Kristine Meile^1,*, Martins Romanovskis^1,2, Thomas Nicol³, Neil Hindle³, Aivars Zhurinsh¹

Journal of Renewable Materials, Vol.12, No.12, pp. 2135-2152, 2024, DOI:10.32604/jrm.2024.056775 - 20 December 2024

Abstract Fast pyrolysis of pre-treated birch wood in a super-heated steam environment produces a condensate rich in anhydrosugars. With the objective to obtain several product streams from this condensate, the possibility of extracting additional chemical species is explored, thus promoting the development of a pyrolysis-based biorefinery. In this work, the extraction and recovery of pyrolytic phenols from birch wood pyrolysis condensate was studied using ion exchange resins. With an aim to achieve effective phenol recovery, while obtaining high purity levoglucosan, basic ion exchange resins, both in OH⁻ and Cl⁻ form, as well as polystyrene-divinyl resins without functional… More > Graphic Abstract

Mehul Barde^1,2, Yusuf Celikbag³, Brian Via³, Sushil Adhikari⁴, Maria L. Auad^1,2,*

Journal of Renewable Materials, Vol.6, No.7, pp. 724-736, 2018, DOI:10.32604/JRM.2018.00116

Abstract Bio-based phenol-formaldehyde polymer (BioNovolac) was developed by reacting molar excess of bio-oil/phenol with formaldehyde in acidic medium. Glycidyl 3,5-diglycidoxybenzoate (GDGB), was prepared by direct glycidylation of α-resorcylic acid (RA), a naturally occurring phenolic monomer. GDGB was crosslinked in the presence of BioNovolac by anionic polymerization. Fourier transform infrared spectroscopy (FTIR) confirmed the formation of semi-interpenetrating polymer networks. The glass transition temperature and moduli of bio-based crosslinked systems were observed to increase with increasing GDGB content. Active chain density and mass retention measured by dynamic mechanical analysis (DMA) and Soxhlet extraction, respectively, indicated a high crosslink More >