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  • Open Access

    ARTICLE

    Synthesis of Lignin-Based Polyacid in an Acidic Ionic Liquid: A Green Method to Improve the Performance of Lignin as Catalyst in Urea-Formaldehyde Resin

    Hamed Younesi-Kordkheili1,*, Antonio Pizzi2

    Journal of Renewable Materials, Vol.10, No.2, pp. 237-246, 2022, DOI:10.32604/jrm.2022.017851 - 30 August 2021

    Abstract The aim of this research was to investigate the effect of ionic liquid treated lignin-based polyacid as a catalyst for urea-formaldehyde (UF) resins. Esterification of lignin was carried out, without any catalyst, with anhydride maleic and 1-butyl-3-methylimidazolium hydrogen sulfate [Bmim][HSO4] as acidic ionic liquid to form maleated lignin-based polyacids (MA-IL). The performance of MA-IL as UF resin catalyst was respectively compared to hyroxymethylated lignin-based polyacid (MA-HL) and to NH4Cl. The FTIR analysis indicated that the proportion of -COOH and C-O bonds increased due to the esterification of lignin with ionic liquid rather than its hyroxymethylation. Physicochemical… More >

  • Open Access

    ARTICLE

    Revalorisation of Posidonia Oceanica as Reinforcement in Polyethylene/Maleic Anhydride Grafted Polyethylene Composites

    D. Puglia*, R. Petrucci, E. Fortunati, F. Luzi, J.M. Kenny, L. Torre

    Journal of Renewable Materials, Vol.2, No.1, pp. 66-76, 2014, DOI:10.7569/JRM.2013.634134

    Abstract Posidonia Oceanica waste was used as reinforcement in a polyethylene matrix and the obtained composites were characterised by a tensile test and morphological analysis. The fi brous material derived from P. Oceanica wastes was characterised by morphological, thermal and chemical analysis, and a subsequent treatment with sodium hydroxide (NaOH) at different weight content (2, 5 and 10 wt%) was considered as an optimised method for surface modifi cation of pristine fi bres (PO). The TGA analysis and morphological investigation of the treated fi bres selected the 5 wt% of NaOH as the best treatment. Matrix compatibilisation with More >

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