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  • Open Access

    ARTICLE

    Fabrication of UV–Curing Linalool–Polysiloxane Hybrid Films with High Refractive Index and Transparency

    Wenqing Xiao1,#, Lewen Tan1,2,#, Xunjun Chen1,*, Qiaoguang Li1,*, Yunqing Ruan1

    Journal of Renewable Materials, Vol.12, No.3, pp. 569-583, 2024, DOI:10.32604/jrm.2023.046662

    Abstract

    In this article, a series of high refractive indices (1.50–1.53) thiol phenyl polysiloxane (TPS) were synthesized via hydrolytic sol–gel reaction. The Fourier transform infrared spectra (FT–IR) and nuclear magnetic resonance spectra (NMR) results showed that TPS conformed to the predicted structures. Natural terpene linalool was exploited as photocrosslinker to fabricate UV–curing linalool–polysiloxane hybrid films (LPH) with TPS via photoinitiated thiol–ene reaction. LPH rapidly cured under UV irradiation at the intensity of 80 mW/cm2 in 30 s, exhibiting good UV–curing properties. The optical transmittance of LPH in the wavelength of 300–800 nm was over 90%, exhibiting good optical transparency. The water… More >

  • Open Access

    ARTICLE

    Biocomposites of Polylactic Acid Reinforced by DL-Lactic Acid-Grafted Microfibrillated Cellulose

    Chaodong Liu, Yutong Yang, Boyu Cui, Weihong Wang*

    Journal of Renewable Materials, Vol.10, No.11, pp. 2961-2972, 2022, DOI:10.32604/jrm.2022.019761

    Abstract Microfibrillated cellulose (MFC) is often added to polylactic acid (PLA) matrixes as a reinforcing filler to obtain fully-biodegradable composites with improved mechanical properties. However, the incompatibility between MFC and the PLA matrix limits the mechanical performance of MFC-reinforced PLA composites. In this paper, DL-lactic acid-grafted-MFC (MFC-g-DL) was used to improve the compatibility with PLA. Reinforced composites were prepared by melt extrusion and hot-cold pressing. The tensile strength of the PLA/MFC-g-DL composite increased by 22.1% compared with that of PLA after adding 1% MFC-g-DL. Scanning electron microscopy (SEM), differential scanning calorimetry (DSC), and dynamic thermomechanical analysis (DMA) were used to explore… More > Graphic Abstract

    Biocomposites of Polylactic Acid Reinforced by DL-Lactic Acid-Grafted Microfibrillated Cellulose

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