Chengcheng Wang^1,2,*, Dawei Luo¹, Bingxue Hou³, Mortaza Gholizadeh⁴, Zanxiong Tan¹, Xiaojie Han¹

Journal of Renewable Materials, Vol.10, No.5, pp. 1337-1348, 2022, DOI:10.32604/jrm.2022.018770 - 22 December 2021

Abstract It is critical to study efficient, stable oxygen reduction reaction (ORR) electrocatalysts due to insufficient stability and expensive price of Pt/C catalysts for Zn-air batteries. Fe–N–C electrocatalysts was synthesized by a facile solvent-green method and the efficiency of Fe–N–C optimized was studied as potential ORR electrocatalysts under alkaline condition. Results indicated that it had excellent ORR activity with E_1/2 of 0.93 V, which was competitive to that of Pt/C-JM under the same conditions. Moreover, the assembled Zn-air battery exhibited discharge potential and charge potential of 1.2 V, 2.32 V at 5 mA cm⁻² with high stability, respectively. More > Graphic Abstract

Xianglong Lu¹, Tianshui Yu¹, Hailing Wang¹, Ruichun Luo², Pan Liu², Songliu Yuan¹, Lihua Qian^1,*

Journal of Renewable Materials, Vol.8, No.2, pp. 133-151, 2020, DOI:10.32604/jrm.2020.08650 - 01 February 2020

Abstract Hydrogen evolution reaction (HER) in neutral medium suffers from slow kinetics as compared to that in alkaline or acidic conditions, owing to larger Ohmic loss and low proton concentration. Here we report that a self-supported nanoporous Au-SnO_x (NP Au-SnO_x) catalyst with gradient tin oxide surface could significantly enhance HER activity in neutral buffer solution (0.2 M PBS). The NP Au-SnO_x catalyst exhibits a low onset overpotential of 38 mV and a small Tafel slope of 79 mV dec⁻¹ . The current density of 10 mA cm⁻² is manifested at an overpotential as low as 148 mV, representing the More >