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  • Open Access

    ARTICLE

    Development and Characterization of Eco-Friendly Non-Isocyanate Urethane Monomer from Jatropha curcas Oil for Wood Composite Applications

    Samsul Bhakri1, Muhammad Ghozali2,*, Edy Cahyono1, Evi Triwulandari2, Witta Kartika Restu2, Nissa Nurfajrin Solihat3, Apri Heri Iswanto4,5, Petar Antov6, Viktor Savov6, Lee Seng Hua7, Erika Ayu Agustiany8, Lubos Kristak9, Widya Fatriasari3,*

    Journal of Renewable Materials, Vol.11, No.1, pp. 41-59, 2023, DOI:10.32604/jrm.2022.023151 - 10 August 2022

    Abstract The aim of this research work was to evaluate the potential of using renewable natural feedstock, i.e., Jatropha curcas oil (JCO) for the synthesis of non-isocyanate polyurethane (NIPU) resin for wood composite applications. Commercial polyurethane (PU) is synthesized through a polycondensation reaction between isocyanate and polyol. However, utilizing toxic and unsustainable isocyanates for obtaining PU could contribute to negative impacts on the environment and human health. Therefore, the development of PU from eco-friendly and sustainable resources without the isocyanate route is required. In this work, tetra-n-butyl ammonium bromide was used as the activator to open the… More > Graphic Abstract

    Development and Characterization of Eco-Friendly Non-Isocyanate Urethane Monomer from <i>Jatropha curcas</i> Oil for Wood Composite Applications

  • Open Access

    ARTICLE

    Feasibility Study of the Synthesis of Isocyanate-Free Polyurethanes from Catechin

    Wissem Sahmim1, Febrina Dellarose Boer1, Hubert Chapuis1, Firmin Obounou-Akong1, Antonio Pizzi2, Philippe Gérardin1, Christine Gérardin-Charbonnier1,*

    Journal of Renewable Materials, Vol.10, No.5, pp. 1175-1184, 2022, DOI:10.32604/jrm.2022.016365 - 22 December 2021

    Abstract With the current trend of increasing efforts to develop non-isocyanate-based polyurethanes (NIPUs), this study aimed to check the feasibility of the development of a method using cyclic carbonate modified catechin and amine to synthesis non-isocyanate urethane with the objective to further extend these results to polyurethane synthesis. The methods used in this study consist of four steps: glycidilation of catechin, hydrolysis of epoxide, cyclic carbonate synthesis, and carbamate synthesis through condensation of butylamine. The resulting products were analyzed using FTIR (Fourier transform infrared) spectroscopy and NMR (nuclear magnetic resonance) spectroscopy. The results showed that carbamate More > Graphic Abstract

    Feasibility Study of the Synthesis of Isocyanate-Free Polyurethanes from Catechin

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