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    ARTICLE

    Halogen-Free Flame Retarded Poly(Lactic Acid) with an Isosorbide-Derived Polyphosphonate

    Wenwen Guo1,2,3, Wei Cai3, Dong Wang1, Junling Wang4, Xiefei Zhu5,*, Bin Fei2,*

    Journal of Renewable Materials, Vol.10, No.7, pp. 1875-1888, 2022, DOI:10.32604/jrm.2022.018823

    Abstract Fabrication of flame retardants from renewable biomass has aroused extensive interest over the past decade. This work reported a synthesis of isosorbide-derived polyphosphonate (PICPP) as an anti-flammable agent for poly (lactic acid) (PLA). The presence of PICPP notably declined the storage modulus of PLA/PICPP owing to the declined molecular weight of PLA catalyzed by the presence of PICPP. PLA and PLA/PICPP thermally degraded in one stage under either air or nitrogen atmosphere. With increasing the amount of PICPP, the onset thermal decomposition temperature of PLA/PICPP was decreased gradually, owing to the earlier decomposition of PICPP. With only 10 wt% of… More >

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