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  • Open Access

    REVIEW

    Little Secrets for the Successful Industrial Use of Tannin Adhesives: A Review

    Antonio Pizzi*

    Journal of Renewable Materials, Vol.11, No.9, pp. 3403-3415, 2023, DOI:10.32604/jrm.2023.030930

    Abstract This brief article reviews a very particular and quite narrow field, namely what has been done and what is needed to know for tannin adhesives for wood panels to succeed industrially. The present fashionable focus on bioadhesives has led to producing chemical adhesive formulations and approaches for tannin adhesives as a subject of academic publications. These, as good and original they might be, are and will still remain a rather empty academic exercise if not put to the test of real industrial trials and industrial use. They will remain so without the “little” secrets and techniques outlined here that show… More >

  • Open Access

    ARTICLE

    Desorption Behavior and Thermogravimetric Analysis of Bio-Hardeners

    Benoit Ndiwe1,2,3, Antonio Pizzi4,*, Hubert Chapuis5, Noel Konai6, Lionel Karga7, Pierre Girods4, Raidandi Danwe6,8

    Journal of Renewable Materials, Vol.10, No.8, pp. 2015-2027, 2022, DOI:10.32604/jrm.2022.019891

    Abstract In this work, the thermal degradation and drying of bio-hardeners are investigated. Four bio-hardeners based on exudates of Senegalia senegal, Vachellia nilotica, Vachellia seyal, and Acacia Siebteriana were analyzed by FTIR and thermogravimetric analysis, and a desorption study was also conducted. The analysis by infrared spectroscopy indicates the existence of oligomers of different types all giving 5-hydroxy-2-hydroxymethylfuran and 2, 5-dihydroxymethylfuran which are then the real hardening molecules. The pyrolysis of these extracts reveals three main regions of mass loss, a first region is located between 25°C and 110°C reflecting the loss of water from the adhesive and the formation of… More > Graphic Abstract

    Desorption Behavior and Thermogravimetric Analysis of Bio-Hardeners

  • Open Access

    ARTICLE

    Performance of Unidirectional Biocomposite Developed with Piptadeniastrum Africanum Tannin Resin and Urena Lobata Fibers as Reinforcement

    Achille Gnassiri Wedaïna1,2, Antonio Pizzi2, Wolfgang Nzie1, Raidandi Danwe3, Noel Konaï4,*, Siham Amirou2, Cesar Segovia5, Raphaël Kueny5

    Journal of Renewable Materials, Vol.9, No.3, pp. 477-493, 2021, DOI:10.32604/jrm.2021.012782

    Abstract The Piptadeniastrum Africanum bark tannin extract was characterized using MALDI TOF, ATR-FT MIR. It was used in the development of a resin with Vachellia nilotica extract as a biohardener. This tannin is consisting of Catechin, Quercetin, Chalcone, Gallocatechin, Epigallocatechin gallate, Epicatechin gallate. The gel time of the resin at natural pH (pH = 5.4) is 660 s and its MOE obtained by thermomechanical analysis is 3909 MPa. The tenacity of Urena lobata fibers were tested, woven into unidirectional mats (UD), and used as reinforcement in the development of biocomposite. The fibers tenacity at 20, 30 and 50 mm lengths are… More >

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