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  • Open Access

    ARTICLE

    A Melamine–Dialdehyde Starch Wood Particleboard Surface Finish without Formaldehyde

    Bengang Zhang1,*, Antonio Pizzi2,*, Mathieu Petrissans1, Anelie Petrissans1, Baptiste Colin1

    Journal of Renewable Materials, Vol.11, No.11, pp. 3867-3889, 2023, DOI:10.32604/jrm.2023.028888 - 31 October 2023

    Abstract Melamine-dialdehyde starch resins used for wood surface finishes have been developed. The reaction of melamine with dialdehyde starch has been shown to occur by FTIR and MALDI ToF spectrometry, with several oligomer species due to the reaction of the two materials being identified, and the resin thermal stability was studied by thermogravimetric analysis. The resins were prepared by two different procedures when it was realized that dialdehyde starch is sensitive to too high a temperature for prolonged times. The melamine-dialdehyde starch resins were applied on particleboard supports as a direct liquid surface finish and a More >

  • Open Access

    REVIEW

    A Review of Graphene Oxide Crosslinking as Enhanced Corrosion Shield Application

    Nurul Anis Athirah Ab Aziz*, Chin Wei Lai*, Boon Hoong Ong

    Journal of Renewable Materials, Vol.11, No.6, pp. 2745-2770, 2023, DOI:10.32604/jrm.2023.025899 - 27 April 2023

    Abstract Nowadays, corrosion is not only undesirable, but it also has a significant influence on the industrial sectors and technical innovations that have demand for metals. The global economic damage is expected to reach $2.5 trillion, equivalent to more than 3.4% of the world’s GDP in 2013. It is linked with significant financial harm, manufacturing pollution, and safety issues. An electrochemical process primarily induces metal corrosion at the metalelectrolyte interface region, caused by steel oxidation and the reduction of oxygen, protons, and water. Therefore, organic and epoxy coatings can be applied as protective coatings. Additionally, it… More > Graphic Abstract

    A Review of Graphene Oxide Crosslinking as Enhanced Corrosion Shield Application

  • Open Access

    ARTICLE

    Modification of Wood by Tannin-Furfuryl Alcohol Resins–Effect on Dimensional Stability, Mechanical Properties and Decay Durability

    Mahdi Mubarok1,2, Christine Gérardin-Charbonnier1,*, Elham Azadeh1, Firmin Obounou Akong1, Stéphane Dumarçay1, Antonio Pizzi1, Philippe Gérardin1,*

    Journal of Renewable Materials, Vol.11, No.2, pp. 505-521, 2023, DOI:10.32604/jrm.2022.024872 - 22 September 2022

    Abstract Furfurylation is a well-known wood modification technology. This paper studied the effect of tannin addition on the wood furfurylation. Three kinds of dicarboxylic acids, adipic acid, succinic acid, and tartaric acid, as well as glyoxal as a comparing agent, were used to catalyse the polymerisation of furanic or tannin-furanic solutions during wood modification. Impregnation of furanic or tannin-furanic solution at a certain concentration into the wood followed with curing at 103°C for a specific duration was performed for the wood modification. Different properties of the modified woods like dimensional stability, resistance of treatment to leaching, More >

  • Open Access

    ARTICLE

    MUF Resins Improved by Citric Acid as Adhesives for Wood Veneer Panels

    Claudio Del Menezzi1,2,3, Antonio Pizzi2,*, Siham Amirou2, Xuedong Xi4,5

    Journal of Renewable Materials, Vol.11, No.2, pp. 539-553, 2023, DOI:10.32604/jrm.2022.024971 - 22 September 2022

    Abstract

    This article presents the first applied results of using citric acid in combinations with a melamine-urea-formaldehyde (MUF) resin for bonding wood veneers. The chemical reactions involved are shown based on a MALDI ToF analysis of the reaction of the MUF resin with citric acid. The preliminary results of the physical and mechanical properties of the LVL prepared are also presented. Veneers from Populus sp were used to manufacture 5-layer laminated veneer lumber (LVL) of small dimensions. Five combinations of the amount of citric acid, MUF spread rate and pressing parameters were tested. LVL bonded with 20%

    More > Graphic Abstract

    MUF Resins Improved by Citric Acid as Adhesives for Wood Veneer Panels

  • Open Access

    REVIEW

    A Review of Soy-Tannin Gelling for Resins Applications

    Antonio Pizzi*

    Journal of Renewable Materials, Vol.11, No.1, pp. 1-25, 2023, DOI:10.32604/jrm.2022.023314 - 10 August 2022

    Abstract Soy flour (SF), soy protein and soy protein isolates (SPI) have been the focus of increasing research on their application as new materials for a variety of applications, mainly for wood adhesives and other resins. Tannins too have been the focus of increasing research for similar applications. While both materials are classed as non-toxic and have achieved interesting results the majority of the numerous and rather inventive approaches have still relied on some sort of hardeners or cross-linkers to bring either of them or even their combination to achieve acceptable results. The paper after a More >

  • Open Access

    ARTICLE

    Phosphorylated Salicylic Acid as Flame Retardant in Epoxy Resins and Composites

    Lara Greiner1,*, Philipp Kukla2, Sebastian Eibl1, Manfred Döring3

    Journal of Renewable Materials, Vol.10, No.7, pp. 1931-1950, 2022, DOI:10.32604/jrm.2022.019548 - 07 March 2022

    Abstract A novel, versatile flame retardant substructure based on phosphorylated salicylic acid (SCP) is described and used in the synthesis of new flame retardants for HexFlow® RTM6, a high-performance epoxy resin used in resin transfer molding processes as composite matrix. The starting material salicylic acid can be obtained from natural sources. SCP as reactive phosphorus chloride is converted with a novolak, a novolak containing 9, 10-dihydro-9- oxa-10-phospha-phenanthrene-10-oxide (DOPO) substituents or DOPO-hydroquinone to flame retardants with sufficient thermal stability and high char yield. Additionally, these flame retardants are soluble in the resin as well as react into the… More >

  • Open Access

    ARTICLE

    A Study on a Magnesium-Based Layered Composite Used as a Flame Retardant for Phenolic Epoxy Resins

    Hongxiang Liu1,2,,*, Neng Xiong1,2, Songli Wang1,2, Wei Zhang1,2, Bo Yong1,2

    FDMP-Fluid Dynamics & Materials Processing, Vol.18, No.3, pp. 549-561, 2022, DOI:10.32604/fdmp.2022.017979 - 22 February 2022

    Abstract

    The effects of a magnesium-based layered composite on the flammability of a phenolic epoxy resin (EP) are studied. In order to produce the required composite material, first, magnesium hydroxide, aluminum salt and deionized water are mixed into a reactor according to a certain proportion to induce a hydrothermal reaction; then, the feed liquid is filtered out using a solid-liquid separation procedure; finally, the material is dried and crushed. In order to evaluate its effects on the flammability of the EP, first, m-phenylenediamine is added to EP and vacuum defoamation is performed; then, EP is poured into

    More >

  • Open Access

    REVIEW

    Recent Advances in Flame Retardant Bio-Based Benzoxazine Resins

    Hongliang Ding, Xin Wang*, Lei Song, Yuan Hu

    Journal of Renewable Materials, Vol.10, No.4, pp. 871-895, 2022, DOI:10.32604/jrm.2022.018150 - 02 November 2021

    Abstract Benzoxazines have attracted wide attention from academics all over the world because of their unique properties. However, most of the production and preparation of benzoxazine resins depends on petroleum resources now, especially bisphenol A-based benzoxazine. Therefore, owing to the environmental impacts, the development of bio-based benzoxazines is gaining more and more interest to substitute petroleum-based benzoxazines. Similar to petroleum-based benzoxazines, most of bio-based benzoxazines suffer from flammability. Thus, it is necessary to endow bio-based benzoxazines with outstanding flame retardancy. The purpose of this review is to summarize the latest advance in flame retardant bio-based benzoxazines. More > Graphic Abstract

    Recent Advances in Flame Retardant Bio-Based Benzoxazine Resins

  • Open Access

    ARTICLE

    Degradation of Spent Radioactive Ion Exchange Resins and Its Mechanisms by Fenton Process

    Wendong Feng1,2, Jian Li2, Hongxiang An2, Yunhai Wang1,*

    Journal of Renewable Materials, Vol.8, No.10, pp. 1283-1293, 2020, DOI:10.32604/jrm.2020.011000 - 31 August 2020

    Abstract Spent IERs are released during the operation and decommissioning of nuclear facilities. The safe and efficient treatment of spent IERs is an emergent problem in nuclear industry. IRN77 is a typical ion exchange resin widely used in many nuclear power plants. Fenton process can degrade organic resins and reduce the radioactive residues volume and the disposal cost significantly. In this work, the IRN77 resin was selected as a model ion exchange resin and its treatment via Fenton process was investigated. The influencing factors for resin degradation, including catalyst dosage, reaction time, initial pH, temperature and… More >

  • Open Access

    ARTICLE

    Impregnated Paper-Based Decorative Laminates Prepared from Lignin-Substituted Phenolic Resins

    Marion Thébault1, Ya Li1, Christopher Beuc1, Stephan Frömel-Frybort1,2, Edith-Martha Zikulnig-Rusch1, Larysa Kutuzova3, Andreas Kandelbauer3,*

    Journal of Renewable Materials, Vol.8, No.10, pp. 1181-1198, 2020, DOI:10.32604/jrm.2020.09755 - 31 August 2020

    Abstract High Pressure Laminates (HPL) panels consist of stacks of self-gluing paper sheets soaked with phenol-formaldehyde (PF) resins. An important requirement for such PFs is that they must rapidly penetrate and saturate the paper pores. Partially substituting phenol with bio-based phenolic chemicals like lignin changes the physico-chemical properties of the resin and affects its ability to penetrate the paper. In this study, PF formulations containing different proportions of lignosulfonate and kraft lignin were used to prepare paper-based laminates. The penetration of a Kraft paper sheet was characterized by a recently introduced, new device measuring the conductivity… More >

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