RAVI KUMAR, VISHWA PRATAP SINGH, MADHUKAR PRAJAPATI, ASHWITH, PRIYANKA SINGH, SATYAJIT SAMANTA, SAIKAT BANERJEE^*

Journal of Polymer Materials, Vol.36, No.4, pp. 323-335, 2019, DOI:10.32381/JPM.2019.36.04.3

Abstract Types of nucleating agents and their dosage level play an important role on the crystallinity of the polymer which controls the final properties like optical clarity, stiffness and reduced cycle time during molding. In this study, the efficiency of two different types of commercially available nucleating agents, phosphate ester and dicarboxylic acid based, have been studied. Both the nucleating agents were compounded with molding grade polypropylene homopolymer having melt flow index (MFI) of 12 g/10min at 2.16 Kg and 230°C, in a co-rotating twin screw extruder at two different dosage level, i.e. 300 ppm and 600 ppm. The effectiveness of… More >

XIAOYAN LIU^a,*, XU CHEN^a, HONGXING ZHANG^b, CHANGJUN ZHANG^a, SHIYUAN YANG^a, GUANGQUAN LI^a

Journal of Polymer Materials, Vol.36, No.2, pp. 121-132, 2019, DOI:10.32381/JPM.2019.36.02.2

Abstract In this work, three in situ impact polypropylene copolymer(IPC) samples were prepared through Ziegler-Natta catalyst only changing the feed composition (ethylene to ethylene and propylene molar ratio, C2/C2+C3) in gas-phase polymerization reactor. Polymer (IPC) were characterical by solvent classification, gel permeation chromatography (GPC), differential scanning calorimetry (DSC), successive self-nucleation and annealing (SSA), nuclear magnetic resonance(13C-NMR) and scanning electron microscopy(SEM). The mechanical properties of IPC samples were tested.The results indicate that with similar ethylene content, the feed composition which determines the content and structure of EPR and EbP component in IPC, further impacts the rubber phase size and distribution in IPC,… More >

ASIS K. MANDAL¹, DEBABRATA CHAKRABORTY², MAHUYA DAS³, SAMIR K SIDDHANTA^4,*

Journal of Polymer Materials, Vol.38, No.1-2, pp. 21-34, 2021, DOI:10.32381/JPM.2021.38.1-2.3

Abstract Elastomeric chlorosulfonated polyethylene (Hypalon) and thermoplastic polypropylene (PP) based thermoplastic Vulcanizates (TPVs) were prepared in presence of different doses of partial methyl ester of styrene-maleic anhydride copolymer (PMES-MA) as compatibilizer employing dynamic vulcanization technique. The mechanical analysis of the prepared TPVs exhibited significant improvements in stress at 25% modulus, ultimate tensile strength (UTS), and hardness values. FTIR studies revealed that a chemical interaction had taken place between hypalon and compatibilizer during the process of dynamic vulcanization which led to an enhancement of interfacial adhesion between them. The two-phase morphologies were clearly observed by scanning electron microscopic studies. The Tg values… More >

SHOGO TAKASUKA^1,*, TATSUHIRO TAKAHASHI¹

Journal of Polymer Materials, Vol.38, No.1-2, pp. 1-10, 2021, DOI:10.32381/JPM.2021.38.1-2.1

Abstract The effects of compounds containing oxazoline groups and the presence of maleic anhydridegrafted polypropylene (PP-g-MAH) on the spectral, morphological, and tensile properties of polypropylene (PP)/liquid crystalline polymer (LCP) blends were investigated. A wholly aromatic LCP having a low melting point which was copolyester, namely AL-7000 have been used, because thermal decomposition of PP and compatibilizer must be prevented.Compression molding was selected as the molding method because it allows molding with a small amount of sample. The binary blends of PP and LCP showed a degradation of tensile properties compared to pure PP. However, the addition of 2,2'-bis(2-oxazoline) and PP-g-MAH as… More >

MINGYU HE¹, AMATJAN SAWUT¹, LI GUAN², YING LI¹, MAMATJAN YIMIT²

Journal of Polymer Materials, Vol.38, No.3-4, pp. 191-203, 2021, DOI:10.32381/JPM.2021.38.3-4.2

Abstract The weathering performance of polypropylene (PP) was studied in an artificial accelerated weathering chamber of 340 nm ultraviolet light and natural conditions in Turpan, China. This work aimed to provide a method for calculating the aging failure of PP under natural conditions by the means of artificial accelerated aging. SEM showed that large crack widths of approximately 1.25 µm and 1.63 µm appealed on the PP surface after 15 days artificial accelerated aging and 150 days natural aging, respectively. XPS data revealed that the number of C-O and C=O bonds on the PP surface were generally the same after artificial… More >

Jakkid Sanetuntikul¹, Borwon Narupai², Nawadon Petchwattana^3,*

Journal of Renewable Materials, Vol.11, No.9, pp. 3567-3582, 2023, DOI:10.32604/jrm.2023.029308

Abstract Wastes from polypropylene (PP) packages are accumulating every year because it is one of the most widely consumed and short lifecycle products. This paper aims to develop low thermal conductive and fire-retardant materials from post-consumer PP (pPP) packages. Ammonium polyphosphate (APP) and hollow glass microsphere (HGM) were further added to improve the fire retardancy and thermal conductivity of pPP. The influence of APP and HGM on the mechanical and thermal properties, fire retardancy and thermal conductivity of pPP were investigated and compared with that of virgin PP (vPP). HGM was constantly added at 5 wt% while the content of APP… More > Graphic Abstract

Yongdong Yan^*, Youdong Si, Chunhua Lu, Keke Wu

Structural Durability & Health Monitoring, Vol.17, No.3, pp. 225-238, 2023, DOI:10.32604/sdhm.2022.022629

Abstract This research aims to investigate the effect of frost damage on chloride transportation mechanism in ordinary and fiber concrete with both theoretical and experimental methods. The proposed theoretical model takes into account the varying damage levels caused by concrete cover depth and freeze-thaw cycles, which are the two primary parameters affecting the expression of the chloride diffusion coefficient. In the experiment, three types of concrete were prepared: ordinary Portland concrete (OPC), polypropylene fiber concrete (PFC), and steel fiber concrete (SFC). These were then immersed in NaCl solution for 120 days after undergoing 10, 25, and 50 freeze-thaw cycles. The damage… More >

Wankui Ni¹, Jiaxin Zhong^1,2, Haiman Wang^1,*

Journal of Renewable Materials, Vol.11, No.4, pp. 1699-1814, 2023, DOI:10.32604/jrm.2022.023805

Abstract Fiber-reinforced soils have been of great interest to experimenters for building foundations’strength performance, time, and economy. This paper investigates the effects of water content and polypropylene fiber dosage and length on loess’s unconfined compressive strength (UCS) according to the central composite response surface design test procedure. The water content is 11%–25%, the mass ratio of fiber to soil is 0.1%–0.9%, and the fiber length ranges from 6–18 mm. The response surface method (RSM) developed full quadratic models of different variables with response values. After analysis of variance (ANOVA), the mathematical model developed in this study was statistically significant (p ≤… More > Graphic Abstract

Weeradech Kiratitanavit¹, Sethumadhavan Ravichandran²,Zhiyu Xia¹, Jayant Kumar^3,4, Ramaswamy Nagarajan^1,4,*

Journal of Renewable Materials, Vol.1, No.4, pp. 289-301, 2013, DOI:10.7569/JRM.2013.634126

Abstract Globally, certain types of halogenated fl ame retardant additives (FR) are becoming increasingly regulated or banned from being used in polymers. There is an immediate need for alternative non-toxic thermally stable polymers and char-forming additives. Development of non-halogenated FR for the commonly used and highly fl ammable thermoplastics, namely polyolefi ns, is particularly important and challenging. This research explores the possibility of utilizing char-forming compounds based on polymer of cardanol as an additive that can lower the heat release capacity (HRC) when blended with polypropylene (PP). Polycardanol is thermally stable and exhibits moderate HRC upon thermal decomposition and forms a… More >

Xiaoqing Zhang^*, Simon Schmidt^φ, Nick Rigopoulos, Januar Gotama, Eustathios Petinakis

Journal of Renewable Materials, Vol.3, No.2, pp. 91-100, 2015, DOI:10.7569/JRM.2014.634135

Abstract The behavior of a biodegradable CO₂ -based polymer polypropylene carbonate (PPC) as polymer matrix of wood fi ber (WF) composites was examined and compared with that of using poly(lactic acid) (PLA) as the matrix. The PPC/WF composites displayed poor mechanical properties as compared to PLA/WF composites because PPC is an amorphous polymer with low T_g and poor thermal stability. However, when PPC was used in conjunction with PLA in WF composites, the mechanical strength and modulus of the composites could match or even exceed the level of PLA/WF composites. The strong intermolecular interactions between PPC and WF and those between… More >