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    ARTICLE

    Self-Supported Nanoporous Gold with Gradient Tin Oxide for Sustainable and Efficient Hydrogen Evolution in Neutral Media

    Xianglong Lu1, Tianshui Yu1, Hailing Wang1, Ruichun Luo2, Pan Liu2, Songliu Yuan1, Lihua Qian1,*

    Journal of Renewable Materials, Vol.8, No.2, pp. 133-151, 2020, DOI:10.32604/jrm.2020.08650 - 01 February 2020

    Abstract Hydrogen evolution reaction (HER) in neutral medium suffers from slow kinetics as compared to that in alkaline or acidic conditions, owing to larger Ohmic loss and low proton concentration. Here we report that a self-supported nanoporous Au-SnOx (NP Au-SnOx) catalyst with gradient tin oxide surface could significantly enhance HER activity in neutral buffer solution (0.2 M PBS). The NP Au-SnOx catalyst exhibits a low onset overpotential of 38 mV and a small Tafel slope of 79 mV dec−1 . The current density of 10 mA cm−2 is manifested at an overpotential as low as 148 mV, representing the More >

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