Aiga Ivdre^*, Ralfs Pomilovskis, Arnis Abolins

Journal of Renewable Materials, Vol.13, No.2, pp. 349-361, 2025, DOI:10.32604/jrm.2024.056820 - 20 February 2025

Abstract Studies on the use of renewable materials for various applications, including polymers, have gained momentum due to global climate change and the push towards a circular economy. In this study, polymer resins were developed through Michael 1,4-addition. The precursors were synthesized from tall oil-based acetoacetates derived from epoxidized tall oil fatty acids or their methyl esters. Two different epoxidation methods were employed: enzymatic epoxidation of tall oil fatty acids and ion-exchange resin epoxidation of tall oil fatty acid methyl esters. Following oxirane opening and transesterification with trimethylolpropane, further esterification or transesterification was carried out to… More >

Kristine Meile^1,*, Martins Romanovskis^1,2, Thomas Nicol³, Neil Hindle³, Aivars Zhurinsh¹

Journal of Renewable Materials, Vol.12, No.12, pp. 2135-2152, 2024, DOI:10.32604/jrm.2024.056775 - 20 December 2024

Abstract Fast pyrolysis of pre-treated birch wood in a super-heated steam environment produces a condensate rich in anhydrosugars. With the objective to obtain several product streams from this condensate, the possibility of extracting additional chemical species is explored, thus promoting the development of a pyrolysis-based biorefinery. In this work, the extraction and recovery of pyrolytic phenols from birch wood pyrolysis condensate was studied using ion exchange resins. With an aim to achieve effective phenol recovery, while obtaining high purity levoglucosan, basic ion exchange resins, both in OH⁻ and Cl⁻ form, as well as polystyrene-divinyl resins without functional… More > Graphic Abstract

Bengang Zhang^1,*, Antonio Pizzi^2,*, Mathieu Petrissans¹, Anelie Petrissans¹, Baptiste Colin¹

Journal of Renewable Materials, Vol.11, No.11, pp. 3867-3889, 2023, DOI:10.32604/jrm.2023.028888 - 31 October 2023

Abstract Melamine-dialdehyde starch resins used for wood surface finishes have been developed. The reaction of melamine with dialdehyde starch has been shown to occur by FTIR and MALDI ToF spectrometry, with several oligomer species due to the reaction of the two materials being identified, and the resin thermal stability was studied by thermogravimetric analysis. The resins were prepared by two different procedures when it was realized that dialdehyde starch is sensitive to too high a temperature for prolonged times. The melamine-dialdehyde starch resins were applied on particleboard supports as a direct liquid surface finish and a More >

Nurul Anis Athirah Ab Aziz^*, Chin Wei Lai^*, Boon Hoong Ong

Journal of Renewable Materials, Vol.11, No.6, pp. 2745-2770, 2023, DOI:10.32604/jrm.2023.025899 - 27 April 2023

Abstract Nowadays, corrosion is not only undesirable, but it also has a significant influence on the industrial sectors and technical innovations that have demand for metals. The global economic damage is expected to reach $2.5 trillion, equivalent to more than 3.4% of the world’s GDP in 2013. It is linked with significant financial harm, manufacturing pollution, and safety issues. An electrochemical process primarily induces metal corrosion at the metalelectrolyte interface region, caused by steel oxidation and the reduction of oxygen, protons, and water. Therefore, organic and epoxy coatings can be applied as protective coatings. Additionally, it… More > Graphic Abstract

Mahdi Mubarok^1,2, Christine Gérardin-Charbonnier^1,*, Elham Azadeh¹, Firmin Obounou Akong¹, Stéphane Dumarçay¹, Antonio Pizzi¹, Philippe Gérardin^1,*

Journal of Renewable Materials, Vol.11, No.2, pp. 505-521, 2023, DOI:10.32604/jrm.2022.024872 - 22 September 2022

Abstract Furfurylation is a well-known wood modification technology. This paper studied the effect of tannin addition on the wood furfurylation. Three kinds of dicarboxylic acids, adipic acid, succinic acid, and tartaric acid, as well as glyoxal as a comparing agent, were used to catalyse the polymerisation of furanic or tannin-furanic solutions during wood modification. Impregnation of furanic or tannin-furanic solution at a certain concentration into the wood followed with curing at 103°C for a specific duration was performed for the wood modification. Different properties of the modified woods like dimensional stability, resistance of treatment to leaching, More >

Claudio Del Menezzi^1,2,3, Antonio Pizzi^2,*, Siham Amirou², Xuedong Xi^4,5

Journal of Renewable Materials, Vol.11, No.2, pp. 539-553, 2023, DOI:10.32604/jrm.2022.024971 - 22 September 2022

Abstract

This article presents the first applied results of using citric acid in combinations with a melamine-urea-formaldehyde (MUF) resin for bonding wood veneers. The chemical reactions involved are shown based on a MALDI ToF analysis of the reaction of the MUF resin with citric acid. The preliminary results of the physical and mechanical properties of the LVL prepared are also presented. Veneers from Populus sp were used to manufacture 5-layer laminated veneer lumber (LVL) of small dimensions. Five combinations of the amount of citric acid, MUF spread rate and pressing parameters were tested. LVL bonded with 20%

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Antonio Pizzi^*

Journal of Renewable Materials, Vol.11, No.1, pp. 1-25, 2023, DOI:10.32604/jrm.2022.023314 - 10 August 2022

Abstract Soy flour (SF), soy protein and soy protein isolates (SPI) have been the focus of increasing research on their application as new materials for a variety of applications, mainly for wood adhesives and other resins. Tannins too have been the focus of increasing research for similar applications. While both materials are classed as non-toxic and have achieved interesting results the majority of the numerous and rather inventive approaches have still relied on some sort of hardeners or cross-linkers to bring either of them or even their combination to achieve acceptable results. The paper after a More >

Lara Greiner^1,*, Philipp Kukla², Sebastian Eibl¹, Manfred Döring³

Journal of Renewable Materials, Vol.10, No.7, pp. 1931-1950, 2022, DOI:10.32604/jrm.2022.019548 - 07 March 2022

Abstract A novel, versatile flame retardant substructure based on phosphorylated salicylic acid (SCP) is described and used in the synthesis of new flame retardants for HexFlow^® RTM6, a high-performance epoxy resin used in resin transfer molding processes as composite matrix. The starting material salicylic acid can be obtained from natural sources. SCP as reactive phosphorus chloride is converted with a novolak, a novolak containing 9, 10-dihydro-9- oxa-10-phospha-phenanthrene-10-oxide (DOPO) substituents or DOPO-hydroquinone to flame retardants with sufficient thermal stability and high char yield. Additionally, these flame retardants are soluble in the resin as well as react into the… More >

Hongxiang Liu^1,2,,*, Neng Xiong^1,2, Songli Wang^1,2, Wei Zhang^1,2, Bo Yong^1,2

FDMP-Fluid Dynamics & Materials Processing, Vol.18, No.3, pp. 549-561, 2022, DOI:10.32604/fdmp.2022.017979 - 22 February 2022

Abstract

The effects of a magnesium-based layered composite on the flammability of a phenolic epoxy resin (EP) are studied. In order to produce the required composite material, first, magnesium hydroxide, aluminum salt and deionized water are mixed into a reactor according to a certain proportion to induce a hydrothermal reaction; then, the feed liquid is filtered out using a solid-liquid separation procedure; finally, the material is dried and crushed. In order to evaluate its effects on the flammability of the EP, first, m-phenylenediamine is added to EP and vacuum defoamation is performed; then, EP is poured into

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Hongliang Ding, Xin Wang^*, Lei Song, Yuan Hu

Journal of Renewable Materials, Vol.10, No.4, pp. 871-895, 2022, DOI:10.32604/jrm.2022.018150 - 02 November 2021

Abstract Benzoxazines have attracted wide attention from academics all over the world because of their unique properties. However, most of the production and preparation of benzoxazine resins depends on petroleum resources now, especially bisphenol A-based benzoxazine. Therefore, owing to the environmental impacts, the development of bio-based benzoxazines is gaining more and more interest to substitute petroleum-based benzoxazines. Similar to petroleum-based benzoxazines, most of bio-based benzoxazines suffer from flammability. Thus, it is necessary to endow bio-based benzoxazines with outstanding flame retardancy. The purpose of this review is to summarize the latest advance in flame retardant bio-based benzoxazines. More > Graphic Abstract