heated
rather than melt under atmospheric pressure. This phenomenon is coincident with
that of graphite at pressures below 10MPa. The sublimation point of C60 fullerene,
rather than the melting, is about 4350±20K, locating in the published range of
about 4000-4500K for graphite at More >