Leiju Tian¹, Yuhuan Bu^1,*, Huajie Liu^1,*, Lingyun Zhao^2,3

FDMP-Fluid Dynamics & Materials Processing, Vol.19, No.5, pp. 1215-1226, 2023, DOI:10.32604/fdmp.2022.022219

Abstract The mechanical properties of Portland cement differ from the weakly consolidated shallow formation in deep water. This results in undesired abrupt changes in the compressive strength and elastic modulus at the cement–formation interface. In this study, a water-borne epoxy resin was applied as a strengthening material to reinforce the weakly consolidated shallow formation and protect the cement sheath from potential failure. The mechanical properties of the unconsolidated clay were tested, including their changes with increases in the temperature and curing time. In addition, the effects of the seawater, cement slurry alkaline filtrate, and saltwater drilling fluid were evaluated. As confirmed… More >

Pronob Gogoi, Dhaneswar Das, Shyamalima Sharma, Swapan K. Dolui^*

Journal of Renewable Materials, Vol.3, No.2, pp. 151-159, 2015, DOI:10.7569/JRM.2014.634129

Abstract Alkyd resins based on Jatropha curcas oil with different molar ratios of phthalic anhydride (PA) and maleic anhydride (MA) were prepared by alcoholysis followed by polyesterifi cation reaction. The progress of the reaction was traced by the determination of acid value at regular time intervals. From the kinetic study the extent of the reaction was found in the range of 52.4–61.2%. The prepared resins were blended with a commercially available fast-curing epoxy resin in order to improve the properties like curing time, chemical resistance, tensile strength, and thermal stability. The morphology study of the blends showed good compatibility of alkyd… More >

Yongming Chen^1,2,#, Shuai Huang^1,#, Han Zhao¹, Ru Yang², Yining He¹, Tianyu Zhao¹, Yunlong Zhang¹, Qinghong Kong^1,*, Shasha Sun^3,*, Junhao Zhang³

Journal of Renewable Materials, Vol.10, No.12, pp. 3119-3130, 2022, DOI:10.32604/jrm.2022.019576

Abstract To enhance the thermal stability and flame retardancy of epoxy resin (EP), beta-cyclodextrin (β-CD) is successfully introduced into the layered tin phenylphosphonate (SnPP), which is incorporated into EP matrix for preparing EP/β-CD@SnPP composites. The results indicate that the addition of β-CD@SnPP obviously improve the thermal stability and residual yield of EP composites at higher temperature. When the amount of β-CD@SnPP is only 4 wt%, EP/4β-CD@SnPP composites pass V-1 rating, and LOI value is up to 30.8%. Meanwhile, β- CD@SnPP effectively suppress the heat release and reduce the smoke production of EP/β-CD@SnPP composites in combustion, and the peak heat release rate… More >

Meixian Li¹, Xin Hu¹, Jie Yang¹, Hongyu Yang^1,3,*, Yao Yuan^2,*

Journal of Renewable Materials, Vol.10, No.10, pp. 2639-2654, 2022, DOI:10.32604/jrm.2022.019491

Abstract In this work, a bio-based flame retardant (Cy-HEDP) was synthesized from cytosine and HEDP through a facile salt-forming reaction and embedded into epoxy matrix to improve the flame retardancy and smoke suppression performance. The product Cy-HEDP was well characterized by FTIR, ¹ H and ³¹P NMR and SEM tests. On the basis of the results, by adding 15 wt% Cy-HEDP, the EP₁₅ can pass UL-94 V-0 rating, and the total smoke production (TSP) as well as total heat release (THR) can be decreased by 61.05% (from 22.61 to 8.7 m² /m² ) and 39.44% (from 103.19 to 62.50 MJ/m² )… More > Graphic Abstract

Xianling Fu^#, Hongliang Ding^#, Xin Wang^*, Lei Song, Yuan Hu^*

Journal of Renewable Materials, Vol.10, No.9, pp. 2303-2317, 2022, DOI:10.32604/jrm.2022.020759

Abstract Although epoxy resin has been widely used in various fields, it still suffers from some problems including brittleness and flammability. In this study, a new phosphonic acid, N, N-bis(phosphomethyl) glycine (GDMP), was prepared by Mannich reaction with bio-based glycine and then a novel layered zirconium phosphonate (ZrGDMP) was synthesized using GDMP and zirconyl chloride hydrate as reactants. The chemical structure of ZrGDMP was well characterized by ¹H and ³¹P NMR, SEM, XRD and XPS. The effect of ZrGDMP on the flame retardancy, smoke suppression, strengthening and toughening performances of the epoxy matrix was investigated and evaluated. TGA results indicated that… More > Graphic Abstract

Lara Greiner^1,*, Philipp Kukla², Sebastian Eibl¹, Manfred Döring³

Journal of Renewable Materials, Vol.10, No.7, pp. 1931-1950, 2022, DOI:10.32604/jrm.2022.019548

Abstract A novel, versatile flame retardant substructure based on phosphorylated salicylic acid (SCP) is described and used in the synthesis of new flame retardants for HexFlow^® RTM6, a high-performance epoxy resin used in resin transfer molding processes as composite matrix. The starting material salicylic acid can be obtained from natural sources. SCP as reactive phosphorus chloride is converted with a novolak, a novolak containing 9, 10-dihydro-9- oxa-10-phospha-phenanthrene-10-oxide (DOPO) substituents or DOPO-hydroquinone to flame retardants with sufficient thermal stability and high char yield. Additionally, these flame retardants are soluble in the resin as well as react into the epoxy network. The determined… More >

Hongxiang Liu^1,2,,*, Neng Xiong^1,2, Songli Wang^1,2, Wei Zhang^1,2, Bo Yong^1,2

FDMP-Fluid Dynamics & Materials Processing, Vol.18, No.3, pp. 549-561, 2022, DOI:10.32604/fdmp.2022.017979

Abstract

The effects of a magnesium-based layered composite on the flammability of a phenolic epoxy resin (EP) are studied. In order to produce the required composite material, first, magnesium hydroxide, aluminum salt and deionized water are mixed into a reactor according to a certain proportion to induce a hydrothermal reaction; then, the feed liquid is filtered out using a solid-liquid separation procedure; finally, the material is dried and crushed. In order to evaluate its effects on the flammability of the EP, first, m-phenylenediamine is added to EP and vacuum defoamation is performed; then, EP is poured into a polytetrafluoroethylene mold, cooled… More >

Li Wang^1,2,#, Rongbai Tong^3,#, Juanli Wang^1,2,*, Jintao Wan^1,2,*, Yuhu Li^1,2, Pujun Jin^1,2, Daodao Hu^1,2

Journal of Renewable Materials, Vol.10, No.5, pp. 1349-1364, 2022, DOI:10.32604/jrm.2022.019372

Abstract Quest for bio-based halogen-free green flame retardant has attracted many concerns in recent years. Herein a reactive functional flame retardant containing phosphorus VDP is synthesized from vanillin, 9,10-dihydro-9-oxa-10-phosphophene-10-oxide (DOPO) and phenol via a facile way. VDP is characterized with ¹H NMR, ³¹P NMR, FTIR and Time of Flight Mass Spectrometry, and used as a new reactive flame retardant for bisphenol epoxy thermosets. Thermogravimetry analysis shows that when the VDP loading is only 0.5P% (based on phosphorus content), the residue increases from 14.2% to 21.1% at 750°C in N₂ compare with neat DGEBA. Correspondingly, the limit oxygen index increased to 29.6%,… More >

Syed Waheedullah Ghori^1,*, G. Srinivasa Rao²

Journal of Renewable Materials, Vol.9, No.7, pp. 1283-1292, 2021, DOI:10.32604/jrm.2021.014987

Abstract Date palm fiber (DPF) and kenaf fiber were reinforced in epoxy having various fiber loading 40%, 50%, and 60% by weight. These hybrid samples were manufactured by hot press technique and then characterized for tensile, impact, and morphological behavior to evaluate the ratio of fibers in the hybrid composites; the addition of kenaf improved the tensile properties, Scanning Electron Microscopy (SEM) revealed the interfacial bonding of fiber/matrix, and dispersion and void content in composites. Impact test studies reflected the effect of natural fiber with epoxy, level of stress transfer from matrix to reinforced material, and reinforced material’s role in absorbing… More > Graphic Abstract

Xiaofu Wang^1,*, Xiong Zhang¹, Yan He², Chunming Lian³

Journal of Renewable Materials, Vol.8, No.8, pp. 947-968, 2020, DOI:10.32604/jrm.2020.011327

Abstract In order to solve the problem of urban surface runoff, it is necessary to study permeable brick deeply. Tensile test and DMA test were used to study the binder material of permeable brick, and a material with the best mechanical properties was selected as the binder of resin based permeable brick; The permeable brick with single gradation and continuous gradation and porosity of 0.1–0.5 gradient is constructed by 3D modeling method. The particle composition and the seepage simulation results of permeable brick under different design parameters were analyzed; A resin-based permeable brick with micro-pores was prepared using the selected binder… More >