Jiling Song¹, Hua Wang^2,*, Jianbing Guo¹, Minghua Lin², Bin Zheng^2,*, Jiqiang Wu^3,*

Journal of Polymer Materials, Vol.42, No.4, pp. 1143-1157, 2025, DOI:10.32604/jpm.2025.073414 - 26 December 2025

Abstract The pursuit of safer energy storage systems is driving the development of advanced electrolytes for lithium-ion batteries. Traditional liquid electrolytes pose flammability risks, while solid-state alternatives often suffer from low ionic conductivity. Gel polymer electrolytes (GPEs) emerge as a promising compromise, combining the safety of solids with the ionic conductivity of liquids. Cellulose, an abundant and eco-friendly polymer, presents an ideal base material for sustainable GPEs due to its biocompatibility and mechanical strength. This study systematically investigates how drying methods affect cellulose-based GPEs. Cellulose hydrogels were synthesized through dissolution-crosslinking and processed using vacuum drying (VD),… More >

M. F. Aziz^1,2,*, A. A. Rahim¹, A. R. M. Rais^1,2,*

Journal of Polymer Materials, Vol.42, No.4, pp. 1097-1109, 2025, DOI:10.32604/jpm.2025.071129 - 26 December 2025

Abstract To study the behavior of structural dynamics, ionic conductivity and ion transport properties, the gel polymer electrolytes (GPEs) was developed using polyvinyl alcohol in combination with potassium iodide, dimethyl sulfoxide, ethylene carbonate, propylene carbonate and tetra-N-propylammonium iodide (C₁₂H₂₈IN), The GPEs were synthesized via a solution mixing technique, systematically varying the tetra-N-propylammonium iodide concentration to optimize ionic transport properties. The gel polymer electrolytes (GPEs) preparation was initially dissolving the potassium iodide and tetra-N-propylammonium iodide in a measured combination of ethylene carbonate, propylene carbonate, and dimethyl sulfoxide within a glass container. Subsequently, polyvinyl alcohol (PVA) was introduced into… More >

Nurrul Asyiqin Shamsuri¹, Zamil Khairuddin², Muhamad Hafiz Hamsan³, Norhana Abdul Halim⁴, Mohd Fakhrul Zamani Kadir^1,5, Muhammad Fadhlullah Shukur^6,7,*

Journal of Polymer Materials, Vol.42, No.3, pp. 729-742, 2025, DOI:10.32604/jpm.2025.069060 - 30 September 2025

Abstract Polymeric materials have emerged as a promising alternative to electrolytic solutions in energy storage applications. However, high crystallinity and poor ionic conductivity are the main barriers restricting their daily application. In this study, we propose a polymer electrolyte system consisting of methylcellulose-polyvinyl alcohol (MC-PVA) blend as host material and lithium trifluoromethanesulfonate (LiCF₃SO₃) as dopant, which was prepared using the solution-casting method. The electrochemical impedance spectroscopy (EIS) analysis revealed a maximum conductivity of 5.42 × 10⁻⁶ S cm⁻¹ with 40 wt.% LiCF₃SO₃. The key findings demonstrated that the variation in the dielectric loss (ε_i) and dielectric constant (ε_r) was… More >

M. A. H. Nizam¹, A. F. Fuzlin^1,2, A. S. Samsudin^1,2,*

Journal of Polymer Materials, Vol.42, No.1, pp. 173-185, 2025, DOI:10.32604/jpm.2025.059244 - 27 March 2025

Abstract This work explores the dielectric and electrochemical properties of solid biopolymer blend electrolytes (SBEs) based on a combination of alginate and polyvinyl alcohol (PVA), doped with varying concentrations of ammonium iodide (NH₄I). The SBEs were synthesized using the solution casting method, and their ac conductivity exhibited an optimal value of 1.01 × 10⁻⁵ S · cm⁻¹ at 25 wt.% NH₄I. Detailed dielectric and modulus spectroscopy analyses revealed distinctive trends in relation to NH₄I concentration, suggesting complex dielectric relaxation behavior. The universal power law (UPL) analysis identified the Small Polaron Hopping (SPH) mechanism as the dominant conduction process in More >

Christin Rina Ratri^1,2, Qolby Sabrina², Adam Febriyanto Nugraha¹, Sotya Astutiningsih¹, Mochamad Chalid^1,*

Journal of Renewable Materials, Vol.12, No.11, pp. 1863-1878, 2024, DOI:10.32604/jrm.2024.055492 - 22 November 2024

Abstract Commercial lithium-ion batteries (LIBs) use polyolefins as separators. This has led to increased research on separators composed of renewable materials such as cellulose and its derivatives. In this study, the ionic conductivity of cellulose acetate (CA) polymer electrolyte membranes was enhanced via plasticization with citric acid and succinonitrile. The primary objective of this study was to evaluate the effectiveness of these plasticizers in improving cellulose-based separator membranes in LIBs. CA membranes were fabricated using solution casting technique and then plasticized with various concentrations of plasticizers. The structural, thermal, and electrochemical properties of the resulting membranes… More > Graphic Abstract

ÇAĞLA GÜL GÜLDİKEN, LEVENT AKYALÇIN, HASAN FERDİ GERÇEL^*

Journal of Polymer Materials, Vol.36, No.4, pp. 337-349, 2019, DOI:10.32381/JPM.2019.36.04.4

Abstract In the present study, polybenzimidazole (PBI) polymer which has a great importance in polymer electrolyte membrane (PEM) research was synthesized via the solution polycondensation method, under various synthesis conditions to put forward the effect of the synthesis parameters on the properties of the synthesized polymer and consequently to the quality of the prepared polymer electrolyte membrane. The synthesized polymers were characterized in terms of their chemical structure, thermal degradation behaviour, and molecular weight by Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance spectroscopy (¹ H NMR), thermogravimetric analysis (TGA). The Mechanical properties, acid-doping level capacity, proton More >

Cheng-Hung San¹, Che-Wun Hong^1,2

CMC-Computers, Materials & Continua, Vol.23, No.2, pp. 101-118, 2011, DOI:10.3970/cmc.2011.023.101

Abstract Poly(ethylene oxide) (PEO) is a commonly used electrolytic polymer in lithium ion batteries because of its high viscosity which allows fabricating thin layers. However, its inherent low ionic conductivity must be enhanced by the addition of highly conductive salt additives. Also its weak mechanical strength needs a complementary block, such as poly(styrene) (PS), to strengthen the electrolytic membrane during charging/discharging processes. PS is a strong material to complement the PEO and to create a reinforced copolymer electrolyte termed as the poly(styrene-b-ethylene oxide) (PS-PEO). In this work, molecular dynamics simulations are employed to study the effects More >