Chaodong Liu, Yutong Yang, Boyu Cui, Weihong Wang^*

Journal of Renewable Materials, Vol.10, No.11, pp. 2961-2972, 2022, DOI:10.32604/jrm.2022.019761 - 29 June 2022

Abstract Microfibrillated cellulose (MFC) is often added to polylactic acid (PLA) matrixes as a reinforcing filler to obtain fully-biodegradable composites with improved mechanical properties. However, the incompatibility between MFC and the PLA matrix limits the mechanical performance of MFC-reinforced PLA composites. In this paper, DL-lactic acid-grafted-MFC (MFC-g-DL) was used to improve the compatibility with PLA. Reinforced composites were prepared by melt extrusion and hot-cold pressing. The tensile strength of the PLA/MFC-g-DL composite increased by 22.1% compared with that of PLA after adding 1% MFC-g-DL. Scanning electron microscopy (SEM), differential scanning calorimetry (DSC), and dynamic thermomechanical analysis (DMA) were… More > Graphic Abstract

Dzun Noraini Jimat^*, Sharifah Shahira Syed Putra, Parveen Jamal, Wan Mohd Fazli Wan Nawawi, Mohammed Saedi Jami

Journal of Renewable Materials, Vol.8, No.7, pp. 739-757, 2020, DOI:10.32604/jrm.2020.010357 - 01 June 2020

Abstract Increasing usage of foams in various industry sectors had causing serious disposal problems once it reaches the end of its life-cycle. Herein, PVA-MFC foam was prepared by freeze-drying using polyvinyl alcohol (PVA) and microfibrillated cellulose (MFC) as a reinforced material from sugarcane bagasse (SCB). In this study, the PVA-MFC foam was chemically silylated with Y-methacryloxypropyltrimethoxysilane (MPS) and tetraethoxysilane (TEOS). The wetting ability and mechanical strength of the silylated _2,20PVA-MFC foam was greatly enhanced compared with unmodified _2,20PVA-MFC foam. The silane chemicals (MPS and TEOS) had been confirmed grafted on _2,20PVA-MFC foam due to the presence of Si-C… More >

Rafael Grande^1*, Eliane Trovatti², Maria Tereza B. Pimenta³, Antonio J. F. Carvalho¹

Journal of Renewable Materials, Vol.6, No.2, pp. 195-202, 2018, DOI:10.7569/JRM.2018.634109

Abstract Research involving the preparation of microfibrillated cellulose (MFC) from sugarcane bagasse is a relevant topic to the production of new nanomaterials and more accessible cellulose substrates for the production of second generation ethanol. Regarding the transformation of cellulose into glucose, the precursor of second generation ethanol, this nanosized cellulosic substrate represents a more appropriate material for the chemical hydrolysis process. The high aspect ratio of MFC improves hydrolysis, requiring mild conditions and decreasing the generation of by-products. Here, MFC was prepared from sugarcane bagasse by ultrasound defibrillation. This material was oxidized with 2,2,6,6-tetramethylpiperidine-N-oxyl (TEMPO) to More >