ZHAO JUN^a, LIU AIQIN^a, ZHOU HONG^a, LUO JUN^b,*, AND LIU YUAN^b,*

Journal of Polymer Materials, Vol.37, No.1-2, pp. 29-42, 2020, DOI:10.32381/JPM.2020.37.1-2.3

Abstract Heteroatoms (N, O, and F) and hydrogen groups are important elements for forming the H-bonds. It is well known that a large number of hydrogen groups are formed after curing reaction of epoxy. However, literatures about epoxy resins containing heteroaromatic ring and the H-bonds after cure reaction of the epoxy resins are seldom published. To bridge the gap, a kind of new epoxy monomer containing pyridine ring (EMP) has been synthesized in this work, andit is further cured by 4,4-diaminodiphenyl methane (DDM). The properties of cured EMP/ DDM are evaluated by DSC, DMA, and static contact angle measurement. Moreover, the… More >

ARCHANA KUMARI, KHEYANATH MITRA, SAMBHAV VISHWAKARMA, SOUROV MONDAL, SHIKHA SINGH, RAJSHREE SINGH, JAYDEEP SINGH, BISWAJIT MAITI, SUSANTA KUMAR SEN GUPTA, BISWAJIT RAY^*

Journal of Polymer Materials, Vol.37, No.3-4, pp. 143-164, 2020, DOI:10.32381/JPM.2020.37.3-4.3

Abstract A new acrylamide monomer N-(3-(hexylamino)-N-(3-(isopropylamino)-3-oxopropyl) acrylamide (HA-NIPAM-AM) and a new RAFT agent O-propionyl-2-(N,N-diphenylcarbamothioylthio) propanoate have successfully been synthesized and used for the synthesis of poly(HA-NIPAM-AM) homopolymers via RAFT polymerization. The formed homopolymers have been characterized by GPC, ¹ H NMR, FTIR, contact angle measurement, TG-DTA, DSC, and PXRD. Numberaveragemolar masses of the prepared polymers are in the range of 2,500 – 11,500 g/mol. Selfassembly of homopolymer has been studied viacmc determination in water using pyrene as fluorescence probe, HRTEM and DLS. Polymeris thermally stable up to 300 °C and has a glass transition temperature at 85.3 °C. XRD study reveals… More >

RAFAT SABA^*, MOHD. KASHIF AZIZ, GHULAM MUSTAFA, ARPIT SRIVASTAVA, SHEKHAR SRIVASTAVA^*

Journal of Polymer Materials, Vol.38, No.1-2, pp. 153-166, 2021, DOI:10.32381/JPM.2021.38.1-2.12

Abstract We have synthesized Schiff’s base of Fe₃ O₄ @chitosan with 4,4'-diselenobisbenzaldehyde (Fe₃O₄ @CSSe) composite and used it as acatalyst for the oxidation of sulfides, having some advantageous properties such as eco-friendly, cost-effective and highly efficient magnetic biocatalyst of selenium. The synthesized schiff’s base was characterized by different physical characterization techniques such as Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), Vibrating sample magnetometer (VSM)and Dynamic light scattering (DLS). Further, we used the resulting schiff’s base as a catalyst in the presence of a green oxidant (H₂ O₂ ) to oxidize sulfides to corresponding sulfoxides at room temperature. It has been… More >

RAID BANAT^1,*, MANAL AL-RAWASHDEH¹, HEBA ALKHLAIFAT¹

Journal of Polymer Materials, Vol.38, No.1-2, pp. 137-151, 2021, DOI:10.32381/JPM.2021.38.1-2.11

Abstract Composite of oil Shale ash (OSA) filler and high density polyethylene (HDPE) matrix was formulated and studied. OSA mainly composed of Ca, Si, and Fe most of which in oxide forms. OSA-HDPE composite with 0, 5, 10, 15, 20, and 25 wt. % OSA were produced using extrusion and hot press. Mechanical, morphological, and water uptake properties of the composite are discussed herein. While the tensile stress at yield, 47 MPa, restored its value close to the neat HDPE, an increase in the mean values of the tensile stress at rapture from 19 to 33 MPa, the tensile modulus from… More >

CANSU ULKER TURAN^1,*, YUKSEL GUVENILIR¹

Journal of Polymer Materials, Vol.38, No.3-4, pp. 271-280, 2021, DOI:10.32381/JPM.2021.38.3-4.8

Abstract Rice husk ash is a side-product of rice production; thus, it is a cheap, abundant, and renewable material, and utilized as an enzyme carrier to immobilize Candida antarctica lipase B. In this study, Candida antarctica lipase B immobilized onto rice husk ashes was used to catalyze ring opening polymerization of 16-membered lactone, ω-pentadecalactone. In order to determine the best polymerization conditions for highest molar mass polymer, reactions were proceeded at various temperatures and time periods. The best reaction conditions were obtained as 80°C and 6 hours (M_n = 34255 g mol^-1). Molecular structure of this polymer sample was confirmed via… More >

SORAYA SEGHIER^1,2,*, MOHAMMED BELBACHIR¹

Journal of Polymer Materials, Vol.38, No.3-4, pp. 205-218, 2021, DOI:10.32381/JPM.2021.38.3-4.3

Abstract In the present paper, we report the synthesis of a new amino polymer made of oxazolidinone using an efficient ecocatalyst called Maghnite-H⁺. The synthesis process contains two steps: the first consists to the preparation of an amino oxiran 3-(oxiran-ylmethyl) oxazolidin- 2-one (OMO) by a substitution reaction of epichlorhydrin by 2-oxazolidinone, the second step concerns a green polymerization of the resultant oxiran by a ring opening reaction catalysed by Maghnite-H⁺. The polymer have been successfully prepared and characterized by various techniques, such as ¹H NMR, ¹³C NMR, IR, which were used to elucidate the structural characteristics of the resulting polymers. The… More >

PARSOTAM H. PARSANIA^1,*, JIGNESH V. PATEL², JIGNESH P. PATEL³

Journal of Polymer Materials, Vol.40, No.3-4, pp. 271-284, 2023, DOI:10.32381/JPM.2023.40.3-4.9

Abstract Bisphenol-C epoxy crotonate resin was synthesized by reacting 8.09g epoxy resin of bisphenolC, and 2.15g crotonic acid using 25 mL 1,4-dioxane as a solvent, and 1 mL triethylamine as a catalyst at reflux temperature for 1-6 h. Solid epoxy crotonate (ECCR) is highly soluble in common organic solvents. ECCR was characterized by its acid (24.5-1.5 mg KOH/g) and hydroxyl (504.5-678.4 mg KOH/g) values. The structure of ECCR is supported by FTIR and 1 HNMR spectroscopic methods. A DSC endothermic transition at 229o C indicated melting followed by thermal polymerization of ECCR. ECCR is thermally stable up to 320o C and… More >

NEETU TRIPATHI, DIBYENDU S. BAG^*, MAYANK DWIVEDI

Journal of Polymer Materials, Vol.40, No.3-4, pp. 227-269, 2023, DOI:10.32381/JPM.2023.40.3-4.8

Abstract Over the last three decades, there has been considerable interest in the captivating mechanical properties displayed by auxetic materials, highlighting the advantages stemming from their distinct negative Poisson's ratio. The negative Poisson's ratio observed in auxetic polymeric materials is a result of the distinctive geometries of their unit cells. These unit cells, encompassing structures such as chiral, re-entrant, and rotating rigid configurations, are carefully engineered to collectively generate the desired auxetic behaviour. This comprehensive review article explores the field of auxetic polymeric materials, offering a detailed exploration of their geometries, fabrication methods, mechanical properties, and characterisation. The diverse applications of… More >

K. KRISHNAMOORTHY^a,*, N. PRABHU^b

Journal of Polymer Materials, Vol.40, No.3-4, pp. 215-226, 2023, DOI:10.32381/JPM.2023.40.3-4.7

Abstract The acoustic emission monitoring with artificial neural networks predicts the ultimate strength of glass/epoxy composite laminates using Acoustic Emission Data. The ultimate loads of all the specimens were used to characterise the emission of hits during failure modes. The six layered glass fiber laminates were prepared (in woven mat form) with epoxy as the binding medium by hand lay-up technique. At room temperature, with a pressure of 30 kg/cm², the laminates were cured. The laminates of standard dimensions as per ASTM D3039 for the tensile test were cut from the lamina. The Acoustic Emission (AE) test was conducted on these… More >

NURUL HAYATI YUSOF^1,*, DAZYLAH DARJI¹, TAN KIM SONG¹, NGHIEM THI THUONG²

Journal of Polymer Materials, Vol.39, No.1-2, pp. 151-166, 2022, DOI:10.32381/JPM.2022.39.1-2.10

Abstract In this work, a pure gum mould made of prevulcanized natural rubber/cloisite-Na⁺ nanocomposite (PVNR/CN) was prepared and characterized for ornament application. The suitable conditions to prepare PVNR/CN latex mixtures and the properties of the resulting PVNR/CN nanocomposites were investigated. The optimum CN concentration in the latex mixture was 1.0 phr, with the properties of 60 wt% total solid content, more than 600 sec mechanical stability time, lower than 350 cP Brookfield viscosity, and pH 10. The properties of PVNR/CN nanocomposite showed high strength, moderate hardness, and good thermal stability. The morphology by TEM showed well dispersion of CN particles in… More >