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  • Open Access

    ARTICLE

    Fluid-Related Performances and Compressive Strength of Clinker-Free Cementitious Backfill Material Based on Phosphate Tailings

    Jin Yang1,2, Senye Liu1, Xingyang He1,2,*, Ying Su1,2, Jingyi Zeng2, Bohumír Strnadel1,3

    FDMP-Fluid Dynamics & Materials Processing, Vol.20, No.9, pp. 2077-2090, 2024, DOI:10.32604/fdmp.2024.050360 - 23 August 2024

    Abstract Phosphate tailings are usually used as backfill material in order to recycle tailings resources. This study considers the effect of the mix proportions of clinker-free binders on the fluidity, compressive strength and other key performances of cementitious backfill materials based on phosphate tailings. In particular, three solid wastes, phosphogypsum (PG), semi-aqueous phosphogypsum (HPG) and calcium carbide slag (CS), were selected to activate wet ground granulated blast furnace slag (WGGBS) and three different phosphate tailings backfill materials were prepared. Fluidity, rheology, settling ratio, compressive strength, water resistance and ion leaching behavior of backfill materials were determined.… More > Graphic Abstract

    Fluid-Related Performances and Compressive Strength of Clinker-Free Cementitious Backfill Material Based on Phosphate Tailings

  • Open Access

    ARTICLE

    Preparation and Performance of Ternesite-Ye’Elimite Clinker Produced from Steel Slag at Lower Temperature

    Zhengyang Li1, Wei Guo1,*, Yueyang Hu1, Xiao Wang1, Binbin Qian2, Cuifeng Jiang1

    Journal of Renewable Materials, Vol.10, No.11, pp. 2921-2935, 2022, DOI:10.32604/jrm.2022.019258 - 29 June 2022

    Abstract Ternesite (4CaO·2SiO2·CaSO4)-Ye’elimite (3CaO·3Al2O3·CaSO4) (simplified as TY) cement clinker was successfully prepared from steel slag at 1200°C in this study. XRD, TG/DSC and SEM were used to analyze the mineral composition and hydration products of the TY clinker. The sintering process and hydration mechanism of the TY clinker were investigated. Results show that a large amount of ternesite and ye’elimite have been formed at 1200°C, while ternesite has not been decomposed. Clinker minerals include ternesite, ye’elimite, gypsum and a small amount of iron phase. Iron phase from steel slag can promote the formation of liquid phase with More >

  • Open Access

    ARTICLE

    Assisted Compatibility, and Balanced Regulation of the Mechanical, Thermal, and Antioxidant Activity of Polyvinyl Alcohol-Chinese Bayberry Tannin Extract Films Using Different Di-Aldehydes as Cross-Linkers

    Jingjing Liao1,2, Jinxing Li2, Fuxian Yang2, Yan Zhu2, Hongyan Wang3, Guanben Du1,2,*, Hisham Essawy4, Xiaojian Zhou2,*

    Journal of Renewable Materials, Vol.10, No.2, pp. 359-372, 2022, DOI:10.32604/jrm.2021.016335 - 30 August 2021

    Abstract Polyvinyl alcohol (PVA)-based films containing Chinese bayberry tannin (BT) were prepared by cross-linking using glyoxal, glutaraldehyde and dialdehyde starch, individually. The presence of cross-linkers was evident to promote the transparency and decrease the moisture content of PVA/BT films, while the water solubility stayed almost unchanged in the cross-linked PVA/BT films. All cross-linkers provided promotion of the water vapor permeability, mechanical property and thermal stability of PVA/BT films. The best water vapor barrier capacity was found in case of glutaraldehyde cross-linked PVA/BT film, while the highest tensile strength was encountered in case of glyoxal cross-linked PVA/BT More > Graphic Abstract

    Assisted Compatibility, and Balanced Regulation of the Mechanical, Thermal, and Antioxidant Activity of Polyvinyl Alcohol-Chinese Bayberry Tannin Extract Films Using Different Di-Aldehydes as Cross-Linkers

  • Open Access

    ARTICLE

    Utilization of Bayer Red Mud Derived from Bauxite for Belite-Ferroaluminate Cement Production

    Yanrong Zhao1,2,3,#, Ping Chen1,4,*,#, Shifeng Wang5, Yaxiong Ji3,4, Yuanhao Wang3,4,*, Bolin Wu1,2, Rongjin Liu1

    Journal of Renewable Materials, Vol.8, No.11, pp. 1531-1541, 2020, DOI:10.32604/jrm.2020.011462 - 28 September 2020

    Abstract Bayer red mud (BRM) is a kind of industrial solid waste characterized by huge volume and high alkalinity. Its disposal generates serious environmental pollution and occupies a large number of farmland. The utilization and recycling of BRM is currently a crucial issue and needs to be addressed as soon as possible. The chemical composition of BRM is similar to cement clinker. In this study, the feasibility of preparing Belite-ferroaluminate clinker (BFAC) with different BRM was explored. The physical properties, mechanics performance, radioactivity levels and trace harmful metals leaching were measured. XRD, BEI and EDS were… More >

  • Open Access

    ARTICLE

    Preparation and Properties of Guiqi Polysaccharides/Chitosan/Alginate Composite Hydrogel Microspheres

    Xiaoliang Zhao1,#, Yuting Wang1,#, Xiuying Pu1, Jianzhong Ma1, Feifan Leng1, Yonggang Wang1, Yanling Wang1, Shuhong Yang1, Fen Ran2, Weijie Zhang1,*

    Journal of Renewable Materials, Vol.7, No.12, pp. 1321-1332, 2019, DOI:10.32604/jrm.2019.07757

    Abstract A series of the Guiqi polysaccharides/chitosan/alginate composite hydrogel microspheres (GPcM) with different particle sizes were prepared with Guiqi polysaccharides (GP), chitosan (CS) and sodium alginate (Alg). The optimum preparation process was also determined by single factor and orthogonal experiment analysis. The GPcM were characterized by fourier transform infrared spectroscopy (FT-IR), scanning electron microscope (SEM), drug loading efficiency test (LE), encapsulation efficiency test (EE) and in vitro release study. The results showed that the Guiqi polysaccharides chitosan hydrogel (GPCH) and sodium alginate hydrogel (SAH) formed a crossover system in GPcM. The GPcM have a uniform particle More >

  • Open Access

    ABSTRACT

    Microspheres Modified with the Heparin Increasing the Length of Molecular Linker to Better Capture the Endotoxin

    Qi Dang1, Chun-Gong Li1, Xin-Xin Jin1, Ya-Jin Zhao1, Xiang Wang1,*

    Molecular & Cellular Biomechanics, Vol.16, Suppl.2, pp. 146-146, 2019, DOI:10.32604/mcb.2019.07074

    Abstract Endotoxin is a a very powerful and toxic inflammatory stimulator usually leading to the sepsis occurred. In order to remove endotoxin better through hemoperfusion, it is a pretty choice to increase the length of molecular linker on adsorbents. In this study, we chose the heparin as a molecular linker because of its being anticoagulant linear polysaccharide. Heparin as a linker was covalently immobilized on the chloromethylated polystyrene microspheres (Ps) and then connected with L-phenylalanine (Phe) forming the Ps-Hep-Phe structure to adsorbed endotoxin better. The property of microspheres was characterized by Fourier transform infrared spectroscopy, X-ray More >

  • Open Access

    ARTICLE

    Development of Cardanol-Based Polyol via Click Chemistry and Crosslinking with Melamine Formaldehyde Resin for Coating Applications

    Kunal Wazarkar, Anagha Sabnis*

    Journal of Renewable Materials, Vol.6, No.4, pp. 438-449, 2018, DOI:10.7569/JRM.2017.634159

    Abstract The research work presented in this article deals with the synthesis of cardanol-based polyol and its curing with hexabutoxymethyl melamine (HBMM) for application in coatings. Cardanol-based polyol was prepared via thiol-ene click reaction using thioglycerol. Unsaturation present in the long chain of cardanol was successfully utilized to synthesize polyol via thiol-ene coupling. The reaction was carried out between cardanol and thioglycerol in the presence of Irgacure 184 (photoinitiator) and 1,8-Diazabicyclo[5.4.0]undec-7-ene (catalyst) under UV light for 12 h at 80 °C. After completion of the reaction, one mole of thioglycerol was successfully added across the double More >

  • Open Access

    ARTICLE

    Renewable Resource-Based Hybrid Crosslinker for Sustainable Industrial Coatings

    Dinesh Balgude, Anagha Sabnis*

    Journal of Renewable Materials, Vol.2, No.3, pp. 235-245, 2014, DOI:10.7569/JRM.2014.634115

    Abstract Renewable resource-based hybrid crosslinker was successfully synthesized via sol-gel technology. The synthesis involved malenization of Cashew Nut Shell Liquid (CNSL) followed by its silane modifi cation and subsequent hydrolysis and condensation with tetraethyl orthosilicate (TEOS). The synthesized crosslinker was characterized by spectroscopic analysis (FT-IR, 1 H-NMR, 13C-NMR and 29Si-NMR) for structural elucidation. The crosslinker was further formulated in a conventional stoving system. Fully-cured coatings were obtained after stoving at 120°C for ½ hr and were then evaluated for physical, mechanical, chemical, optical, accelerated weathering, electrochemical and morphological properties. The incorporation of hybrid crosslinker in a conventional stoving More >

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