BAOHAI PAN^1,2, JUNCHENG HUANG¹, LAI CHEN², FEI LIU^1,*, CHEN JING, HAINING NA^1,*, JIN ZHU¹

Journal of Polymer Materials, Vol.37, No.1-2, pp. 17-27, 2020, DOI:10.32381/JPM.2020.37.1-2.2

Abstract A switchable CO₂ /1,8-diazabicyclo[5.4.0]undec-7-ene (DBU)/dimethyl sulfoxide (DMSO) solvent system is applied to prepare corn cellulose film with controllable mechanical property. By use of the switchable CO₂ /DBU/DMSO system, a rather simple process concerning reacted dissolution and heated precipitation controlled by addition and releasing of CO₂ respectively, to prepare corn cellulose film, is formed. Results exhibit the degree of dissolution of corn cellulose is easily controlled just by adjusting the feeding amount of DBU in the switchable solvent system. Accordingly, some undissolved part of corn cellulose with relative high crystallinity can be appropriately retained to contribute to the improvement of mechanical… More >

RAFAT SABA^*, MOHD. KASHIF AZIZ, GHULAM MUSTAFA, ARPIT SRIVASTAVA, SHEKHAR SRIVASTAVA^*

Journal of Polymer Materials, Vol.38, No.1-2, pp. 153-166, 2021, DOI:10.32381/JPM.2021.38.1-2.12

Abstract We have synthesized Schiff’s base of Fe₃ O₄ @chitosan with 4,4'-diselenobisbenzaldehyde (Fe₃O₄ @CSSe) composite and used it as acatalyst for the oxidation of sulfides, having some advantageous properties such as eco-friendly, cost-effective and highly efficient magnetic biocatalyst of selenium. The synthesized schiff’s base was characterized by different physical characterization techniques such as Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), Vibrating sample magnetometer (VSM)and Dynamic light scattering (DLS). Further, we used the resulting schiff’s base as a catalyst in the presence of a green oxidant (H₂ O₂ ) to oxidize sulfides to corresponding sulfoxides at room temperature. It has been… More >

RAID BANAT^1,*, MANAL AL-RAWASHDEH¹, HEBA ALKHLAIFAT¹

Journal of Polymer Materials, Vol.38, No.1-2, pp. 137-151, 2021, DOI:10.32381/JPM.2021.38.1-2.11

Abstract Composite of oil Shale ash (OSA) filler and high density polyethylene (HDPE) matrix was formulated and studied. OSA mainly composed of Ca, Si, and Fe most of which in oxide forms. OSA-HDPE composite with 0, 5, 10, 15, 20, and 25 wt. % OSA were produced using extrusion and hot press. Mechanical, morphological, and water uptake properties of the composite are discussed herein. While the tensile stress at yield, 47 MPa, restored its value close to the neat HDPE, an increase in the mean values of the tensile stress at rapture from 19 to 33 MPa, the tensile modulus from… More >

ANU SINGH AND P.K. DUTTA^*

Journal of Polymer Materials, Vol.38, No.1-2, pp. 63-69, 2021, DOI:10.32381/JPM.2021.38.1-2.6

Abstract The experiment was designed to examine the microsphere of the chitin-glucan complex. We formed a chitin-glucan microsphere (ChGMS) from the spray dryer technique. SEM images observed that shape of ChGMS was spherical. From particle size analyzer and SEM analysis both showed that the size of particles was in the range of 1.5 to 3.5 µm. It showed amorphous nature after the formation of microsphere particles of chitin-glucan. The effect of chitin-glucan complex and ciprofloxacin loaded chitin-glucan microsphere on Bacillus subtilis and Escherichia coli were also tested. Antibacterial analysis was indicating that the ciprofloxacin loaded chitinglucan microsphere strongly inhibited the growth… More >

PETR SYSEL¹, ROMAN HOLAKOVSKݲ, ŠTĚPÁN HOVORKA³, JAROSLAV Ž ÁDNÝ⁴, PAVEL IZÁK⁴

Journal of Polymer Materials, Vol.39, No.3-4, pp. 325-335, 2022, DOI:10.32381/JPM.2022.39.3-4.10

Abstract Linear polyimides based on both of the 2,2´-diamino-1,1´-binaphthalene enantiomers and their racemic mixture were synthesized and characterized. A two-step synthetic route, consisting of the preparation of the polyimide precursor followed by its thermal imidization at temperatures not exceeding 200°C, was employed. The products were analyzed by FTIR and ¹ H NMR spectroscopy. All of the tested materials were nearly fully imidized after 25 h. The final polyimides possess high glass transition temperatures, are thermo-oxidatively stable and are soluble in common organic solvents as 1-methyl-2-pyrrolidone, tetrahydrofuran and chloroform; additionally, those prepared from the enantiomers show optical activity. The values of specific… More >

NURUL HAYATI YUSOF^1,*, DAZYLAH DARJI¹, TAN KIM SONG¹, NGHIEM THI THUONG²

Journal of Polymer Materials, Vol.39, No.1-2, pp. 151-166, 2022, DOI:10.32381/JPM.2022.39.1-2.10

Abstract In this work, a pure gum mould made of prevulcanized natural rubber/cloisite-Na⁺ nanocomposite (PVNR/CN) was prepared and characterized for ornament application. The suitable conditions to prepare PVNR/CN latex mixtures and the properties of the resulting PVNR/CN nanocomposites were investigated. The optimum CN concentration in the latex mixture was 1.0 phr, with the properties of 60 wt% total solid content, more than 600 sec mechanical stability time, lower than 350 cP Brookfield viscosity, and pH 10. The properties of PVNR/CN nanocomposite showed high strength, moderate hardness, and good thermal stability. The morphology by TEM showed well dispersion of CN particles in… More >

V. S. MAMTANI, A. K. GHOSH^*, R. C. BINDAL

Journal of Polymer Materials, Vol.39, No.1-2, pp. 137-149, 2022, DOI:10.32381/JPM.2022.39.1-2.9

Abstract In this study, polysulfone based capillary ultrafiltration membranes with desired characteristics were indigenously developed and their performance was evaluated with respect to turbidity removal from raw sea water. Capillary membranes were spun with in-house fabricated spinneret using polymer casting solution (dope solution) of different compositions having different viscosity using polyvinyl pyrrolidone (PVP) as pore-forming agent. Different experimental conditions namely dope pressure, bore fluid flow rate and air gap distance are optimized to get membranes of desired properties. Test results of individual capillaries in terms of pure water permeability (PWP), separation of single uncharged solutes like polyethylene glycol (PEG) and mechanical… More >

CONGHUI XU, ZHEQING GONG, XIAOLONG CHEN, LIJUN CHEN^*

Journal of Polymer Materials, Vol.40, No.1-2, pp. 47-58, 2023, DOI:10.32381/JPM.2023.40.1-2.4

Abstract The self-crosslinking polyacrylate latex was prepared via the semi-continuous seed emulsion polymerization technology that methyl methacrylate(MMA) and butyl acrylate (BA)were used as the main monomers and hexafluorobutyl methacrylate (HFMA) and monobutylitaconate (MBI) were used as the modified monomers and glycidyl methacrylate (GMA) was used as the crosslinked monomer which were emulsified with the environmentally friendly mixed surfactant of the isomeric triethylene (9) ether (E-1309) and the lauryl polyoxyethylene ether sulfosuccinate disodium salt (MES-30). The resultant latex and its film is characterized by Fourier transform infrared spectroscopy (FTIR), differential scanning calorimeter (DSC), laser particle sizer, contact angle determinator. The comparison of… More >

Zhiyong Yang, Enjie Hu, Lei Xi, Zhi Chen^*, Feng Xiong, Chuanhai Zhan

FDMP-Fluid Dynamics & Materials Processing, Vol.20, No.4, pp. 705-723, 2024, DOI:10.32604/fdmp.2023.044030

Abstract An experimental investigation into the thermal conductivity of CF-SiC two-phase composite asphalt concrete is presented. The main objective of this study was to verify the possibility of using SiC powder instead of mineral powder as the thermal conductive filler to prepare a new type of asphalt concrete and improve the efficiency of electrothermal snow and ice melting systems accordingly. The thermal conductivity of asphalt concrete prepared with different thermally conductive fillers was tested by a transient plane source method, and the related performances were measured. Then the temperature rise rate and surface temperature were studied through field heating tests. Finally,… More >

Jianlong Jin, Jingjing Ding, Long Xiong, Ming Bao, Peng Zeng^*

FDMP-Fluid Dynamics & Materials Processing, Vol.20, No.4, pp. 803-814, 2024, DOI:10.32604/fdmp.2023.027311

Abstract The effects of different contents of a MgO expansive agent and phosphorus slag on the mechanical properties, shrinkage behavior, and the heat of hydration of concrete were studied. The slump flow, setting time, dry shrinkage, and hydration heat were used as sensitive parameters to assess the response of the considered specimens. As shown by the results, in general, with an increase in the phosphorus slag content, the hydration heat of concrete decreases for all ages, but the early strength displays a downward trend and the dry shrinkage rate increases. The 90-d strength and dry shrinkage of concrete could be improved… More > Graphic Abstract