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  • Open Access

    ARTICLE

    Hybrid Taguchi and Machine Learning Framework for Optimizing and Predicting Mechanical Properties of Polyurethane/Nanodiamond Nanocomposites

    Markapudi Bhanu Prasad1, Borhen Louhichi2, Santosh Kumar Sahu1,*

    CMES-Computer Modeling in Engineering & Sciences, Vol.145, No.1, pp. 483-519, 2025, DOI:10.32604/cmes.2025.069395 - 30 October 2025

    Abstract This study investigates the mechanical behavior of polyurethane (PU) nanocomposites reinforced with nanodiamonds (NDs) and proposes an integrated optimization–prediction framework that combines the Taguchi method with machine learning (ML). The Taguchi design of experiments (DOE), based on an L9 orthogonal array, was applied to investigate the influence of composite type (pure PU, 0.1 wt.% ND, 0.5 wt.% ND), temperature (145°C–165°C), screw speed (50–70 rpm), and pressure (40–60 bar). The mechanical tests included tensile, hardness, and modulus measurements, performed under varying process parameters. Results showed that the addition of 0.5 wt.% ND substantially improved PU performance,… More >

  • Open Access

    ARTICLE

    Enhancing Mechanical Properties of Biobased Polyurethane Composites Using Birch Flour and Diatomite Fillers

    Dmitry S. Konovalov1, Natalia N. Saprykina2, Vjacheslav V. Zuev1,2,*

    Journal of Renewable Materials, Vol.13, No.10, pp. 2043-2058, 2025, DOI:10.32604/jrm.2025.02025-0079 - 22 October 2025

    Abstract In this study, the polyurethanes (PU) were synthesized from 4,4-methylene diphenyl diisocyanate and biobased ethoxylated castor oil or one mixture of ethoxylated and neat castor oil by direct mixing method. Utilization of ethoxylated castor oil increases the tensile strength of PU up to 2.75 times (from 3.2 to 8.8 MPa), compared to PU based on neat castor oil. The PU composites filled with birch flour, diatomite, and their mixture were prepared using a homemade dissolver with a cutter-shaped attachment at a speed of 1500 r min−1. The tensile strength of PU composites filled with birch flour… More > Graphic Abstract

    Enhancing Mechanical Properties of Biobased Polyurethane Composites Using Birch Flour and Diatomite Fillers

  • Open Access

    PROCEEDINGS

    External Field Induced High Speed Sintering of Polyurethane Covalent Adaptable Network

    Lingyao Zhou, Ling Zhang, Qifan Zhao, Zhanhua Wang, Xili Lu, Guoxia Fei, Lirong He*, Hesheng Xia*

    The International Conference on Computational & Experimental Engineering and Sciences, Vol.33, No.1, pp. 1-1, 2025, DOI:10.32604/icces.2025.012861

    Abstract Powder based high speed sintering (HSS) improves the printing efficiency compared to SLS printing. The shortened layer time for HSS requires quick melting and solidification of powders, which is a big challenge for traditional printing powders materials, especially the viscous elastomers. Herein, a dynamic cross-linked polyurethane containing Diels-Alder bonds (PUDA) was synthesized at kilo scale and used for HSS. The incorporation of dynamic DA bonds into PU enables the dissociation of the polymer chain under IR light heating, and will lead to fast relaxation, diffusion and dis/re-entanglement, addressing the problem of incomplete sintering and weak… More >

  • Open Access

    ARTICLE

    Experimental Study on Additional Stress Induced by Grouting with Polyurethane-Modified Cementitious Materials under Confined Conditions

    Qizhi Chen1,2, Wensheng Cheng1,2, Baoping Zou1,2,*, Bowen Kong1,2, Yansheng Deng1,2, Xu Long3,*

    Journal of Polymer Materials, Vol.42, No.2, pp. 463-475, 2025, DOI:10.32604/jpm.2025.064257 - 14 July 2025

    Abstract The rapid development of urban rail transit has posed increasing construction and operational challenges for metro tunnels, often leading to structural damage. Grouting technology using cement-based materials is widely applied to address issues such as seepage, leakage, and alignment correction in shield tunnels. This study investigates the additional stress induced by grouting in silty soil layers, using cement-based grouts with different water-to-cement ratios and polyurethane-modified cement-based materials. Results show that additional stress decreases with depth and is more influenced by horizontal distance from the grouting point. In staged grouting, the first injection phase contributes about More >

  • Open Access

    REVIEW

    Synthesis of Biomass Polyurethane and Its Properties

    Zhen-Yu Chen1, Yue-RU Wang1, De-Yi Teng1, Yan-Fang Xue1, Gui-Chang Jiang1,2,*

    Journal of Polymer Materials, Vol.42, No.2, pp. 359-377, 2025, DOI:10.32604/jpm.2025.063342 - 14 July 2025

    Abstract PU, or polyurethane, features a repeating urethane group (-NH-COO-) in its molecular structure. Traditionally, PUs are synthesized from isocyanate and polyol compounds derived from fossil resources through polymerization reactions. The depletion of fossil fuels and the increasing climate problems call for the expansion of more renewable sources of chemicals, such as modern biomass. However, the conversion of biomass into chemicals is challenging due to the inherent molecular complexity of its composition. In recent years, advances in green chemistry have led researchers to focus on developing bio-based polyurethanes by sourcing polyols, isocyanates, and chain extender precursors More >

  • Open Access

    ARTICLE

    Mechanical Performance Analysis of Rubber Elastic Polymer-Polyurethane Reinforced Cement-Based Composite Grouting Materials

    Baoping Zou1,2, Jiahao Yin1,2, Chunhui Cao1,2,*, Xu Long3,*

    Journal of Polymer Materials, Vol.42, No.1, pp. 255-275, 2025, DOI:10.32604/jpm.2025.062081 - 27 March 2025

    Abstract The ongoing operation of subway systems makes existing tunnels vulnerable to deformations and structural damage caused by adjacent foundation pit construction. Such deformations-manifesting as horizontal displacement, heightened lateral convergence, and internal force redistribution-may significantly compromise subway operational safety. Grouting remediation has become a widely adopted solution for tunnel deformation control and structural reinforcement. Developing optimized grouting materials is crucial for improving remediation effectiveness, ensuring structural integrity, and maintaining uninterrupted subway operations. This investigation explores the substitution of fine mortar aggregates with 0.1 mm discarded rubber particles at varying concentrations (0%, 3%, 6%, 9%, 12%, and More >

  • Open Access

    ARTICLE

    Advanced Poly(Lactic Acid)/Thermoplastic Polyurethane Blend-Based Nanocomposites with Carbon Nanotubes and Graphene Nanoplatelets for Shape Memory

    Nayara Koba de Moura Morgado, Guilherme Ferreira de Melo Morgado, Erick Gabriel Ribeiro dos Anjos, Fabio Roberto Passador*

    Journal of Polymer Materials, Vol.42, No.1, pp. 95-110, 2025, DOI:10.32604/jpm.2025.059364 - 27 March 2025

    Abstract The continuous improvement in patient care and recovery is driving the development of innovative materials for medical applications. Medical sutures, essential for securing implants and closing deep wounds, have evolved to incorporate smart materials capable of responding to various stimuli. This study explores the potential of thermoresponsive sutures, made from shape memory materials, that contract upon heating to bring loose stitches closer together, promoting optimal wound closure. We developed nanocomposites based on a blend of poly(lactic acid) (PLA) and thermoplastic polyurethane (TPU)—biopolymers that inherently exhibit shape memory—enhanced with carbon nanotubes (CNT) and graphene nanoplatelets (GN)… More >

  • Open Access

    REVIEW

    Recent Developments in Bioadhesives and Binders

    Hong Lei1, Xiaojian Zhou2, Antonio Pizzi3,*, Guanben Du2,*, Xuedong Xi2

    Journal of Renewable Materials, Vol.13, No.2, pp. 199-249, 2025, DOI:10.32604/jrm.2025.02024-0048 - 20 February 2025

    Abstract This review is composed of three main parts each of which is written by well-known top specialists that have been, in a way or other, also the main participants of the majority of the developments reported. Thus, after a general part covering the grand lines and more in-depth views of more recent tannin, lignin, carbohydrate and soy bioadhesives, some mix of the other bio raw materials with soy protein and soy flour and some other differently sourced bioadhesives for wood, this review presents a more in-depth part on starch-based wood adhesives and a more in-depth… More > Graphic Abstract

    Recent Developments in Bioadhesives and Binders

  • Open Access

    PROCEEDINGS

    Tunable Energy Absorption of Thermoplastic Polyurethane P-type TPMS Lattice Structure via Trimming

    Haoming Mo1,*, Junhao Ding1, Xu Song1

    The International Conference on Computational & Experimental Engineering and Sciences, Vol.29, No.2, pp. 1-1, 2024, DOI:10.32604/icces.2024.011375

    Abstract Triply periodic minimal surface (TPMS) shell-lattices are attracting increasing attention because of their exceptional mechanical and geometric characteristics. Additive manufactured TPMS structures using thermoplastic polyurethane (TPU) have great application potential in energy absorptions, for which the mechanical properties can be conveniently adjusted to meet diverse requirements. Nevertheless, there is a need for further improvement in the stability and adjustability of energy absorption capacity. This is due to the significant impact of the buckling effect and induced stress fluctuations when the structure is subjected to compression. To alleviate the buckling effect and tune the capability of… More >

  • Open Access

    ARTICLE

    Adhesion of Technical Lignin-Based Non-Isocyanate Polyurethane Adhesives for Wood Bonding

    Jaewook Lee1, Byung-Dae Park1,*, Qinglin Wu2

    Journal of Renewable Materials, Vol.12, No.7, pp. 1187-1205, 2024, DOI:10.32604/jrm.2024.049948 - 21 August 2024

    Abstract Lignin is the most abundant aromatic natural polymer, and receiving great attention in replacing various petroleum-based polymers. The aim of this study is to investigate the feasibility of technical lignin as a polyol for the synthesis of non-isocyanate polyurethane (NIPU) adhesives to substitute current polyurethane (PU) adhesives that have been synthesized with toxic isocyanate and polyols. Crude hardwood kraft lignin (C-HKL) was extracted from black liquor from a pulp mill followed by acetone fractionation to obtain acetone soluble-HKL (AS-HKL). Then, C-HKL, AS-HKL, and softwood sodium lignosulfonate (LS) were used for the synthesis of technical lignin-based… More > Graphic Abstract

    Adhesion of Technical Lignin-Based Non-Isocyanate Polyurethane Adhesives for Wood Bonding

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