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  • Open Access

    ARTICLE

    Polystyrene-Grafted Molybdenum Disulfide Filled Polypropylene Composites for Enhanced Laser Marking Performance

    Minglei Hu1, Wei Zhang1, Bin Hu1, Haicun Yang2, Fuqiang Chu2, Zheng Cao2,*

    Journal of Polymer Materials, Vol.42, No.4, pp. 1125-1141, 2025, DOI:10.32604/jpm.2025.073300 - 26 December 2025

    Abstract Polypropylene (PP) has low inherent susceptibility to common industrial lasers, which poses a significant challenge for laser-based marking. To improve the laser sensitivity of PP, molybdenum disulfide grafted with polystyrene (MoS2-g-PS) was synthesized via in-situ free radical polymerization and used as a laser-sensitive filler for PP composites prepared by melt blending. The composites were then marked with a 1064 nm semiconductor laser, producing clear and legible patterns. The marked surfaces were characterized using scanning electron microscopy (SEM), transmission electron microscopy (TEM), colorimetry, Raman spectroscopy, and thermogravimetric analysis (TGA). The results demonstrate that the PP/MoS2-g-PS composites exhibit significantly More >

  • Open Access

    ARTICLE

    Construction of Synergistic and Efficient Flame-Retardant Polyamide 6 Composites by Incorporating Aluminum Diethylphosphinate and Fly Ash

    Ruiping Wang, Chuang He, Shuo Zhang, Miaojun Xu*, Zhuo Wang, Xiaoli Li*, Bin Tao, Suliang Gao, Bin Li*

    Journal of Polymer Materials, Vol.42, No.4, pp. 1035-1049, 2025, DOI:10.32604/jpm.2025.073108 - 26 December 2025

    Abstract The fabrication of highly flame-retardant polyamide 6 (PA6) composites is of great significance for expanding their practical applications. Herein, a new flame-retardant system (ADP/FA) was developed by combining aluminum diethylphosphinate (ADP) with excellent flame retardancy and fly ash (FA), an economical and environmentally friendly industrial waste. Due to the synergistic flame-retardant effect of ADP/FA in the condensed phase and gas phase, the PA6 composite containing only 11 wt% of ADP/FA (mass ratio 93:7) obtained vertical burning (UL-94) tests V-0 rating with a limiting oxygen index (LOI) of 30.9%. To obtain the same flame-retardant level of… More > Graphic Abstract

    Construction of Synergistic and Efficient Flame-Retardant Polyamide 6 Composites by Incorporating Aluminum Diethylphosphinate and Fly Ash

  • Open Access

    ARTICLE

    The Failure Analysis of Carbon Fiber-Reinforced Epoxy Composites against Impact Loading with Numerical and Experimental Investigations

    Md Salah Uddin*

    Journal of Polymer Materials, Vol.42, No.4, pp. 1051-1073, 2025, DOI:10.32604/jpm.2025.070688 - 26 December 2025

    Abstract Carbon fiber-reinforced composites (CFRCs) have a wide range of applications in the aerospace, automotive, and energy sectors. A higher specific strength-to-weight ratio is desired in high-performance applications. The failure mechanism of CFRCs involves multiscale phenomena, such as failure that can occur at the matrix, fibers, interface, layers, lamina, and laminates. When an impactor hits the CFRCs, the design involves analyzing each of these stages to prevent failure and optimize the properties of CFRCs under various loading conditions. A numerical model was employed to predict the fracture toughness of CFRCs with varying weight fractions and orientations.… More >

  • Open Access

    ARTICLE

    Structural and optical properties of ZnS/rGO nanocomposites optoelectronic devices

    A. M. Abdel-Daiema, M. Ahmeda,, E. R. Shaabanb,

    Chalcogenide Letters, Vol.22, No.2, pp. 131-142, 2025, DOI:10.15251/CL.2025.222.131

    Abstract This paper investigates the impact of reduced graphene oxide (rGO) addition on the structural and optical properties of ZnS nanocomposites. The study began with the synthesis of graphene oxide (GO) through the oxidation of natural graphite powder. This process involved using potassium permanganate in a mixture of sulfuric and phosphoric acids, maintained at 50°C for 48 hours. The reaction was terminated using hydrogen peroxide, followed by purification and drying, yielding 1.5 grams of GO. The preparation of ZnS/GO nanocomposites involved dissolving zinc acetate and varying quantities of GO in water, adjusting the pH, and incorporating… More >

  • Open Access

    ARTICLE

    Evaluation of the structural and physical properties of CdxZn1-xS nanocomposites depending technological condition

    L. Gahramanlia,b,c,*, M. Muradova, G. Eyvazovaa, A. Karimovaa, M. Jafarovb

    Chalcogenide Letters, Vol.22, No.2, pp. 109-121, 2025, DOI:10.15251/CL.2025.222.109

    Abstract The study presents nanocomposite materials based on CdxZn1-xS, synthesized as thin films and nanoparticles through two distinct techniques—sonochemical and SILAR synthesis techniques. The characteristics of these materials were investigated using X-ray diffraction (XRD), Ultraviolet spectroscopy (UV-Vis), Fourier-transform infrared (FTIR) spectroscopy, and Scanning Electron Microscopy (SEM). In the sonochemical approach, samples were prepared with three different stabilizers for comparative analysis to determine influence of type of the stabilizers. Meanwhile, the SILAR approach created thin layers with different components (distinctive x value-CdxZn1-xS) at various grown temperatures utilizing polyvinyl alcohol (PVA) as a substrate. At the same time, nanocomposite More >

  • Open Access

    ARTICLE

    Molybdenum disulfide carbon composite material using hydrothermal method as electrode material for supercapacitors

    X. L. Guoa, Y. F. Zhanga,*, S. Y. Lib, Q. Lib, Q. Haoc, X. Y. Ranc, Y. M. Zhaod

    Chalcogenide Letters, Vol.22, No.4, pp. 313-330, 2025, DOI:10.15251/CL.2025.224.313

    Abstract MoS2 has excellent properties but low conductivity, limiting its use in supercapacitors. Carbon’s high conductivity and stability enhance MoS2’s electrochemical performance and cycling stability. This study prepared MoS2/C composites via a one-step hydrothermal method, exploring the effects of solvents and carbon content. Deionized water as a solvent resulted in composites with large specific surface areas and good electrochemical properties. Increasing carbon content improved electrochemical performance, peaking at a glucose content of 0.28 mmol, achieving a specific capacitance of 202.6 F/g. However, excessive carbon content led to decreased performance. More >

  • Open Access

    ARTICLE

    Synthesis of MoS2/Fe3O4 composites for the detection of liver cancer biomarker alpha-fetoprotein

    C. B. Cuia,b, G. C. Yangb, Z. Zhanga,, X. J. Wangc,

    Chalcogenide Letters, Vol.22, No.6, pp. 507-520, 2025, DOI:10.15251/CL.2025.226.507

    Abstract This research introduces an innovative aptasensor for detecting alpha-fetoprotein with exceptional sensitivity and specificity, employing a novel MoS2/Fe3O4 composite fabricated through an advanced in-situ growth methodology. The composite exhibited a hierarchical flower-like structure with uniformly distributed Fe3O4 nanoparticles, confirmed by SEM, XRD, and Raman spectroscopy. The MoS2/Fe3O4 composite demonstrated a 66% increase in surface area (7.16 m²/g) compared to pristine MoS2, enhancing aptamer immobilization and electron transfer efficiency. Electrochemical characterization revealed a significant increase in interfacial resistance upon AFP binding, with a detection limit of 0.3 pg/mL and a dual linear range of 0.001–0.1 ng/mL and 0.1–100 More >

  • Open Access

    ARTICLE

    Preparation of ZnS-Carbon nanotube nanocomposites via solvothermal method and their application in electrochemical detection of escherichia coli O157:H7

    F. F. Tonga,*, J. L. Hanb

    Chalcogenide Letters, Vol.22, No.8, pp. 719-733, 2025, DOI:10.15251/CL.2025.228.719

    Abstract In this study, hierarchical ZnS–CNT hybrids were synthesized via a solvothermal reaction at 180 °C for 48 h, producing ∼200 nm ZnS spheres uniformly anchored onto oxidized multiwalled carbon nanotubes. Structural analyses by XRD confirmed the cubic sphalerite phase, while SEM and TEM revealed a “pearl-necklace” morphology and effective nanoparticle dispersion. XPS spectra verified Zn2+ and oxygen-containing surface groups on the composite. Nitrogen adsorption–desorption measurements showed that incorporating CNTs transformed the material’s isotherm from type III to type IV, increasing the BET surface area from 68 to 155 m2 /g and introducing mesoporosity. When drop-cast onto More >

  • Open Access

    ARTICLE

    Design and synthesis of diketopyrrolopyrrole-CdS hybrid nanostructures for enhanced photovoltaic applications

    Q. Fei1,*, B. Jin2, B. C. Jiang3, J. S. Huang4, L. Li5

    Chalcogenide Letters, Vol.22, No.8, pp. 693-705, 2025, DOI:10.15251/CL.2025.228.693

    Abstract An innovative hybrid nanostructure composed of diketopyrrolopyrrole (DPP) oligomers and cadmium sulfide (CdS) nanoparticles was developed to enhance the efficiency of organic– inorganic photovoltaic devices. The DPP-CdS hybrids were synthesized via a solution-phase mixing method, resulting in uniform nanoparticle dispersion along polymer fibrils and strong interfacial coupling. Structural characterization confirmed the coexistence of crystalline CdS domains and partially ordered DPP phases, while spectroscopic analyses indicated notable redshifts and band broadening, evidencing electronic interactions at the interface. The hybrid material displayed significantly broadened light absorption across the 400–700 nm range and an optimized optical bandgap of… More >

  • Open Access

    ARTICLE

    Photoelectric effects in polymer – (CdS) – ferrocene composites

    A. N. Jafarova, A. F. Gochuyeva*

    Chalcogenide Letters, Vol.22, No.9, pp. 821-828, 2025, DOI:10.15251/CL.2025.229.821

    Abstract In our work, we investigated the photoelectric effects arising in composites consisting of polar (fluorine-containing) and non-polar (polyolefin) polymers—such as high-density polyethylene (HDPE), PVDF, F42 — and an inorganic phase composed of AII< BVI (CdS, ZnS) and ferrocene. In addition, the processes occurring in these composites during the creation of these effects have been studied. It was found that the parameters of the formation of the posistor effect in the polymer-ferrocene composite are related to the presence of an interphase potential barrier, which is determined by the geometric dimensions of the interphase transition layer, dielectric permeability, More >

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