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  • Open Access

    ARTICLE

    An Investigation into the Performances of Cement Mortar Incorporating Superabsorbent Polymer Synthesized with Kaolin

    Xiao Huang1,2, Jin Yang3,*

    FDMP-Fluid Dynamics & Materials Processing, Vol.20, No.6, pp. 1393-1406, 2024, DOI:10.32604/fdmp.2024.046360

    Abstract Cement-based materials are fundamental in the construction industry, and enhancing their properties is an ongoing challenge. The use of superabsorbent polymers (SAP) has gained significant attention as a possible way to improve the performance of cement-based materials due to their unique water-absorption and retention properties. This study investigates the multifaceted impact of kaolin intercalation-modified superabsorbent polymers (K-SAP) on the properties of cement mortar. The results show that K-SAP significantly affects the cement mortar’s rheological behavior, with distinct phases of water absorption and release, leading to changes in workability over time. Furthermore, K-SAP alters the hydration More >

  • Open Access

    ARTICLE

    Optimizing Hybrid Fibre-Reinforced Polymer Bars Design: A Machine Learning Approach

    Aneel Manan1, Pu Zhang1,*, Shoaib Ahmad2, Jawad Ahmad2

    Journal of Polymer Materials, Vol.41, No.1, pp. 15-44, 2024, DOI:10.32604/jpm.2024.053859

    Abstract Fiber-reinforced polymer (FRP) bars are gaining popularity as an alternative to steel reinforcement due to their advantages such as corrosion resistance and high strength-to-weight ratio. However, FRP has a lower modulus of elasticity compared to steel. Therefore, special attention is required in structural design to address deflection related issues and ensure ductile failure. This research explores the use of machine learning algorithms such as gene expression programming (GEP) to develop a simple and effective equation for predicting the elastic modulus of hybrid fiber-reinforced polymer (HFPR) bars. A comprehensive database of 125 experimental results of HFPR… More >

  • Open Access

    REVIEW

    Renewable Polymers in Biomedical Applications: From the Bench to the Market

    Rauany Cristina Lopes1, Tamires Nossa2, Wilton Rogério Lustri1, Gabriel Lombardo3,4,5, Maria Inés Errea3,4, Eliane Trovatti1,*

    Journal of Renewable Materials, Vol.12, No.4, pp. 643-666, 2024, DOI:10.32604/jrm.2024.048957

    Abstract Polymers from renewable resources have been used for a long time in biomedical applications and found an irreplaceable role in some of them. Their uses have been increasing because of their attractive properties, contributing to the improvement of life quality, mainly in drug release systems and in regenerative medicine. Formulations using natural polymer, nano and microscale particles preparation, composites, blends and chemical modification strategies have been used to improve their properties for clinical application. Although many studies have been carried out with these natural polymers, the way to reach the market is long and only More >

  • Open Access

    REVIEW

    Overview of Jute Fibre as Thermoplastic Matrix Polymer Reinforcement

    Tezara Cionita1,*, Mohammad Hazim Mohamad Hamdan2, Januar Parlaungan Siregar3,4,*, Deni Fajar Fitriyana5, Ramli Junid6, Wong Ling Shing7, Jamiluddin Jaafar8, Agustinus Purna Irawan9, Teuku Rihayat10, Rifky Ismail11, Athanasius Priharyoto Bayuseno11, Emilianus Jehadus12

    Journal of Renewable Materials, Vol.12, No.3, pp. 457-483, 2024, DOI:10.32604/jrm.2024.045814

    Abstract Recent decades have seen a substantial increase in interest in research on natural fibres that is aligned with sustainable development goals (SDGs). Due to their renewable resources and biodegradability, natural fiber-reinforced composites have been investigated as a sustainable alternative to synthetic materials to reduce the usage of hazardous waste and environmental pollution. Among the natural fibre, jute fibre obtained from a bast plant has an increasing trend in the application, especially as a reinforcement material. Numerous research works have been performed on jute fibre with regard to reinforced thermoset and thermoplastic composites. Nevertheless, current demands More >

  • Open Access

    ARTICLE

    Effect of Synthesis Parameters on Phosphoric Acid Doped Polybenzimidazole Membranes: A Parametric Evaluation from Microstructural Level to Fuel Cell Performance

    ÇAĞLA GÜL GÜLDİKEN, LEVENT AKYALÇIN, HASAN FERDİ GERÇEL*

    Journal of Polymer Materials, Vol.36, No.4, pp. 337-349, 2019, DOI:10.32381/JPM.2019.36.04.4

    Abstract In the present study, polybenzimidazole (PBI) polymer which has a great importance in polymer electrolyte membrane (PEM) research was synthesized via the solution polycondensation method, under various synthesis conditions to put forward the effect of the synthesis parameters on the properties of the synthesized polymer and consequently to the quality of the prepared polymer electrolyte membrane. The synthesized polymers were characterized in terms of their chemical structure, thermal degradation behaviour, and molecular weight by Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance spectroscopy (1 H NMR), thermogravimetric analysis (TGA). The Mechanical properties, acid-doping level capacity, proton More >

  • Open Access

    ARTICLE

    Performance Evaluation of Nucleating Agents in Polypropylene Homopolymer

    RAVI KUMAR, VISHWA PRATAP SINGH, MADHUKAR PRAJAPATI, ASHWITH, PRIYANKA SINGH, SATYAJIT SAMANTA, SAIKAT BANERJEE*

    Journal of Polymer Materials, Vol.36, No.4, pp. 323-335, 2019, DOI:10.32381/JPM.2019.36.04.3

    Abstract Types of nucleating agents and their dosage level play an important role on the crystallinity of the polymer which controls the final properties like optical clarity, stiffness and reduced cycle time during molding. In this study, the efficiency of two different types of commercially available nucleating agents, phosphate ester and dicarboxylic acid based, have been studied. Both the nucleating agents were compounded with molding grade polypropylene homopolymer having melt flow index (MFI) of 12 g/10min at 2.16 Kg and 230°C, in a co-rotating twin screw extruder at two different dosage level, i.e. 300 ppm and… More >

  • Open Access

    ARTICLE

    Synthesis of Functional Photoactive Polysilane Copolymers with Disperse Yellow 7 Methacrylate and Study of their Optical, Photophysical and Thermal Properties

    KM. MEENU, DIBYENDU S. BAG*, REKHA LAGARKHAa

    Journal of Polymer Materials, Vol.36, No.3, pp. 275-292, 2019, DOI:10.32381/JPM.2019.36.03.7

    Abstract Functional photoactive polysilane copolymers of poly(methylphenylsilane) (PMPS) and disperse yellow 7 methacrylate (DY7MA) were synthesized using UV-technique. In the same manner functional polysilane copolymers of poly(methylphenylsilane-co-dimethylsilane) (CPS) and disperse yellow 7 methacrylate (DY7MA) were also synthesized. By the UV irradiation polysilanes (PMPS and CPS) give rise to silyl macroradicals which initiate the polymerization of photoactive monomer (DY7MA). The synthesized samples were characterized by FTIR, NMR, and UV-Vis spectroscopy. The molar mass of synthesized photoactive functional polysilane copolymers is of order of 103 gm/mol. They exhibited multimodal optical and photoluminescence functional properties. Optical absorbance was observed… More >

  • Open Access

    ARTICLE

    Fabrication of Microspherical Catalyst with Hierarchical Porous Structure from Functional Monomers via Low-Temperature Phase-Separation Photopolymerization

    KEMIN WANG, LIFEI HE

    Journal of Polymer Materials, Vol.36, No.3, pp. 253-260, 2019, DOI:10.32381/JPM.2019.36.03.5

    Abstract This study proposes a simple approach for the fabrication of microspherical catalysts with a hierarchical porous structure. The cross-linked porous microspheres with catalytic ability were prepared directly from small-molecular monomers via low-temperature phase-separation photopolymerization of water/oil suspension. The morphology, pore size, chemical structure, and thermal stability of the obtained porous microspheres were characterized by SEM, Mercury Intrusion Porosimetry, FTIR, and TGA. The porous microspheres directly served as an acid catalyst for the condensation reaction of benzaldehyde and ethylene glycol, which exhibited superior catalytic activity and recyclability. The results indicated that such porous microspheres have great More >

  • Open Access

    ARTICLE

    Novel Sugar Based Acrylate: Synthesis, Characterization and Polymerization

    MERYEM KORUYUCUa, FEHMi SALTANa,b, GÖKHAN KÖKa, HAKAN AKATa, YEŞIM SALMANa,*

    Journal of Polymer Materials, Vol.36, No.3, pp. 207-216, 2019, DOI:10.32381/JPM.2019.36.03.1

    Abstract The present study has demonstrated that novel acrylic glycopolymers are successfully prepared by using monosaccharides containing an acrylate group (9-12). For this purpose, sugar based acrylate monomers were synthesized via ring opening method (Method B) and homopolymerization of this sugar oxypropylacrylates was performed using free radical polymerization. The characterization of all the monomers and polymers were verified by 1HNMR, 13CNMR, FTIR and GPC techniques. The Glass transition temperatures and thermal characteristics of the polymers were also analyzed by using DSC and TG techniques. The thermal stability of prepared polymers have changed with the stereochemistry of the More >

  • Open Access

    REVIEW

    Recent Advancement in Comb-like Polymers: A Review

    AMRITA SHARMA, P. P. PANDE

    Journal of Polymer Materials, Vol.36, No.2, pp. 175-194, 2019, DOI:10.32381/JPM.2019.36.02.6

    Abstract ‘Comb-like polymers’ are a special class of polymers. These are consisting of two types of chains, first one is the backbone chain and second is long side chains. The structure of such a polymer is very similar to hair comb. Usually, every monomer unit in the backbone has a long n-alkyl side chain. Comb like polymers have an intrinsic ability towards forming ordered structure. Now-a-days, these polymers find wide range of applications because of their excellent physicochemical properties. Some applications are in preparation of polysoaps (polymeric disinfectants), as dispersing agent for ink and paints, textile More >

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