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  • Open Access

    ARTICLE

    Properties of Activated Carbons from Sugarcane Leaves and Rice Straw Derived Charcoals by Activation at Low Temperature via KMnO4 Pre-Oxidation-Hydrolysis

    Sumrit Mopoung*, Narissara Namkaew, Sasiwan Srikasaem

    Journal of Renewable Materials, Vol.12, No.8, pp. 1433-1454, 2024, DOI:10.32604/jrm.2024.052925 - 06 September 2024

    Abstract Activated carbon preparation from sugarcane leaves and rice straw by carbonization (250°C–400°C) and activation at 500°C were studied. The effects of pre-oxidation, hydrolysis of derived charcoals by boiled KMnO4 aqueous solution were evaluated. The derived charcoals products were pretreated using oxidation-hydrolysis with 1–5 wt.% KMnO4 at 100°C and then activated at 500°C. The derived charcoal and activated carbon products were characterized by FTIR, XRD, SEM-EDS and BET. Iodine number and methylene blue number of derived products were also used for the analysis of the products. It was found that fabricated charcoal materials made at 350°C–400°C possess… More > Graphic Abstract

    Properties of Activated Carbons from Sugarcane Leaves and Rice Straw Derived Charcoals by Activation at Low Temperature via KMnO<sub>4</sub> Pre-Oxidation-Hydrolysis

  • Open Access

    ARTICLE

    Orientation on the Mechanistics of Electron-Transfer on Oxidation of Chondroitin-4-Sulfate as Sustainable Sulfated Polysaccharide by Permanganate Ion in Aqueous Perchlorate Solutions

    Refat Hassan1,*, Hideo Takagi2, Samia Ibrahim3

    Journal of Renewable Materials, Vol.8, No.2, pp. 205-218, 2020, DOI:10.32604/jrm.2020.08530 - 01 February 2020

    Abstract A spectrophotometric investigation of oxidation of chondroitin-4-sulfate (CS) as a sustainable and biodegradable sulfated macromolecule by oxyanion permanganate ion as multi-equivalent oxidant in acid perchlorate solutions at a constant ionic strength of 2.0 mol dm-3 has been studied. The experimental results on the influence of the concentration of the reactants the reaction rates revealed first-order dependence in MnO4 , fractional second-order in [CS] and fractional first-order with respect to the hydrogen ion concentration. The hydrogen acid concentration dependence of the rate constants indicated that the oxidation rates were increased with increasing the acid concentration which means… More >

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