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  • Open Access

    ARTICLE

    Green Chemistry of Cellulose Acetate Membrane Plasticized by Citric Acid and Succinonitrile for Lithium-Ion Battery Application

    Christin Rina Ratri1,2, Qolby Sabrina2, Adam Febriyanto Nugraha1, Sotya Astutiningsih1, Mochamad Chalid1,*

    Journal of Renewable Materials, Vol.12, No.11, pp. 1863-1878, 2024, DOI:10.32604/jrm.2024.055492 - 22 November 2024

    Abstract Commercial lithium-ion batteries (LIBs) use polyolefins as separators. This has led to increased research on separators composed of renewable materials such as cellulose and its derivatives. In this study, the ionic conductivity of cellulose acetate (CA) polymer electrolyte membranes was enhanced via plasticization with citric acid and succinonitrile. The primary objective of this study was to evaluate the effectiveness of these plasticizers in improving cellulose-based separator membranes in LIBs. CA membranes were fabricated using solution casting technique and then plasticized with various concentrations of plasticizers. The structural, thermal, and electrochemical properties of the resulting membranes… More > Graphic Abstract

    Green Chemistry of Cellulose Acetate Membrane Plasticized by Citric Acid and Succinonitrile for Lithium-Ion Battery Application

  • Open Access

    ARTICLE

    Enhanced Dye Adsorption and Bacterial Removal of Magnetic Nanoparticle-Functionalized Bacterial Cellulose Acetate Membranes

    Heru Suryanto1,2,*, Daimon Syukri3, Fredy Kurniawan4, Uun Yanuhar5, Joseph Selvi Binoj6, Sahrul Efendi2, Fajar Nusantara2, Jibril Maulana7, Nico Rahman Caesar5, Komarudin Komarudin2

    Journal of Renewable Materials, Vol.12, No.9, pp. 1605-1624, 2024, DOI:10.32604/jrm.2024.054047 - 25 September 2024

    Abstract Utilizing biomass waste as a potential resource for cellulose production holds promise in mitigating environmental consequences. The current study aims to utilize pineapple biowaste extract in producing bacterial cellulose acetate-based membranes with magnetic nanoparticles (Fe3O4 nanoparticles) through the fermentation and esterification process and explore its characteristics. The bacterial cellulose fibrillation used a high-pressure homogenization procedure, and membranes were developed incorporating 0.25, 0.50, 0.75, and 1.0 wt.% of Fe3O4 nanoparticles as magnetic nanoparticle for functionalization. The membrane characteristics were measured in terms of Scanning Electron Microscope, X-ray diffraction, Fourier Transform Infrared, Vibrating Sample Magnetometer, antibacterial activity, bacterial… More > Graphic Abstract

    Enhanced Dye Adsorption and Bacterial Removal of Magnetic Nanoparticle-Functionalized Bacterial Cellulose Acetate Membranes

  • Open Access

    ARTICLE

    Novel Sustainable Cellulose Acetate Based Biosensor for Glucose Detection

    M. F. Elkady1,2,*, E. M. El-Sayed2, Mahmoud Samy3, Omneya A. Koriem1, H. Shokry Hassan4,5

    Journal of Renewable Materials, Vol.12, No.2, pp. 369-380, 2024, DOI:10.32604/jrm.2023.046585 - 11 March 2024

    Abstract In this study, green zinc oxide (ZnO)/polypyrrole (Ppy)/cellulose acetate (CA) film has been synthesized via solvent casting. This film was used as supporting material for glucose oxidase (GOx) to sensitize a glucose biosensor. ZnO nanoparticles have been prepared via the green route using olive leaves extract as a reductant. ZnO/Ppy nanocomposite has been synthesized by a simple in-situ chemical oxidative polymerization of pyrrole (Py) monomer using ferric chloride (FeCl3) as an oxidizing agent. The produced materials and the composite films were characterized using X-ray diffraction analysis (XRD), scanning electron microscope (SEM), Fourier transform infrared (FTIR) and… More > Graphic Abstract

    Novel Sustainable Cellulose Acetate Based Biosensor for Glucose Detection

  • Open Access

    ARTICLE

    Cellulose Acetate/Carbon Nanotube Composites by Melt Mixing

    A. Delgado-Lima, M. C. Paiva*, A. V. Machado

    Journal of Renewable Materials, Vol.5, No.2, pp. 145-153, 2017, DOI:10.7569/JRM.2017.634104

    Abstract Cellulose acetate (CA) is produced from a natural polymer and presents excellent properties, finding applications in a variety of areas. Unlike cellulose, CA is melt processable and may be molded into parts and formed into fibers or films. In this context, the production of conductive CA composites that may be processable and integrated into parts to provide specific functionalities is an area of increasing interest. The present work aims to prepare electrically conductive composites based on CA and carbon nanotubes (CNTs) by melt mixing. The nanocomposites were produced with pure and pyrrolidine-functionalized nanotubes, using a More >

  • Open Access

    ARTICLE

    Cellulose Acetate Blends – Effect of Plasticizers on Properties and Biodegradability

    Vu Thanh Phuong1,2, Steven Verstichel3, Patrizia Cinelli1,4, Irene Anguillesi1, Maria-Beatrice Coltelli1, Andrea Lazzeri1,*

    Journal of Renewable Materials, Vol.2, No.1, pp. 35-41, 2014, DOI:10.7569/JRM.2013.634136

    Abstract Cellulose acetate (CDA) cannot be processed as raw material because it starts to decompose before melting. Triacetin and diacetin were tested to improve CDA processing versus conventional phthalate as environmentally sustainable plasticizers, because of their low toxicity and fast biodegradability. The addition of triacetin and diacetin allowed melt processing of CDA and the results of tensile tests outlined their effect as plasticizers. The values of mechanical properties were compatible with the requirements for applications in rigid packaging. From the results of biodegradation tests it can be concluded that for pure cellulose acetate, complete biodegradation was More >

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