Xujing Zhang¹, Hatem Abushammala², Debora Puglia³, Binbao Lu¹, Pengwu Xu¹, Weijun Yang^1,*, Piming Ma¹

Journal of Renewable Materials, Vol.12, No.5, pp. 895-908, 2024, DOI:10.32604/jrm.2024.049810

Abstract Fluorescent nanomaterials have attracted much attention, due to their unique luminescent properties and promising applications in biomedical areas. In this study, lignin based fluorescent nanoparticles (LFNP) with high yield (up to 32.4%) were prepared from lignin nanoparticles (LNP) by one-pot hydrothermal method with ethylenediamine (EDA) and citric acid. Morphology and chemical structure of LFNP were investigated by SEM, FT-IR, and zeta potential, and it was found that the structure of LFNP changed with the increase of citric acid addition. LFNP showed the highest fluorescence intensity under UV excitation at wavelengths of 375–385 nm, with emission More > Graphic Abstract

Naglaa Salem El‑Sayed, Mohamed Hasanin, Samir Kamel^*

Journal of Renewable Materials, Vol.12, No.4, pp. 699-720, 2024, DOI:10.32604/jrm.2024.049118

Abstract In recent decades, the ozone layer has suffered considerable damage, increasing the entry of ultraviolet (UV) light into the atmosphere and reaching the earth’s surface, negatively affecting life. Accordingly, researchers aimed to solve this problem by synthesizing advanced UV-shielding materials. On the other hand, developing an easy and green strategy to prepare functional materials with outstanding properties based on naturally abundant and environmentally friendly raw materials is highly desirable for sustainable development. Because biomass-derived materials are sustainable and biodegradable, they present a promising substitute for petroleum-based polymers. The three main structural constituents of the plant More > Graphic Abstract

Rafidah Md Salim^1,2,*, Jahimin Asik², Mohd Sani Sarjadi²

Journal of Renewable Materials, Vol.12, No.4, pp. 737-769, 2024, DOI:10.32604/jrm.2024.045695

Abstract Lignin extraction from bark can maximize the utilization of biomass waste, offer cost-effectiveness, and promote environmental friendliness when employed as an adhesive material in bark particleboard production. Particles of fine (0.2 to 1.0 mm), medium (1.0 to 2.5 mm), and coarse (2.5 to 12.0 mm) sizes, derived from the bark of Leucaena leucocephala, were hot-pressed using a heating plate at 175°C for 7 min to create single-layer particleboards measuring 320 mm × 320 mm × 10 mm, targeting a density of 700 kg/m. Subsequently, the samples were trimmed and conditioned at 20°C and 65% relative humidity.… More > Graphic Abstract

CHUNYAN LIU^*, YUNHE LIU, ZIHAN PAN, QIUTING LI, HAN XU, TAO LIU

Journal of Polymer Materials, Vol.36, No.1, pp. 87-99, 2019, DOI:10.32381/JPM.2019.36.01.7

Abstract In this work, a series of novel lignin-based bis-benzoxazine monomers were efficiently synthesized by the reaction of renewable phenols: guaiacol, vanillyl alcohol, eugenol, vanillin with ethylene diamine and paraformaldehyde. The chemical structures of these lignin-based bis-benzoxazine monomers were confirmed by ¹H-NMR, ¹³C-NMR and FTIR, indicating the formation of benzoxazine ring. The obtained bis-benzoxazine monomers were cured via thermal treatment. The curing behavior of these lignin-based bis-benzoxazine monomers were compared and analyzed via differential scanning calorimetry (DSC), showing that Va-e possessed higher ring-opening polymerization activity than G-e, while E-e and V-e had lower curing activity than G-e. More >

Fatemeh Hassani Khorshidi¹, Saeed Kazemi Najafi¹, Farhood Najafi^2,*, Antonio Pizzi^3,*, Dick Sandberg⁴, Rabi Behrooz¹

Journal of Renewable Materials, Vol.12, No.2, pp. 305-323, 2024, DOI:10.32604/jrm.2023.043953

Abstract The purpose of this research study was to investigate the properties of polyurethane coatings based on lignin nano-particles. For this purpose, the prepared coatings were applied to pine wood surfaces and weathered artificially. Subsequently, color and gloss of the coatings were measured before and after the weathering test. Field emission scanning electron microscopy (FE-SEM) micrographs prepared from the coatings showed that the average size of nano-particles in the polyurethane substrate was approximately 500 nm. Nuclear magnetic resonance (¹³C-NMR) spectroscopy showed that strong urethane bonds were formed in the nano-lignin-based polyurethane. Differential calorimetric analysis (DSC) test revealed… More > Graphic Abstract

Jiapeng Wang¹, Bo Zhang^1,*, Haoqiang Cheng¹, Zhixiang Xu²

Journal of Renewable Materials, Vol.11, No.10, pp. 3595-3612, 2023, DOI:10.32604/jrm.2023.030005

Abstract A new method of pretreatment of corn straw with Phanerochaete chrysosporium combined with pyrolysis was proposed to improve the quality of bio-oil. The characterization results demonstrated that microbial pretreatment was an effective method to decrease the lignin, which can achieve a maximum removal rate of 44.19%. Due to the destruction of biomass structure, the content of alkali metal and alkaline earth metal is reduced. Meanwhile, the depolymerized biomass structure created better pyrolysis conditions to promote the pyrolysis efficiency, increase the average decomposition rate of pyrolysis and reduce the residue. In fast pyrolysis, because of the enrichment… More > Graphic Abstract

Wenjing Xia^1,*, JinHui Wang¹, Tao Xu¹, Nan Jiang²

Journal of Renewable Materials, Vol.11, No.8, pp. 3387-3402, 2023, DOI:10.32604/jrm.2023.026971

Abstract To understand the effects of filler-asphalt ratio on different properties of lignin and polyester fiber reinforced shape memory polyurethane (SMPU)/styrene butadiene styrene (SBS) composite modified asphalt mortar (PSAM), as well as to reveal the reinforcing and toughening mechanisms of lignin and polyester fibers on PSAM, SMPU, SBS and mineral powder were first utilized to prepare PSAM. Then the conventional, rheological and anticracking properties of lignin fiber reinforced PSAM (LFAM) and polyester fiber reinforced PSAM (PFAM) at different filler-asphalt ratios were characterized. Test results indicate that the shear strength, deformation resistance and viscosity are increased after… More > Graphic Abstract

Honghong Wang¹, Zhixin Xiong^1,*, Yunchao Hu¹, Zhijian Liu¹, Long Liang²

Journal of Renewable Materials, Vol.11, No.6, pp. 2713-2727, 2023, DOI:10.32604/jrm.2023.025817

Abstract This study aims to realize the sharing of near-infrared analysis models of lignin and holocellulose content in pulp wood on two different batches of spectrometers and proposes a combined algorithm of SPA-DS, MCUVE-DS and SiPLS-DS. The Successive Projection Algorithm (SPA), the Monte-Carlo of Uninformative Variable Elimination (MCUVE) and the Synergy Interval Partial Least Squares (SiPLS) algorithms are respectively used to reduce the adverse effects of redundant information in the transmission process of the full spectrum DS algorithm model. These three algorithms can improve model transfer accuracy and efficiency and reduce the manpower and material consumption… More >

Chengxiang Li, Yue Wu, Chunhui Zhang^*, Yao Liu, Qixuan Lin, Junli Ren^*

Journal of Renewable Materials, Vol.11, No.6, pp. 2555-2574, 2023, DOI:10.32604/jrm.2023.026908

Abstract Hemicellulose and lignin are not reasonably utilized during the dissolved pulp preparation process. This work aimed to propose a process for the co-production of dissolving pulp, furfural, and lignin from eucalyptus. High-grade dissolving pulp was prepared from eucalyptus using a combination of extremely low acid (ELA) pretreatment, Kraft cooking, and elementary chlorine-free (ECF) bleaching. The obtained pre-hydrolysate was catalytic conversion into furfural in a biphasic system, and lignin during Kraft cooking and ECF was recovered. The process condition was discussed as well as the mass flow direction. The results showed that ELA pretreatment could effectively… More >

Sri Hidayati^1,*, Eugenia Fonny Budiyanto¹, Hadi Saputra¹, Sutopo Hadi¹, Apri Heri Iswanto^2,3, Nissa Nurfajrin Solihat⁴, Petar Antov⁵, Lee Seng Hua^6,7, Widya Fatriasari^4,8, Mohd. Sapuan Salit⁹

Journal of Renewable Materials, Vol.11, No.6, pp. 2865-2879, 2023, DOI:10.32604/jrm.2023.027579

Abstract Black liquor is obtained as a by-product of the pulping process, which is used to convert biomass into pulp by removing lignin, hemicelluloses and other extractives from wood to free cellulose fibers. Lignin represents a major constituent in black liquor, with quantities varying from 20% to 30%, of which a very low share is used for manufacturing value-added products, while the rest is mainly burned for energy purposes, thus underestimating its great potential as a raw material. Therefore, it is essential to establish new isolation and extraction methods to increase lignin valorization in the development… More > Graphic Abstract