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  • Open Access

    ARTICLE

    Schiff’s base of Fe3O4 @chitosan with 4,4'- diselenobisbenzaldehyde: Preparation, characterization and its catalytic activity for oxidation of sulphides

    RAFAT SABA*, MOHD. KASHIF AZIZ, GHULAM MUSTAFA, ARPIT SRIVASTAVA, SHEKHAR SRIVASTAVA*

    Journal of Polymer Materials, Vol.38, No.1-2, pp. 153-166, 2021, DOI:10.32381/JPM.2021.38.1-2.12

    Abstract We have synthesized Schiff’s base of Fe3 O4 @chitosan with 4,4'-diselenobisbenzaldehyde (Fe3O4 @CSSe) composite and used it as acatalyst for the oxidation of sulfides, having some advantageous properties such as eco-friendly, cost-effective and highly efficient magnetic biocatalyst of selenium. The synthesized schiff’s base was characterized by different physical characterization techniques such as Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), Vibrating sample magnetometer (VSM)and Dynamic light scattering (DLS). Further, we used the resulting schiff’s base as a catalyst in the presence of a green oxidant (H2 O2 ) to oxidize sulfides to corresponding sulfoxides at room temperature. It has been… More >

  • Open Access

    ARTICLE

    Bioinformatics analysis and experimental validation of cystathionine-gamma-lyase as a potential prognosis biomarker in hepatocellular carcinoma

    YANAN MA1, SHANSHAN WANG2,*, HUIGUO DING1,*

    BIOCELL, Vol.48, No.3, pp. 463-471, 2024, DOI:10.32604/biocell.2024.048244

    Abstract Background: Hepatocellular carcinoma (HCC) is a common malignant tumor with poor prognosis and high mortality worldwide. Although cystathionine-gamma-lyase (CSE) plays an important role in the development of multiple tumors, the clinical implication and potential mechanisms of CSE in HCC development remain elusive. Methods: In our study, the CSE expression in HCC was analyzed in Gene Expression Omnibus (GEO) and The Cancer Genome Atlas (TCGA) datasets and further confirmed by RT-qPCR and immunohistochemistry assays in HCC samples. Furthermore, the associations between CSE expression and HCC malignancy as well as survival were analyzed in GSE14520 and validated in HCC patients. Finally, the… More >

  • Open Access

    ARTICLE

    Optimal Operation Strategy of Electricity-Hydrogen Regional Energy System under Carbon-Electricity Market Trading

    Jingyu Li1,2, Mushui Wang1,2,*, Zhaoyuan Wu1,3, Guizhen Tian1,2, Na Zhang1,2, Guangchen Liu1,2

    Energy Engineering, Vol.121, No.3, pp. 619-641, 2024, DOI:10.32604/ee.2023.044862

    Abstract Given the “double carbon” objective and the drive toward low-carbon power, investigating the integration and interaction within the carbon-electricity market can enhance renewable energy utilization and facilitate energy conservation and emission reduction endeavors. However, further research is necessary to explore operational optimization methods for establishing a regional energy system using Power-to-Hydrogen (P2H) technology, focusing on participating in combined carbon-electricity market transactions. This study introduces an innovative Electro-Hydrogen Regional Energy System (EHRES) in this context. This system integrates renewable energy sources, a P2H system, cogeneration units, and energy storage devices. The core purpose of this integration is to optimize renewable energy… More > Graphic Abstract

    Optimal Operation Strategy of Electricity-Hydrogen Regional Energy System under Carbon-Electricity Market Trading

  • Open Access

    ARTICLE

    Low expression of fatty acid oxidation related gene ACADM indicates poor prognosis of renal clear cell carcinoma and is related to tumor immune infiltration

    JIECHUAN QIU1, TIANMIN YANG1, YANNING SUN2, KAI SUN2, YINGKUN XU3, QINGHUA XIA1,*

    Oncology Research, Vol.32, No.3, pp. 545-561, 2024, DOI:10.32604/or.2023.030462

    Abstract This research aims to identify the key fatty acid beta-oxidation (FAO) genes that are altered in kidney renal clear cell carcinoma (KIRC) and to analyze the role of these genes in KIRC. The Gene Expression Omnibus (GEO) and FAO datasets were used to identify these key genes. Wilcoxon rank sum test was used to assess the levels of acyl-CoA dehydrogenase medium chain (ACADM) between KIRC and non-cancer samples. The logistic regression and Wilcoxon rank sum test were used to explore the association between ACADM and clinical features. The diagnostic performance of ACADM for KIRC was assessed using a diagnostic receiver… More >

  • Open Access

    ARTICLE

    Hydrogen Permeation Characteristics of Pd-Cu Membrane in Plasma Membrane Reactor

    Muhd Hadi Iskandar Abd Razak*, Motoki Tsuda, Yukio Hayakawa, Shinji Kambara

    Energy Engineering, Vol.121, No.2, pp. 259-272, 2024, DOI:10.32604/ee.2023.043615

    Abstract Hydrogen is an alternative energy source that has the potential to replace fossil fuels. One of the hydrogen applications is as a material for Polymer Electrolyte Membrane Fuel Cells (PEMFC) in fuel cell vehicles. High-purity hydrogen can be obtained using a hydrogen separation membrane to prevent unwanted contaminants from potentially harming the PEMFC components. In this study, we fabricated a plasma membrane reactor and investigated the permeation performance of a hydrogen separation membrane in a plasma membrane reactor utilizing atmospheric pressure plasma. The result showed the hydrogen permeation rate increasing with time as reactor temperature is increased through joule heating.… More >

  • Open Access

    ARTICLE

    Modeling of Large-Scale Hydrogen Storage System Considering Capacity Attenuation and Analysis of Its Efficiency Characteristics

    Junhui Li1, Haotian Zhang1, Cuiping Li1,*, Xingxu Zhu1, Ruitong Liu2, Fangwei Duan2, Yongming Peng3

    Energy Engineering, Vol.121, No.2, pp. 291-313, 2024, DOI:10.32604/ee.2023.027593

    Abstract In the existing power system with a large-scale hydrogen storage system, there are problems such as low efficiency of electric-hydrogen-electricity conversion and single modeling of the hydrogen storage system. In order to improve the hydrogen utilization rate of hydrogen storage system in the process of participating in the power grid operation, and speed up the process of electric-hydrogen-electricity conversion. This article provides a detailed introduction to the mathematical and electrical models of various components of the hydrogen storage unit, and also establishes a charging and discharging efficiency model that considers the temperature and internal gas partial pressure of the hydrogen… More >

  • Open Access

    REVIEW

    Advanced Thermochemical Conversion Approaches for Green Hydrogen Production from Crop Residues

    Omojola Awogbemi*, Ayotunde Adigun Ojo, Samson Adedayo Adeleye

    Journal of Renewable Materials, Vol.12, No.1, pp. 1-28, 2024, DOI:10.32604/jrm.2023.045822

    Abstract The huge volumes of crop residues generated during the production, processing, and consumption of farm products constitute an ecological nuisance when ineffectively managed. The conversion of crop residues to green hydrogen is one of the sustainable management strategies for ubiquitous crop residues. Production of green hydrogen from crop residue sources will contribute to deepening access to clean and affordable energy, mitigating climate change, and ensuring environmental sustainability. However, the deployment of conventional thermochemical technologies for the conversion of crop residues to green hydrogen is costly, requires long residence time, produces low-quality products, and therefore needs to be upgraded. The current… More >

  • Open Access

    ARTICLE

    An Evidence-Based CoCoSo Framework with Double Hierarchy Linguistic Data for Viable Selection of Hydrogen Storage Methods

    Raghunathan Krishankumar1, Dhruva Sundararajan2, K. S. Ravichandran2, Edmundas Kazimieras Zavadskas3,*

    CMES-Computer Modeling in Engineering & Sciences, Vol.138, No.3, pp. 2845-2872, 2024, DOI:10.32604/cmes.2023.029438

    Abstract Hydrogen is the new age alternative energy source to combat energy demand and climate change. Storage of hydrogen is vital for a nation’s growth. Works of literature provide different methods for storing the produced hydrogen, and the rational selection of a viable method is crucial for promoting sustainability and green practices. Typically, hydrogen storage is associated with diverse sustainable and circular economy (SCE) criteria. As a result, the authors consider the situation a multi-criteria decision-making (MCDM) problem. Studies infer that previous models for hydrogen storage method (HSM) selection (i) do not consider preferences in the natural language form; (ii) weights… More >

  • Open Access

    ARTICLE

    EFFECT OF WALL THERMAL CONDUCTIVITY ON MICRO-SCALE COMBUSTION CHARACTERISTICS OF HYDROGEN-AIR MIXTURES WITH DETAILED CHEMICAL KINETIC MECHANISMS IN Pt/γ-Al2O3 CATALYTIC MICRO-COMBUSTORS

    Junjie Chen*, Longfei Yan, Wenya Song

    Frontiers in Heat and Mass Transfer, Vol.5, pp. 1-6, 2014, DOI:10.5098/hmt.5.16

    Abstract To understand the effect of different thermal conductivities on catalytic combustion characteristics, effect of thermal conductivity on micro-combustion characteristics of hydrogen-air mixtures in Pt/γ-Al2O3 catalytic micro-combustors were investigated numerically with detailed chemical kinetics mechanisms. Three kinds of wall materials (100, 7.5, and 0.5 W/m·K) were selected to investigate the effect of heat conduction on the catalytic combustion. The simulation results indicate that the catalytic reaction restrains the gas phase reaction in Pt/γ-Al2O3 catalytic micro-combustors. The gas phase reaction restrained by Pt/γ-Al2O3 catalysts is sensitive to thermal boundary condition at the wall. For most conditions, the gas phase reaction cannot be… More >

  • Open Access

    ARTICLE

    Capacity Optimization Configuration of Hydrogen Production System for Offshore Surplus Wind Power

    Yanshan Lu1, Binbin He1, Jun Jiang1, Ruixiao Lin2,*, Xinzhen Zhang2, Zaimin Yang3, Zhi Rao3, Wenchuan Meng3, Siyang Sun3

    Energy Engineering, Vol.120, No.12, pp. 2803-2818, 2023, DOI:10.32604/ee.2023.042328

    Abstract To solve the problem of residual wind power in offshore wind farms, a hydrogen production system with a reasonable capacity was configured to enhance the local load of wind farms and promote the local consumption of residual wind power. By studying the mathematical model of wind power output and calculating surplus wind power, as well as considering the hydrogen production/storage characteristics of the electrolyzer and hydrogen storage tank, an innovative capacity optimization allocation model was established. The objective of the model was to achieve the lowest total net present value over the entire life cycle. The model took into account… More >

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