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  • Open Access

    ARTICLE

    Influence of Sulfonated Chitosan on Conductivity of Sulfonated Polyether Ether Ketone (SPEEK) at Room Temperature

    Aina Aqilah Mohd Rizal1, Oskar Hasdinor Hassan2, Nor Kartini Jaafar1,2, Masnawi Mustaffa1, Mohd Tajudin Mohd Ali1,*, Ajis Lepit3, Nazli Ahmad Aini1,2,*

    Energy Engineering, Vol.123, No.1, 2026, DOI:10.32604/ee.2025.071726 - 27 December 2025

    Abstract Proton exchange membrane (PEM) is an integral component in fuel cells which enables proton transport for efficient energy conversion. Sulfonated Polyether Ether Ketone (SPEEK) has emerged as a cost-effective option with non-fluorinated aromatic backbones for Proton Exchange Membrane Fuel Cell (PEMFC) applications, even though it exhibits lower proton conductivity compared to Nafion. This work aims to study the influence of Sulfonated Chitosan (SCS) concentrations on proton conductivity of SPEEK-based PEM at room temperature. SPEEK was synthesized using a sulfonation process with concentrated sulfuric acid at room temperature. SCS was synthesized via reflux of CS and… More > Graphic Abstract

    Influence of Sulfonated Chitosan on Conductivity of Sulfonated Polyether Ether Ketone (SPEEK) at Room Temperature

  • Open Access

    ARTICLE

    Atomistic Simulation Study on Spall Failure and Damage Evolution in Single-Crystalline Ta at Elevated Temperatures

    Yuntian Wang1,2, Taohua Liang1,2, Yuan Zhou1,2, Weimei Shi1,2, Lijuan Huang1,2, Yuzhu Guo3,*

    CMC-Computers, Materials & Continua, Vol.86, No.2, pp. 1-26, 2026, DOI:10.32604/cmc.2025.071624 - 09 December 2025

    Abstract This investigation utilizes non-equilibrium molecular dynamics (NEMD) simulations to explore shock-induced spallation in single-crystal tantalum across shock velocities of 0.75–4 km/s and initial temperatures from 300 to 2000 K. Two spallation modes emerge: classical spallation for shock velocity below 1.5 km/s, with solid-state reversible Body-Centered Cubic (BCC) to Face-Centered Cubic (FCC) or Hexagonal Close-Packed (HCP) phase transformations and discrete void nucleation-coalescence; micro-spallation for shock velocity above 3.0 km/s, featuring complete shock-induced melting and fragmentation, with a transitional regime (2.0–2.5 km/s) of partial melting. Spall strength decreases monotonically with temperature due to thermal softening. Elevated temperatures More >

  • Open Access

    ARTICLE

    Time-Resolved Experimental Analysis of Granite–Mortar Interface Permeability under High-Temperature Conditions

    Wei Chen*, Yuanteng Zhao, Yue Liang

    FDMP-Fluid Dynamics & Materials Processing, Vol.21, No.12, pp. 3033-3053, 2025, DOI:10.32604/fdmp.2025.073778 - 31 December 2025

    Abstract In deep underground engineering, geological disposal of nuclear waste, and geothermal development, the granite–mortar interface represents a critical weak zone that strongly influences sealing performance under high-temperature conditions. While previous studies have primarily focused on single materials, the dynamic evolution of interface permeability under thermal loading remains insufficiently understood. In this study, time-resolved gas permeability measurements under thermal cycling (20°C → 150°C → 20°C) were conducted, complemented by multi-scale microstructural characterization, to investigate the nonlinear evolution of permeability. Experimental results indicate that interface permeability at room temperature is approximately one order of magnitude higher than… More >

  • Open Access

    ARTICLE

    Analytical Modeling of Internal Thermal Mass: Transient Heat Conduction in a Sphere under Constant, Exponential, and Periodic Ambient Temperatures

    Liangjian Lei1,2, Yihang Lu1,2,*

    Frontiers in Heat and Mass Transfer, Vol.23, No.6, pp. 2109-2126, 2025, DOI:10.32604/fhmt.2025.072643 - 31 December 2025

    Abstract Internal thermal mass, such as furniture and partitions, plays a crucial role in enhancing building energy efficiency and indoor thermal comfort by passively regulating temperature fluctuations. However, the irregular geometry of these elements poses a significant challenge for accurate modeling in building energy simulations. This study addresses this gap by developing a rigorous analytical model that idealizes internal thermal mass as a sphere, thereby capturing multi-directional heat conduction effects that are neglected in simpler one-dimensional slab models. The transient heat conduction within the sphere is solved analytically using Duhamel’s theorem for three representative indoor air… More >

  • Open Access

    ARTICLE

    Simulation of Temperature Field in Oil-Based Drill Cuttings Pyrolysis Furnace for Shale Gas

    Pu Liu, Guangwei Bai*, Wei Li, Chuanhua Ge

    Frontiers in Heat and Mass Transfer, Vol.23, No.6, pp. 1847-1864, 2025, DOI:10.32604/fhmt.2025.070378 - 31 December 2025

    Abstract To address the issue of uneven temperature distribution in shale gas oil-based drill cuttings pyrolysis furnaces, a numerical model was developed using Fluent software. The effects of nitrogen flow rate, heating tube spacing, and furnace dimensions on the internal temperature field were thoroughly analyzed from a mechanistic perspective. The results indicated that non-uniform radiation from the heating tubes and flow disturbances induced by the nitrogen stream were the primary causes of localized heat concentration. Under no-load conditions, the maximum deviation between simulated and on-site measured temperatures was 1.5%, validating the model’s accuracy. Furthermore, this study More >

  • Open Access

    ARTICLE

    Operation Performance of Scroll Compressor under Different Pressure Ratio Conditions

    Weifang Yang1, Yaping Liu1,*, Chao Gui1, Yangyu Shi2, Mengyi Ge1

    Frontiers in Heat and Mass Transfer, Vol.23, No.6, pp. 2051-2072, 2025, DOI:10.32604/fhmt.2025.070138 - 31 December 2025

    Abstract This study experimentally investigates the operational performance of a scroll compressor using R513A to expand its application range as a substitute for R134a. A vapor compression heat pump test platform was established to analyze the variation trends of heating capacity, refrigerant mass flow rate, compressor power consumption, and current by controlling the compressor inlet and outlet pressures (i.e., evaporating and condensing temperatures). The results indicate that both heating capacity and refrigerant mass flow rate decrease with increasing pressure ratio. Compressor power consumption and current initially increase and then decrease with rising evaporating temperature, whereas they… More > Graphic Abstract

    Operation Performance of Scroll Compressor under Different Pressure Ratio Conditions

  • Open Access

    ARTICLE

    Analysis of Air Conditioning Unit Performance Due to Variations in Water Cooling Temperature Using an Extra Cooling Water Loop

    Noor Moneer Basher1, Omar Rafae Alomar1,*, Omar Mohammed Ali2, Diyar Abdullah Ahmed3

    Frontiers in Heat and Mass Transfer, Vol.23, No.6, pp. 2001-2024, 2025, DOI:10.32604/fhmt.2025.066997 - 31 December 2025

    Abstract The energy consumption of a Split air conditioning unit (ACU) inside a building is extremely large, and efforts to decrease this issue are ongoing. The current work aims to experimentally investigate the thermal performance of ACU using an external cooling-water loop for pre-cooling the condenser to improve the efficiency and to reduce energy consumption by reducing refrigerant temperature before entering the condenser, thereby reducing the coefficient of performance. The experiments are performed on ACU with and without using an external cooling-water loop under different climate conditions. By using the experimental data, the systems’ performances for… More >

  • Open Access

    ARTICLE

    Synthesis of Hyperbranched Polyethyleneimine-Propylene Oxide-N-isopropylacrylamide (HPEI-co-PO-co-NIPAM) Terpolymer as a Shale Inhibitor

    Wenjun Hu, Liquan Zhang*

    Journal of Polymer Materials, Vol.42, No.4, pp. 1159-1179, 2025, DOI:10.32604/jpm.2025.072450 - 26 December 2025

    Abstract Addressing the persistent challenge of shale hydration and swelling in water-based drilling fluids (WBDFs), this study developed a smart thermo-responsive shale inhibitor, Hyperbranched Polyethyleneimine-Propylene Oxide-N-isopropylacrylamide (HPN). It was synthesized by grafting hyperbranched polyethyleneimine (HPEI) with propylene oxide (PO) and N-isopropylacrylamide (NIPAM), creating a synergistic hydration barrier through hydrophobic association and temperature-triggered pore plugging. Structural characterization by Fourier-Transform Infrared (FTIR) spectroscopy and gel permeation chromatography (GPC) confirmed the successful formation of the HPN terpolymer, revealing a unique “cationic–nonionic” amphiphilic architecture with temperature-responsive properties. Performance evaluation demonstrated that HPN significantly outperforms conventional inhibitors, including potassium chloride (KCl),… More >

  • Open Access

    ARTICLE

    A Prediction Method for Concrete Mixing Temperature Based on the Fusion of Physical Models and Neural Networks

    Lei Zheng1,*, Hong Pan2,3, Yuelei Ruan2,4, Guoxin Zhang1, Lei Zhang1,*, Jianda Xin1, Zhenyang Zhu1, Jianyao Zhang2,5, Wei Liu1

    CMES-Computer Modeling in Engineering & Sciences, Vol.145, No.3, pp. 3217-3241, 2025, DOI:10.32604/cmes.2025.074651 - 23 December 2025

    Abstract As a critical material in construction engineering, concrete requires accurate prediction of its outlet temperature to ensure structural quality and enhance construction efficiency. This study proposes a novel hybrid prediction method that integrates a heat conduction physical model with a multilayer perceptron (MLP) neural network, dynamically fused via a weighted strategy to achieve high-precision temperature estimation. Experimental results on an independent test set demonstrated the superior performance of the fused model, with a root mean square error (RMSE) of 1.59°C and a mean absolute error (MAE) of 1.23°C, representing a 25.3% RMSE reduction compared to More >

  • Open Access

    ARTICLE

    Raman and x-ray diffraction data analysis of Ge2Sb2Te5 films using gaussian approximation considering the temperature population factor

    S. N. Garibovaa,b,*, А. I. Isayeva, S. A. Rzayevaa, F. N. Mammadovc

    Chalcogenide Letters, Vol.22, No.1, pp. 1-9, 2025, DOI:10.15251/CL.2025.221.1

    Abstract The structure particulars of amorphous Ge2Sb2Te5 thermally evaporated on glass substrates, as well as films annealed at temperatures of 500 and 700 K have been studied by the considering of experimentally established facts obtained from X-ray analysis and Raman spectroscopy measurements. The Debye-Scherrer and Williams-Hall methods were applied to the X-ray diffraction data for estimate the size of crystallites, interatomic distances, dislocation density and structure distortion degree. The features of heat treatment effect on numerical values of the above quantities at a given temperatures have been established. The analysis of the spectral distribution of Raman… More >

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