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  • Open Access

    ARTICLE

    Chemically Modified Sugarcane Bagasse for Innovative Bio-Composites. Part One: Production and Physico-Mechanical Properties

    Peyman Ahmadi1,*, Davood Efhamisisi1,*, Marie-France Thévenon2,3, Hamid Zarea Hosseinabadi1, Reza Oladi1, Jean Gerard2,3

    Journal of Renewable Materials, Vol.12, No.10, pp. 1715-1728, 2024, DOI:10.32604/jrm.2024.054076 - 23 October 2024

    Abstract Sugarcane bagasse is an agro-waste that could replace timber resources for the production of bio-composites. Composite boards such as particleboard offer an issue for the use and recycling of poor quality timber, and these engineered products can overcome some solid wood limitations such as heterogeneity and dimension. Bagasse offers an alternative to wood chips for particleboard production but present some disadvantages as well, such as poor physico-mechanical properties. To address these issues, bagasse fibers were treated with an innovative natural resin formulated with tannin and furfural. Impregnated particles with different concentrations of resin (5%, 10%,… More > Graphic Abstract

    Chemically Modified Sugarcane Bagasse for Innovative Bio-Composites. Part One: Production and Physico-Mechanical Properties

  • Open Access

    ARTICLE

    Thermo-Mechanical, Physico-Chemical, Morphological, and Fire Characteristics of Eco-Friendly Particleboard Manufactured with Phosphorylated Lignin Addition

    Apri Heri Iswanto1,*, Harisyah Manurung1, Asma Sohail2, Lee Seng Hua3,9, Petar Antov4, Deded Sarip Nawawi5, Sarah Latifah5, Dewi Shafa Kayla5,6, Sukma Surya Kusumah6, Muhammad Adly Rahandi Lubis6, Linda Makovická Osvaldová7, Mohd. Hazwan Hussin8, Rangabhashiyam Selvasembian9, Lum Wei Chen10, Puji Rahmawati Nurcahyani6, Nam Hun Kim11, Widya Fatriasari6

    Journal of Renewable Materials, Vol.12, No.7, pp. 1311-1341, 2024, DOI:10.32604/jrm.2024.052172 - 21 August 2024

    Abstract Lignin, lignosulfonate, and synthesized phosphorylated lignosulfonate were introduced as green fillers in citric acid-sucrose adhesives for bonding particleboard fabricated from areca leaf sheath (ALS). The characteristics of particleboards were compared to that of ultralow emitting formaldehyde (ULEF-UF). The fillers derived from Eucalyptus spp. kraft-lignin were added for flame retardancy enhancement. 10% of each lignin and modified lignin was added into the ULEF-UF and citric acid-sucrose bonded particleboards. Analyses applied to particleboards included thermal characteristics, X-ray diffraction analysis (XRD), morphological properties, Fourier transform infrared spectroscopy (FTIR), as well as physical, mechanical, and fire resistance characteristics of the… More > Graphic Abstract

    Thermo-Mechanical, Physico-Chemical, Morphological, and Fire Characteristics of Eco-Friendly Particleboard Manufactured with Phosphorylated Lignin Addition

  • Open Access

    ARTICLE

    Adhesion of Technical Lignin-Based Non-Isocyanate Polyurethane Adhesives for Wood Bonding

    Jaewook Lee1, Byung-Dae Park1,*, Qinglin Wu2

    Journal of Renewable Materials, Vol.12, No.7, pp. 1187-1205, 2024, DOI:10.32604/jrm.2024.049948 - 21 August 2024

    Abstract Lignin is the most abundant aromatic natural polymer, and receiving great attention in replacing various petroleum-based polymers. The aim of this study is to investigate the feasibility of technical lignin as a polyol for the synthesis of non-isocyanate polyurethane (NIPU) adhesives to substitute current polyurethane (PU) adhesives that have been synthesized with toxic isocyanate and polyols. Crude hardwood kraft lignin (C-HKL) was extracted from black liquor from a pulp mill followed by acetone fractionation to obtain acetone soluble-HKL (AS-HKL). Then, C-HKL, AS-HKL, and softwood sodium lignosulfonate (LS) were used for the synthesis of technical lignin-based… More > Graphic Abstract

    Adhesion of Technical Lignin-Based Non-Isocyanate Polyurethane Adhesives for Wood Bonding

  • Open Access

    ARTICLE

    Impact on Mechanical Properties of Surface Treated Coconut Leaf Sheath Fiber/Sic Nano Particles Reinforced Phenol-formaldehyde Polymer Composites

    B. BRAILSON MANSINGH1, K. L. NARASIMHAMU2, K. C. VARAPRASAD3, J. S. BINOJ4,*, A. RADHAKRISHNAN5, ALAMRY ALI6

    Journal of Polymer Materials, Vol.40, No.1-2, pp. 71-82, 2023, DOI:10.32381/JPM.2023.40.1-2.6

    Abstract Several agro-wastes are rich in natural fibers and finds scope to be used as reinforcement in composite industry. These natural fibers have some advantages over man-made fibers, including low cost, light weight, renewable nature, high specific strength and modulus, and availability in various forms worldwide. In this paper, the effect of surface modification of leaf sheath coconut fiber (LSF) (an agro-waste) reinforced in phenol formaldehyde matrix composites with silicon carbide (SiC) nano particles as filler material were investigated for its mechanical characteristics. The investigation portrays that coconut LSF (CLSF) modified with potassium permanganate reinforced polymer More >

  • Open Access

    ARTICLE

    A Melamine–Dialdehyde Starch Wood Particleboard Surface Finish without Formaldehyde

    Bengang Zhang1,*, Antonio Pizzi2,*, Mathieu Petrissans1, Anelie Petrissans1, Baptiste Colin1

    Journal of Renewable Materials, Vol.11, No.11, pp. 3867-3889, 2023, DOI:10.32604/jrm.2023.028888 - 31 October 2023

    Abstract Melamine-dialdehyde starch resins used for wood surface finishes have been developed. The reaction of melamine with dialdehyde starch has been shown to occur by FTIR and MALDI ToF spectrometry, with several oligomer species due to the reaction of the two materials being identified, and the resin thermal stability was studied by thermogravimetric analysis. The resins were prepared by two different procedures when it was realized that dialdehyde starch is sensitive to too high a temperature for prolonged times. The melamine-dialdehyde starch resins were applied on particleboard supports as a direct liquid surface finish and a More >

  • Open Access

    ARTICLE

    Effect of Multi-Hydroxyl Polymer-Treated MUF Resin on the Mechanical Properties of Particleboard Manufactured with Reed Straw

    Yuhui Huang1, Zhiyuan Yin1,2, Ming Liu1, Meng Li1, Yingfeng Zuo1, Yan Qing1, Yiqiang Wu1,*

    Journal of Renewable Materials, Vol.11, No.9, pp. 3417-3431, 2023, DOI:10.32604/jrm.2023.028511 - 20 July 2023

    Abstract The poor bonding performance between aqueous adhesives represented by melamine-urea formaldehyde (MUF) resins and reed straw hinders their applications in the field of non-wood-based panels. Multi-hydroxyl polymers are highly reactive and are often used as crosslinkers. This study fabricated a resin with a strengthened cross-linked structure by combining a multi-hydroxyl polymer and MUF resin prepolymer. The reed particleboard was prepared by using this resin as an adhesive and reed stalk as the matrix. The results show that neighboring molecules combined to form C–O–C bonds that strengthened the cross-linked structure of the resin. In addition, the… More >

  • Open Access

    ARTICLE

    Curing Process of Phenol Formaldehyde Resin for Plywood under Vacuum Conditions

    Guobing Xiong1, Lu Hong2, Zehui Ju3, Xiaoning Lu3,*, Juwan Jin3,*

    Journal of Renewable Materials, Vol.11, No.9, pp. 3447-3461, 2023, DOI:10.32604/jrm.2023.027430 - 20 July 2023

    Abstract The study characterized the curing behaviors of phenol formaldehyde (PF) resin under different vacuum degrees and explored the properties of 9-ply plywood panels hot-pressed under both vacuum and atmospheric conditions. The changes in core temperature and moisture content of the plywood mats during hot pressing were investigated as well. It was found that the gel times and gel temperatures of PF resin decreased with the increase of vacuum degree using a self-made device. FTIR spectra indicated the degree of polycondensation of hydroxymethyl gradually increased with the increase in temperature. It was also observed that a… More >

  • Open Access

    ARTICLE

    Study on Coconut Shell Activated Carbon Temperature Swing Adsorption of Benzene and Formaldehyde

    Zhiguang Yang1,*, Gaojun Yan1,2, Xueping Liu1, Zhengyuan Feng1, Xinfeng Zhu1, Yanli Mao1, Songtao Chen1, Zhisheng Yu2, Ruimei Fan3, Linlin Shan3,*

    Journal of Renewable Materials, Vol.10, No.12, pp. 3573-3585, 2022, DOI:10.32604/jrm.2022.022031 - 14 July 2022

    Abstract Adsorption can be used to recover effectively the volatile organic gases (VOCs) in the exhaust gas from factories through using an appropriate adsorption bed. Due to form a physical or chemical bond, adsorption occurs between the porous solid medium and the liquid or gas multi-component fluid mixture. The regeneration capacity of the adsorbent is as important as the adsorption capacity and it determines the economics of the adsorption system. The regeneration of adsorbent can be realized through changing the pressure or temperature of the system. Here, activated carbon samples from coconut shell were prepared and… More > Graphic Abstract

    Study on Coconut Shell Activated Carbon Temperature Swing Adsorption of Benzene and Formaldehyde

  • Open Access

    ARTICLE

    Formaldehyde Free Renewable Thermosetting Foam Based on Biomass Tannin with a Lignin Additive

    Bowen Liu1, Yunxia Zhou1, Hisham Essawy2, Shang Feng1, Xuehui Li1, Jingjing Liao1, Xiaojian Zhou1,3,*, Jun Zhang1,*, Sida Xie1

    Journal of Renewable Materials, Vol.10, No.11, pp. 3009-3024, 2022, DOI:10.32604/jrm.2022.019848 - 29 June 2022

    Abstract This study presents easily prepared free formaldehyde bio-based foam based on a prepared thermosetting resin comprising tannin–lignin–furfuryl alcohol-glyoxal (TLFG) via mechanical stirring in presence of ether as a foaming agent. The foam was developed through a co-polycondensation reaction of glyoxal and furfuryl alcohol with condensed tannin and lignin, which is a forest-derived product. Investigation using scanning electron microscopy (SEM) showed more closed-cell structure without cracks and collapse in the TLFG foam, with a higher apparent density with respect to tannin–furanic–formaldehyde (TFF) foam. Differential scanning calorimetry (DSC), dynamic thermomechanical analysis (DTMA), and thermogravimetric analysis (TGA) investigations More >

  • Open Access

    ARTICLE

    Effects of Planting Density of Rubber Tree Clone (RRIM 2020 Clone and RRIM 2025 Clone) Wood to Particleboard Properties

    Juliana Abdul Halip1,2, Syeed SaifulAzry Osman Al-Edrus1,*, Seng Hua Lee1,*, Paridah Md Tahir1, Nor Yuziah Mohd Yunus3, Mohd Sapuan Salit1, Ahmad Ilyas Rushdan4,5

    Journal of Renewable Materials, Vol.10, No.7, pp. 1951-1960, 2022, DOI:10.32604/jrm.2022.016025 - 07 March 2022

    Abstract The depletion of log resources encourages research into alternative ways to sustain the wood supply. Therefore, the 4-year-old Rubber Research Institute of Malaysia (RRIM) clones series, RRIM 2020 and RRIM 2025, were chosen as potential raw materials for particleboard in this study. The purpose of this study was to assess the effects of planting density and rubber tree clones on the mechanical and physical properties of single-layer particleboard. The planting densities used were low, moderate-low, moderate-high, and high, representing 500, 1000, 1500, and 2000 trees/ha, respectively. Prior to manufacturing, the RRIM 2000 series clone trees… More >

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