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  • Open Access

    ARTICLE

    Preparation and characterization of ZnO@MoS2 nanocomposites: investigating photoelectrical, electrocatalytic, and electrochemical behaviors

    J. M. Shi*, H. F. Zhang, H. C. Wang

    Chalcogenide Letters, Vol.21, No.3, pp. 263-274, 2024, DOI:10.15251/CL.2024.213.263

    Abstract This study presents the synthesis and characterization of 3D ZnO@MoS2 nanocomposites, demonstrating their superior performance in photoelectrochemical applications. Employing a combination of hydrothermal and solvothermal methods, the research focuses on creating heterostructures with optimized interfacial characteristics. The ZnO@MoS2 composites show a substantial increase in photocurrent density (1.02 mA/cm²), compared to ZnO nanorods (0.32 mA/cm²), underlining enhanced charge separation efficiency. In electrocatalytic hydrogen evolution, the heterostructures exhibit a lower onset potential (-175 mV vs RHE) and reduced Tafel slope (51 mV/dec), indicating improved catalytic activity over MoS2 nanosheets. Additionally, the composites demonstrate a significant increase in electrochemical capacitance (398 More >

  • Open Access

    ARTICLE

    Structural and impedance analysis of tin-sulphide (SnS) nanoparticles produced with the help of hydrothermal process

    Z. Khana, A. D. Khalidb,*, M. I. Khanc, B. Parveena, Ihab M. Moussad, M. S. Hassane, N.-ur-Rehmanf, A. K. Khanf, S. Mumtazg

    Chalcogenide Letters, Vol.21, No.11, pp. 933-943, 2024, DOI:10.15251/CL.2024.2111.933

    Abstract The three samples of SnS with different molarity 1ml, 0.5ml and 0.25ml were prepared by hydrothermal method. The prepared samples were characterized by XRD, SEM and impedance spectroscopies. XRD confirmed the cubic and orthorhombic structure of SnS. The average size of nanoparticles was noted to be about 12.77 nm, 16.43 nm and 16.44 nm at 140 °C. These nanoparticles were of cubic and orthorhombic forms. Average strain came out to be 0.215, 0.142 and 0.140. This result shows that by changing molarity, crystal structure of SnS can be changed. Crystallite size is increasing with decreasing… More >

  • Open Access

    ARTICLE

    Hydrothermally synthesized highly stable binary manganese magnesium sulfide (MnMgS) composite with carbon nanotubes for high-performance supercapattery applications

    M. A. Sadia,*, A. Mahmoodb, W. Al-Masryb, C. W. Dunnillc, N. Mahmoodd

    Chalcogenide Letters, Vol.21, No.12, pp. 965-976, 2024, DOI:10.15251/CL.2024.2112.965

    Abstract The device which combines the outcomes supercapacitor (SC) and battery is known as supercapattery. Due to their high conductivity, sensitivity, and storage capacity, carbon nanotubes have drawn attention in energy storage (EES) applications. To achieve highperformance supercapattery, this study used an electrode based on carbon nanotubes (CNTs) and manganese magnesium sulfide (MnMgS). It showed 963 C/g specific capacity which is significantly greater than the reference sample's value of 1 A/g. The supercapattery is engineered using the CNT-doped MnMgS electrode (MnMgS/CNT//AC), which has a specific capacity (Cs) of 268 Cg-1 at 1 Ag-1 current density. A significantly higher More >

  • Open Access

    ARTICLE

    Voltage and frequency controlled Ge/SeO2 thin film transistors designed as rectifiers, negative capacitance and negative conductance sources

    A. F. Qasrawia,c,*, Hazem K. Khanfarb

    Chalcogenide Letters, Vol.20, No.3, pp. 177-186, 2023, DOI:10.15251/CL.2023.203.177

    Abstract Herein voltage and frequency controlled thin film transistors fabricated by depositing SeO2 onto germanium thin crystals are reported. For these devices measurements of the current-voltage characteristics revealed a biasing dependent rectification ratios. The devices showed metal-oxide-semiconductor character under reverse biasing conditions. In addition, the biasing dependent capacitance and conductance spectral studies in the frequency domain of 20M-1000MHz has shown the possibility of switching the capacitance and negative conductance from negative mode to positive mode. The features of the Ge/SeO2 devices make them attractive for use in electronic circuits as parasitic capacitive circuit elements, noise reducers, signal More >

  • Open Access

    ARTICLE

    N-Doped rGO-Like Carbon Prepared from Coconut Shell: Structure and Specific Capacitance

    Imam Khambali1,2,*, Budhi Priyanto1,2, Retno Asih1, Malik Anjelh Baqiya1, Muhammad Mahyiddin Ramli3, Nurul Huda Osman4, Sarayut Tunmee5, Hideki Nakajima5, Triwikantoro1, Mochamad Zainuri1, Darminto1,*

    Journal of Renewable Materials, Vol.11, No.4, pp. 1823-1833, 2023, DOI:10.32604/jrm.2023.025026 - 01 December 2022

    Abstract An rGO−like carbon compound has been synthesized from biomass, i.e., old coconut shell, by a carbonization process followed by heating at 400°C for 5 h. The nitrogen doping was achieved by adding the urea (CH4N2O) and stirring at 70°C for 14 h. The morphology and structure of the rGO-like carbon were investigated by electron microscopies and Raman spectroscopy. The presence of C-N functional groups was analyzed by Fourier transform infrared and synchrotron X-ray photoemission spectroscopy, while the particle and the specific capacitance were measured by particle sizer and cyclic voltammetry. The highest specific capacitance of 72.78 More > Graphic Abstract

    N-Doped rGO-Like Carbon Prepared from Coconut Shell: Structure and Specific Capacitance

  • Open Access

    ARTICLE

    Preparation of Eco-Friendly High-Performance Manganese Dioxide Supercapacitors by Linear Sweep Voltammetry

    Junshan Zhao1,#, Yihan Shi1,#, Ming Zhang1, Liu Zhang1, Xumei Cui1, Xinghua Zhu2, Jitong Su1, Dandan Jing1, Dingyu Yang1,*

    Journal of Renewable Materials, Vol.11, No.1, pp. 79-91, 2023, DOI:10.32604/jrm.2023.022030 - 10 August 2022

    Abstract In this paper, the non-polluting, non-toxic, and eco-friendly material-MnO2 electrodes were deposited on three-dimensional porous nickel (Ni) foam by linear sweep voltammetry, and the entire electrodeposition process did not require sintering of the material, which was fast and convenient while avoiding unnecessary energy consumption and thus was environmentally friendly. Scanning electron microscopy (SEM) and transmission electron microscopy were used to examine the surface and microscopic characteristics of each sample (TEM). Chronoamperometry (CA), cyclic voltammetry (CV), galvanostatic charge/discharge (GCD), and electrochemical impedance spectroscopy (EIS) were then used to determine the electrochemical characteristics of the manufactured samples. The More >

  • Open Access

    ARTICLE

    Residual Autoencoder Deep Neural Network for Electrical Capacitance Tomography

    Wael Deabes1,2,*, Kheir Eddine Bouazza1,3

    CMC-Computers, Materials & Continua, Vol.73, No.3, pp. 6307-6326, 2022, DOI:10.32604/cmc.2022.030420 - 28 July 2022

    Abstract Great achievements have been made during the last decades in the field of Electrical Capacitance Tomography (ECT) image reconstruction. However, there is still a need to make these image reconstruction results faster and of better quality. Recently, Deep Learning (DL) is flourishing and is adopted in many fields. The DL is very good at dealing with complex nonlinear functions and it is built using several series of Artificial Neural Networks (ANNs). An ECT image reconstruction model using DNN is proposed in this paper. The proposed model mainly uses Residual Autoencoder called (ECT_ResAE). A large-scale dataset… More >

  • Open Access

    ARTICLE

    Visualization Detection of Solid–Liquid Two-Phase Flow in Filling Pipeline by Electrical Capacitance Tomography Technology

    Ningbo Jing1, Mingqiao Li1, Lang Liu2,*, Yutong Shen1, Peijiao Yang1, Xuebin Qin1

    CMES-Computer Modeling in Engineering & Sciences, Vol.131, No.1, pp. 465-476, 2022, DOI:10.32604/cmes.2022.018965 - 24 January 2022

    Abstract During mine filling, the caking in the pipeline and the waste rock in the filling slurry may cause serious safety accidents such as pipe blocking or explosion. Therefore, the visualization of the inner mine filling of the solid–liquid two-phase flow in the pipeline is important. This paper proposes a method based on capacitance tomography for the visualization of the solid–liquid distribution on the section of a filling pipe. A feedback network is used for electrical capacitance tomography reconstruction. This reconstruction method uses radial basis function neural network fitting to determine the relationship between the capacitance… More >

  • Open Access

    ARTICLE

    Image Reconstruction for ECT under Compressed Sensing Framework Based on an Overcomplete Dictionary

    Xuebin Qin1,*, Yutong Shen1, Jiachen Hu1, Mingqiao Li1, Peijiao Yang1, Chenchen Ji1, Xinlong Zhu2

    CMES-Computer Modeling in Engineering & Sciences, Vol.130, No.3, pp. 1699-1717, 2022, DOI:10.32604/cmes.2022.018234 - 30 December 2021

    Abstract Electrical capacitance tomography (ECT) has great application potential in multiphase process monitoring, and its visualization results are of great significance for studying the changes in two-phase flow in closed environments. In this paper, compressed sensing (CS) theory based on dictionary learning is introduced to the inverse problem of ECT, and the K-SVD algorithm is used to learn the overcomplete dictionary to establish a nonlinear mapping between observed capacitance and sparse space. Because the trained overcomplete dictionary has the property to match few features of interest in the reconstructed image of ECT, it is not necessary More >

  • Open Access

    ARTICLE

    Damage Detection for CFRP Based on Planar Electrical Capacitance Tomography

    Wenru Fan, Chi Wang*

    Structural Durability & Health Monitoring, Vol.14, No.4, pp. 303-314, 2020, DOI:10.32604/sdhm.2020.011009 - 04 December 2020

    Abstract Due to the widespread use of carbon fiber reinforced polymer/plastic (CFRP), the nondestructive structural health monitoring for CFRP is playing an increasingly essential role. As a nonradiative, noninvasive and nondestructive detection technique, planar electrical capacitance tomography (PECT) electrodes array is employed in this paper to reconstruct the damage image according to the calculated dielectric constant changes. The shape and duty ratio of PECT electrodes are optimized according to the relations between sensitivity distribution and the dielectric constant of different anisotropic degrees. The sensitivity matrix of optimized PECT sensor is more uniform as the result shows, More >

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