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  • Open Access

    ARTICLE

    Impregnated Paper-Based Decorative Laminates Prepared from Lignin-Substituted Phenolic Resins

    Marion Thébault1, Ya Li1, Christopher Beuc1, Stephan Frömel-Frybort1,2, Edith-Martha Zikulnig-Rusch1, Larysa Kutuzova3, Andreas Kandelbauer3,*

    Journal of Renewable Materials, Vol.8, No.10, pp. 1181-1198, 2020, DOI:10.32604/jrm.2020.09755 - 31 August 2020

    Abstract High Pressure Laminates (HPL) panels consist of stacks of self-gluing paper sheets soaked with phenol-formaldehyde (PF) resins. An important requirement for such PFs is that they must rapidly penetrate and saturate the paper pores. Partially substituting phenol with bio-based phenolic chemicals like lignin changes the physico-chemical properties of the resin and affects its ability to penetrate the paper. In this study, PF formulations containing different proportions of lignosulfonate and kraft lignin were used to prepare paper-based laminates. The penetration of a Kraft paper sheet was characterized by a recently introduced, new device measuring the conductivity… More >

  • Open Access

    ARTICLE

    Effect of Phenolation, Lignin-Type and Degree of Substitution on the Properties of Lignin-Modified Phenol-Formaldehyde Impregnation Resins: Molecular Weight Distribution, Wetting Behavior, Rheological Properties and Thermal Curing Profiles

    Marion Thébault1, Larysa Kutuzova2, Sandra Jury1, Iris Eicher1, Edith-Martha Zikulnig-Rusch1, Andreas Kandelbauer2,*

    Journal of Renewable Materials, Vol.8, No.6, pp. 603-630, 2020, DOI:10.32604/jrm.2020.09616 - 12 May 2020

    Abstract Here, the effects of substituting portions of fossil-based phenol in phenol formaldehyde resin by renewable lignin from two different sources are investigated using a factorial screening experimental design. Among the resins consumed by the wood-based industry, phenolics are one of the most important types used for impregnation, coating or gluing purposes. They are prepared by condensing phenol with formaldehyde (PF). One major use of PF is as matrix polymer for decorative laminates in exterior cladding and wet-room applications. Important requirements for such PFs are favorable flow properties (low viscosity), rapid curing behavior (high reactivity) and… More >

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