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  • Open Access

    ARTICLE

    Copolymerization of 5-[4-(methacryloylamino)phenyl]- l0,15, 20-triphenylporphyrin with Styrene: Investigation of Spectroscopic, Structural and Thermal Properties

    FEHMI SALTAN1,2, AYLIN PALAMUTLU2, HAKAN AKAT2,*

    Journal of Polymer Materials, Vol.36, No.2, pp. 133-147, 2019, DOI:10.32381/JPM.2019.36.02.3

    Abstract In this work, tetraphenylporphyrin (TPP) compound was first synthesized by the condensation reaction of pyrrole and benzaldehyde using Adler method. Then, the synthesized tetraphenylporphyrin was nitrated with sodium nitrite. Nitro-functionalized porphyrin (TPP-NO2 ) compound was reduced to amine-functional using ammonia and this amine- functionalized porphyrin was reacted with methacryloyl chloride to obtain porphyrin-derived radical monomer (TPP-MAO). Copolymer was synthesized with obtained porphyrin functional monomer and styrene by free radical polymerization method. Structural characterization and spectroscopic studies of the synthesized compounds were carried out by FTIR, H1 -NMR, UV spectroscopy. The molecular weight and thermal properties of the copolymer were determined… More >

  • Open Access

    ARTICLE

    Physical and Mechanical Properties of Eco-Friendly Composites Made from Wood Dust and Recycled Polystyrene

    Dafni Foti1, Eleni E. Voulgaridou1, Sotirios Karastergiou2, Hamid R. Taghiyari3, Antonios N. Papadopoulos1,*

    Journal of Renewable Materials, Vol.10, No.1, pp. 75-88, 2022, DOI:10.32604/jrm.2022.017759

    Abstract The development of alternative wood composites based on the use of waste or recycled materials can be beneficial due to over exploitation of natural resources. Under this frame, an option for the successful utilization of waste polystyrene which avoids environmental problems that formaldehyde adhesives cause and also reduces waste disposal, is its potential application as a binder for the production of value-added environmentally friendly and low cost wood composites. Two types of panel were successfully made, consisting of wood dust and two recycled polystyrene contents, namely, 15% and 30%. Both physical properties, water absorption and thickness swelling, and mechanical properties,… More > Graphic Abstract

    Physical and Mechanical Properties of Eco-Friendly Composites Made from Wood Dust and Recycled Polystyrene

  • Open Access

    ARTICLE

    Water Repellency of Cellulosic Fibrous Mats Impregnated with Organic Solutions Based on Recycled Polystyrene

    Dafni Foti1, Costas Passialis1, Elias Voulgaridis1, Stergios Adamopoulos2,*

    Journal of Renewable Materials, Vol.9, No.1, pp. 85-96, 2021, DOI:10.32604/jrm.2021.011868

    Abstract Recycled polystyrene in combination with paraffin wax, alkyd resin, and gum rosin were used as components in formulations to investigate their water repellency when applied to cellulosic filter paper substrates. Polystyrene was used in concentration of 5, 10, 15 and 20%, alkyd resin and gum rosin of 5% each and paraffin wax of 0.5%. Totally, twenty four water repellent solutions were prepared. Water repellency was evaluated in terms of water absorption of the cellulosic fibrous mats. The relations between retention of solid substances of the formulations and grammage and water absorption of filter paper samples were also determined. The results… More >

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