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  • Open Access

    ARTICLE

    Kinetics of the Demineralization Reaction of Deproteinized Lobster Shells Using CO2

    Miguel Ángel Ramírez1, Luis Alfonso, Patricia González2, Juan Reinerio Fagundo2, Margaret Suarez3, Clara Melian3, Tania Rodríguez1, Carlos Peniche4,*

    Journal of Renewable Materials, Vol.3, No.1, pp. 73-80, 2015, DOI:10.7569/JRM.2014.634116

    Abstract The demineralization kinetics of deproteinized lobster shells using CO2 were studied. Demineralization reaction proceeds until the concentration of Ca+2 in solution reaches an equilibrium value. The introduction of a cation exchange resin (cationite), in an open system for CO2 , allows replacement of the solution Ca2+ ions by Na+ ions, whereby the equilibrium shifts and an effective dissolution of the exoskeletons’ calcite is achieved. The mathematical relationships between the conductivity of the solution and the concentrations of major ions, the rate constants and kinetic parameters of the reaction in the absence and presence of the resin were obtained. It was… More >

  • Open Access

    ARTICLE

    Bulk CO2-based Amorphous Triols Used for Designing Biocompatible Shape-Memory Polyurethanes

    Shunjie Liu1,2, Yusheng Qin1,*, Xianhong Wang1,*, Fosong Wang1

    Journal of Renewable Materials, Vol.3, No.2, pp. 101-112, 2015, DOI:10.7569/JRM.2014.634140

    Abstract Precursors with sharp crystalline transition temperature have attracted signifi cant attention in the fi eld of shape-memory materials; however, seldom have reports been related to amorphous ones with industrial application prospects. This study introduced a new family of amorphous CO2 -based hydroxyl-telechelic three-armed oligo(carbonate-ether) triol (Triol) with controllable molecular weight (Mn) and carbonate unit content (CU), which was coupled with PEG and 1,6-hexamethylene diisocyanate (HDI) to afford crosslinked polyurethanes (PU) networks with well-defi ned architecture. A crosslinking point was provided by Triol and PEG was used to afford networks some crystallinity. The resulting networks were characterized using attentuated total refl… More >

  • Open Access

    ARTICLE

    Study on Biological Pathway of Carbon Dioxide Methanation Based on Microbial Electrolysis Cell

    Guanwen Ding, Qifen Li*, Liting Zhang, Yuanbo Hou, Xiaoxiao Yan

    Journal of Renewable Materials, Vol.11, No.1, pp. 197-207, 2023, DOI:10.32604/jrm.2023.020277

    Abstract Realization of CO2 resource utilization is the main development direction of CO2 reduction. The CO2 methanation technology based on microbial electrolysis cell (MEC) has the characteristics of ambient temperature and pressure, green and low-carbon, which meets the need of low-carbon energy transition. However, the lack of the system such as the change of applied voltage and the reactor amplification will affect the methane production efficiency. In this research, the efficiency of methane production with different applied voltages and different types of reactors was carried out. The results were concluded that the maximum methane production rate of the H-type two-chamber microbial… More >

  • Open Access

    ARTICLE

    Monitoring and Prediction of Indoor Air Quality for Enhanced Occupational Health

    Adela POP (Puscasiu), Alexandra Fanca*, Dan Ioan Gota, Honoriu Valean

    Intelligent Automation & Soft Computing, Vol.35, No.1, pp. 925-940, 2023, DOI:10.32604/iasc.2023.025069

    Abstract The amount of moisture in the air is represented by relative humidity (RH); an ideal level of humidity in the interior environment is between 40% and 60% at temperatures between 18° and 20° Celsius. When the RH falls below this level, the environment becomes dry, which can cause skin dryness, irritation, and discomfort at low temperatures. When the humidity level rises above 60%, a wet atmosphere develops, which encourages the growth of mold and mites. Asthma and allergy symptoms may occur as a result. Human health is harmed by excessive humidity or a lack thereof. Dehumidifiers can be used to… More >

  • Open Access

    ARTICLE

    Numerical Analysis of Labyrinth Seal Performance for the Impeller Backface Cavity of a Supercritical CO2 Radial Inflow Turbine

    Jinguang Yang, Feng Zhao, Min Zhang*, Yan Liu, Xiaofang Wang

    CMES-Computer Modeling in Engineering & Sciences, Vol.126, No.3, pp. 935-953, 2021, DOI:10.32604/cmes.2021.014176

    Abstract For a radial inflow turbine (RIT), leakage flow in impeller backface cavity has critical impacts on aerodynamic performance of the RIT and axial force acting on the RIT impeller. In order to control this leakage flow, different types of labyrinth seals are numerically studied in this paper based on a supercritical carbon dioxide (S-CO2) RIT. The effects of seal clearance and cavity outlet pressure are first analyzed, and the impacts of seal design parameters, including height, number and shape of seal teeth, are evaluated. Results indicate that adding labyrinth seal can improve cavity pressure and hence adequately inhibits leakage flow.… More >

  • Open Access

    ARTICLE

    Microparticle Effect of Carbon Dioxide Hydrate Crystal Nucleus in Reaction Kettle

    Yujie Bai1,*, Youquan Huang3, Guangsheng Cao1, Xiaohan Nan1, Qingchao Cheng1, Lei Wang2, Tong Du4

    Journal of Renewable Materials, Vol.9, No.4, pp. 651-669, 2021, DOI:10.32604/jrm.2021.014479

    Abstract This study analyzed the partial effect of carbon dioxide hydrate in reaction kettle experiments. The particle and bubble characteristics of the crystal nucleus during carbon dioxide hydrate decomposition were observed under the microscope. The results showed that in the temperature range of 0.5°C–3.5°C, the pressure range of 3 MPa– 5.5 MPa, phase characteristics in the reaction kettle changed in a complex fashion during carbon dioxide hydrate formation. During hydrate decomposition, numerous carbon dioxide bubbles were produced, mainly by precipitation at high temperatures or in the hydrate cage structure. The hydrate crystal nucleus initially exhibited fluidity in the reaction. However, as… More >

  • Open Access

    ARTICLE

    Applying ANN, ANFIS and LSSVM Models for Estimation of Acid Solvent Solubility in Supercritical CO2

    Amin Bemani1, Alireza Baghban2, Shahaboddin Shamshirband3, 4, *, Amir Mosavi5, 6, 7, Peter Csiba7, Annamaria R. Varkonyi-Koczy5, 7

    CMC-Computers, Materials & Continua, Vol.63, No.3, pp. 1175-1204, 2020, DOI:10.32604/cmc.2020.07723

    Abstract In the present work, a novel machine learning computational investigation is carried out to accurately predict the solubility of different acids in supercritical carbon dioxide. Four different machine learning algorithms of radial basis function, multi-layer perceptron (MLP), artificial neural networks (ANN), least squares support vector machine (LSSVM) and adaptive neuro-fuzzy inference system (ANFIS) are used to model the solubility of different acids in carbon dioxide based on the temperature, pressure, hydrogen number, carbon number, molecular weight, and the dissociation constant of acid. To evaluate the proposed models, different graphical and statistical analyses, along with novel sensitivity analysis, are carried out.… More >

  • Open Access

    ARTICLE

    Numerical Study on Rock Breaking Mechanism of Supercritical CO2 Jet Based on Smoothed Particle Hydrodynamics

    Xiaofeng Yang1, *, Yanhong Li1, Aiguo Nie1, Sheng Zhi2, Liyuan Liu3

    CMES-Computer Modeling in Engineering & Sciences, Vol.122, No.3, pp. 1141-1157, 2020, DOI:10.32604/cmes.2020.08538

    Abstract Supercritical carbon dioxide (Sc-CO2) jet rock breaking is a nonlinear impact dynamics problem involving many factors. Considering the complexity of the physical properties of the Sc-CO2 jet and the mesh distortion problem in dealing with large deformation problems using the finite element method, the smoothed particle hydrodynamics (SPH) method is used to simulate and analyze the rock breaking process by Sc-CO2 jet based on the derivation of the jet velocity-density evolution mathematical model. The results indicate that there exisits an optimal rock breaking temperature by Sc-CO2. The volume and length of the rock fracture increase with the rising of the… More >

  • Open Access

    ABSTRACT

    Comparative Study on Dry Reforming of Methane Over Co-M (M=Ce, Fe, Zr) Catalysts Supported on N-Doped Activated Carbon

    Yinghui Sun1, Guojie Zhang1,2,*

    The International Conference on Computational & Experimental Engineering and Sciences, Vol.22, No.1, pp. 105-105, 2019, DOI:10.32604/icces.2019.05173

    Abstract A series of Co-M (M = Ce, Fe, Zr) binary oxides supported on N-doped catalysts were prepared by impregnation methods and tested for DRM reaction. Moreover, the influence of Co and Ce atomic contents in the catalysts on DRM performance was investigated. Significant enhancement of activity performance over Ce promoted 3Co-1Ce/AC-N catalyst was observed. Compared with Fe and Zr, the catalyst with 1/4 mol% of Ce showed the highest activity and was higher than the supported Co catalyst. The calcined and spent catalysts were characterized by XPS, H2-TPR, TEM and EDX mapping studies. The characterization results demonstrated that the improved… More >

  • Open Access

    ARTICLE

    Supercritical Carbon Dioxide Treated Kenaf Bast Pulp Fiber Reinforcement in Epoxy Composite

    N. A. Sri Aprilia1, M. S. Nurul Atiqah2, Zhari Ismail3, C. Y. Loo2, Chaturbhuj K. Saurabh2, Rudi Dungani4, Abdul Khalil H.P.S2*

    Journal of Renewable Materials, Vol.5, No.5, pp. 380-387, 2017, DOI:10.7569/JRM.2017.634130

    Abstract Due to environmental concerns, green composites have become a highly researched material. In the present study, kenaf fiber was used as reinforcement in epoxy-based composite with weight fraction ranges from 0, 5, 10, and 15% (w/w of resin). The ratio of epoxy to hardener was 65:32.5. Prior to incorporation, kenaf bast fiber underwent Soda-AQ pulping followed by total chlorine-free bleaching (OAZP sequence). The obtained pulp was then subjected to supercritical carbon dioxide extraction (SCE) treatment. It was observed that epoxy composite with 10% of fiber loading demonstrated the highest mechanical properties with a tensile strength of 64 MPa, tensile modulus… More >

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