DIPESHKUMAR D. KACHHADIYA, Z.V.P. MURTHY^*

Journal of Polymer Materials, Vol.38, No.1-2, pp. 49-61, 2021, DOI:10.32381/JPM.2021.38.1-2.5

Abstract The conventional process for methanol-water separation like distillation consumes about 60 % of total energy. As an alternative, researchers have developed a membrane-based separation process for alcohol-water mixtures separation. However, there is a big challenge for researches to separate alcohol-water aqueous mixtures using a polymeric membrane because of swelling. In the present work, the aim is to separate methanol from water by pervaporation using polymeric membranes made up of polyvinylidenefluroide (PVDF) and polyethylene glycol (PEG200) modified PVDF membranes. The membranes were characterized by thermogravimetry analysis (TGA), field emission scanning electron microscopy (FE-SEM), and Fourier-transform infrared spectroscopy (FTIR). A study on… More >

RABIRANJAN MURMU^a,b, DEBASHIS ROY^a, HAREKRUSHNA SUTAR^b

Journal of Polymer Materials, Vol.40, No.3-4, pp. 125-139, 2023, DOI:10.32381/JPM.2023.40.3-4.1

Abstract A one dimensional isothermal model is proposed by modelling the kinetics of methanol transport at anode flow channel (AFC), membrane and cathode catalyst layer of direct methanol fuel cell (DMFC). Analytical model is proposed to predict methanol cross-over rate through the electrolyte membrane and cell performance. The model presented in this paper considered methanol diffusion and electrochemical oxidation at the anode and cathode channels. The analytical solution of the proposed model was simulated in a MATLAB environment to obtain the polarization curve and leakage current. The effect of methanol concentration on cell voltage and leakage current is studied. The methanol… More >

RABIRANJAN MURMU^a,b, DEBASHIS ROY^a, HAREKRUSHNA SUTAR^b, PRAGYAN SENAPATI^c, SWETAK ABHISEK MOHAPATRA^b

Journal of Polymer Materials, Vol.39, No.1-2, pp. 89-109, 2022, DOI:10.32381/JPM.2022.39.1-2.6

Abstract In this work, we have successfully cross-linked the different weight ratio of Chitosan-PVA blend with sulfuric acid. The effect of cross-linker on the properties of blends are studied by using different experimental technique. The cross-linked membrane provides higher ion exchange capacity due to the procurement of extra ionic hooping sites in the membrane. The compatibility of the blends are confirmed from the FTIR and DSC analysis. The crosslinking reaction fastening the phase transition behavior of the blends which reduces the glass transition temperature. The highly compatiblized cross-linked blend provides higher tensile strength and lower modulus at moderate temperature. The significant… More >

Cheng-Kang Guan, James F. Klausner^*, Renwei Mei

Frontiers in Heat and Mass Transfer, Vol.2, No.4, pp. 1-6, 2011, DOI:10.5098/hmt.v2.4.3002

Abstract Pool boiling critical heat flux (CHF) has been measured for pentane, hexane, methanol, FC-72, FC-87, and R113 on a 25.4 mm diameter smooth brass horizontal surface at five different reduced pressures ranging from 0.01to 0.24. The CHF data are compared with various established CHF models as well as the new mechanistic CHF lift-off model recently proposed by the authors. The dependence of CHF on pressure is examined, and it is found that the lift-off model gives a reasonably good prediction of changes in CHF with step changes in the reduced pressure. The R113 and FC-72 boiling curves suggest that a… More >

Q.X. Wu^a, Y.L. He^b, T.S. Zhao^a,b,*

Frontiers in Heat and Mass Transfer, Vol.2, No.3, pp. 1-14, 2011, DOI:10.5098/hmt.v2.3.2001

Abstract Running direct methanol fuel cells (DMFC) with concentrated fuel is desirable to maximize the specific energy of the fuel cell system and to improve the performance by mitigating the water flooding problem associated with diluted methanol operation. This article provides a comprehensive review of recent advances in understanding mass transport phenomena in DMFCs operating with concentrated fuel. The review starts with elaborating the key issues of mass transport of reactants and products associated with highly-concentrated methanol operation, followed by summarizing and discussing past experimental and numerical investigations into the effects of the membrane electrode assembly (MEA) design, flow field structure… More >

Zheng Miao^a, Ya-Ling He^a,*, Tian-Shou Zhao^b, Wen-Quan Tao^a

Frontiers in Heat and Mass Transfer, Vol.2, No.1, pp. 1-10, 2011, DOI:10.5098/hmt.v2.1.3001

Abstract A non-isothermal two-phase mass transport model is developed in this paper to investigate the heat generation and transport phenomena in a direct methanol fuel cell with anisotropic gas diffusion layers (GDLs). Thermal contact resistances at the GDL/CL (catalyst layer) and GDL/Rib interfaces, and the deformation of GDLs are considered together with the inherent anisotropy of the GDL. Latent heat effects due to condensation/evaporation of water and methanol between liquid and gas phases are also taken into account. Formulation of the two-phase mass transport across the membrane electrode assembly (MEA) is mainly based on the classical multiphase flow theory in the… More >

B.G. Suhas^a,* , A. Sathyabhama^b, Kavadiki Veerabhadrappa^a , R. Suresh Kumar^a, U. Kiran Kumar^a

Frontiers in Heat and Mass Transfer, Vol.13, pp. 1-8, 2019, DOI:10.5098/hmt.13.16

Abstract In the present study, heat transfer coefficient of water-ethanol mixture in the subcooled boiling region is determined in a rectangular conventional channel (Channel size ≥3 mm). When the heat flux and mass flux increase it is observed that heat transfer coefficient increases. But the effect of heat flux is significant when compared with that of mass flux in the subcooled boiling region. It is found that maximum and minimum heat transfer coefficient are observed for mixture with 25% Ethanol volume fraction and 75% Ethanol volume fraction respectively. Wall heat flux partitioning analyses is carried out for mixture with different ethanol… More >

Xu Gao, Ziqi Shen, Jinliang Xu, Min Fan, Qiang Li^*

Phyton-International Journal of Experimental Botany, Vol.92, No.7, pp. 1987-1999, 2023, DOI:10.32604/phyton.2023.027318

Abstract Phytophthora nicotianae causes substantial economic losses in most countries where tobacco is produced. At present, the control of P. nicotianae mainly depends on chemical methods, with considerable environmental and health issues. We investigated the effects of ethanol extracts from Scutellaria baicalensis Georgi (SBG) and Magnolia officinalis (MO). On mycelial growth, sporangium formation, and zoospore release of P. nicotianae. Both extracts inhibited the growth of P. nicotianae, with mycelial growth inhibition rates of 88.92% and 93.92%, respectively, at 40 mg/mL, and EC50 values of 5.39 and 5.74 mg/mL, respectively. The underlying mechanisms were the inhibition of sporangium formation, the reduction of… More >

Sri Hidayati^1,*, Eugenia Fonny Budiyanto¹, Hadi Saputra¹, Sutopo Hadi¹, Apri Heri Iswanto^2,3, Nissa Nurfajrin Solihat⁴, Petar Antov⁵, Lee Seng Hua^6,7, Widya Fatriasari^4,8, Mohd. Sapuan Salit⁹

Journal of Renewable Materials, Vol.11, No.6, pp. 2865-2879, 2023, DOI:10.32604/jrm.2023.027579

Abstract Black liquor is obtained as a by-product of the pulping process, which is used to convert biomass into pulp by removing lignin, hemicelluloses and other extractives from wood to free cellulose fibers. Lignin represents a major constituent in black liquor, with quantities varying from 20% to 30%, of which a very low share is used for manufacturing value-added products, while the rest is mainly burned for energy purposes, thus underestimating its great potential as a raw material. Therefore, it is essential to establish new isolation and extraction methods to increase lignin valorization in the development of bio-based chemicals. The aim… More > Graphic Abstract

Chao Zhu¹, Zhuopei Liu², Hao Chen^2,3, Yangyang Li^2,3,*

Energy Engineering, Vol.120, No.5, pp. 1081-1105, 2023, DOI:10.32604/ee.2023.026000

Abstract Experiments were conducted on a diesel-methanol dual-fuel (DMDF) engine modified by a six-cylinder, turbo-charged, inter-cooled diesel engine. According to the number of diesel injection, the experiments are divided to two parts: the single injection mode and double injection mode. The results show that, at the double injection mode, the maximum of pressure rise rate is small and the engine runs smoothly, however, knock still occurs when the co-combustion ratio (CCR) is big enough. Under knock status, the power density of the block vibration concentrating at some special frequencies rises dramatically, and the special frequency of single injection mode (about 4.1… More >