Rachmannu Ilham¹, Fataty Kurnia Rahmah¹, Nurul Faradilah Said², Mohamad Buang Budiono², Suprapto Suprapto^1,*

Journal of Renewable Materials, Vol.12, No.11, pp. 1895-1909, 2024, DOI:10.32604/jrm.2024.055602 - 22 November 2024

Abstract This study investigated the efficiency of activated carbon from Pangium edule shells for removing phosphate from aqueous solution. The adsorption capacity of the synthesized activated carbon was determined to be 19.8392 mg g⁻¹. Various isotherm models were used to analyze the adsorption process, Henry, Freundlich, SIP, and Halsey isotherm fitting showed r² values close to 1.0. These isotherms indicated a combination of physisorption and chemisorption mechanisms, with heterogeneity and multilayer formation playing important roles. A pseudo-second-order model described the adsorption kinetics well, suggesting chemisorption as the dominant mechanism with an r² value of 1.0 and a rate constant… More >

Hao Yu^1,*, Mengcheng Huang¹

The International Conference on Computational & Experimental Engineering and Sciences, Vol.30, No.2, pp. 1-1, 2024, DOI:10.32604/icces.2024.011120

Abstract Understanding the competitive adsorption behavior of CO₂ and CH₄ in shale nanopores is crucial for enhancing the recovery of shale gas and sequestration of CO₂, which is determined by both the inherent characteristics of the molecules and external environmental factors such as pore size, temperature, and partial pressures of CO₂ and CH₄. While the competitive adsorption behavior of CO₂/CH₄ has been analyzed by previous studies, a comprehensive understanding from the perspective of molecular kinetic theory and the efficient calculation for competitive adsorption behavior considering various geological situations is still challenging, limited by the huge computation cost of classical… More >

Marat Satayev^1,2,*, Abdugani Azimov², Arnold Brener², Nina Alekseyeva¹, Zulfia Shakiryanova²

Frontiers in Heat and Mass Transfer, Vol.22, No.5, pp. 1533-1558, 2024, DOI:10.32604/fhmt.2024.052901 - 30 October 2024

Abstract The goal of this work is, first of all, to construct a mathematical model of the mass transfer process in porous adsorption layers, taking into account the fact that in most cases the adsorption process is carried out in non-stationary technological modes, which requires a clear description of its various stages. The scientific contribution of the novel model is based on a probability approach allowing for deriving a differential equation that takes into account the diffusion migration of adsorbed particles. Solving this equation allows us to calculate the reduced degree of the adsorption surface coverage… More >

Heru Suryanto^1,2,*, Daimon Syukri³, Fredy Kurniawan⁴, Uun Yanuhar⁵, Joseph Selvi Binoj⁶, Sahrul Efendi², Fajar Nusantara², Jibril Maulana⁷, Nico Rahman Caesar⁵, Komarudin Komarudin²

Journal of Renewable Materials, Vol.12, No.9, pp. 1605-1624, 2024, DOI:10.32604/jrm.2024.054047 - 25 September 2024

Abstract Utilizing biomass waste as a potential resource for cellulose production holds promise in mitigating environmental consequences. The current study aims to utilize pineapple biowaste extract in producing bacterial cellulose acetate-based membranes with magnetic nanoparticles (Fe₃O₄ nanoparticles) through the fermentation and esterification process and explore its characteristics. The bacterial cellulose fibrillation used a high-pressure homogenization procedure, and membranes were developed incorporating 0.25, 0.50, 0.75, and 1.0 wt.% of Fe₃O₄ nanoparticles as magnetic nanoparticle for functionalization. The membrane characteristics were measured in terms of Scanning Electron Microscope, X-ray diffraction, Fourier Transform Infrared, Vibrating Sample Magnetometer, antibacterial activity, bacterial… More > Graphic Abstract

Annesha Kar¹, Niranjan Karak^1,2,*

Journal of Renewable Materials, Vol.12, No.9, pp. 1507-1540, 2024, DOI:10.32604/jrm.2024.052220 - 25 September 2024

Abstract The pursuit of incorporating eco-friendly reinforcing agents in polymer composites has accentuated the exploration of various natural biomass-derived materials. The burgeoning environmental crisis spurred by the discharge of synthetic dyes into wastewater has catalyzed the search for effective and sustainable treatment technologies. Among the various sorbent materials explored, biochar, being renewable, has gained prominence due to its excellent adsorption properties and environmental sustainability. It has also emerged as a focal point for its potential to replace other conventional reinforcing agents, viz., fumed silica, aluminum oxide, treated clays, etc. This study introduces a novel class of… More > Graphic Abstract

I. Putu Mahendra^*, Kartika Dinita

Journal of Renewable Materials, Vol.12, No.8, pp. 1369-1382, 2024, DOI:10.32604/jrm.2024.053001 - 06 September 2024

Abstract TEMPO/NaOCl/NaBr treatment significantly increased the number of negative charges on the cellulose surface. Two concentrations of NaOCl, 5 and 30 mmol/g of cellulose, were used in this study. The number of carboxyl groups in the two cellulosic samples oxidized using TEMPO/NaOCl/NaBr was 0.5160 and 1.8461 mmol/g of cellulose, respectively. The oxidized cellulose samples treated with 5 and 30 mmol/g NaOCl exhibited higher crystallinity, at 81.15% and 80.14%, respectively, compared to untreated cellulose, which had a crystallinity of 75.95%. The pH effect indicated that the highest adsorption capacity for methylene blue was achieved under alkaline conditions… More > Graphic Abstract

Guochen Xu^*

FDMP-Fluid Dynamics & Materials Processing, Vol.20, No.8, pp. 1915-1924, 2024, DOI:10.32604/fdmp.2024.048337 - 06 August 2024

Abstract Microscopic pore structure in continental shale oil reservoirs is characterized by small pore throats and complex micro-structures. The adsorption behavior of hydrocarbons on the pore walls exhibits unique physical and chemical properties. Therefore, studying the adsorption morphology of hydrocarbon components in nanometer-sized pores and clarifying the exploitation limits of shale oil at the microscopic level are of great practical significance for the efficient development of continental shale oil. In this study, molecular dynamics simulations were employed to investigate the adsorption characteristics of various single-component shale oils in inorganic quartz fissures, and the influence of pore… More >

Nabila Eka Yuningsih, Latifa Ariani, Suprapto Suprapto, Ita Ulfin, Harmami Harmami, Hendro Juwono, Yatim Lailun Ni’mah^*

Journal of Renewable Materials, Vol.12, No.5, pp. 981-992, 2024, DOI:10.32604/jrm.2024.049109 - 17 July 2024

Abstract In this research, activated carbon from mangosteen peel has been synthesized using sulfuric acid as an activator. The adsorption performance of the activated carbon was optimized using malachite green dye as absorbate. Malachite green dye waste is a toxic and non-biodegradable material that damages the environment. Optimization of adsorption processes was carried out using Response Surface Methodology (RSM) with a Box-Behnken Design (BBD). The synthesized activated carbon was characterized using FTIR and SEM instruments. The FTIR spectra confirmed the presence of a sulfonate group (-SOH) in the activated carbon, indicating that the activation process using… More >

Xiaoyu Chen^*

Journal of Renewable Materials, Vol.12, No.4, pp. 815-826, 2024, DOI:10.32604/jrm.2024.048470 - 12 June 2024

Abstract A novel core-shell hydrogel bead was fabricated for effective removal of methylene blue dye from aqueous solutions. The core, made of sodium alginate-g-polyacrylamide and attapulgite nanofibers, was cross-linked by Calcium ions (Ca). The shell, composed of a chitosan/activated carbon mixture, was then coated onto the core. Fourier transform infrared spectroscopy confirmed the grafting polymerization of acrylamide onto sodium alginate. Scanning electron microscopy images showed the core-shell structure. The core exhibited a high water uptake ratio, facilitating the diffusion of methylene blue into the core. During the diffusion process, the methylene blue was first adsorbed by More > Graphic Abstract

Ninis Hadi Haryanti^1,*, Eka Suarso¹, Tetti N. Manik¹, Suryajaya¹, Nurlita Sari¹, Darminto²

Journal of Renewable Materials, Vol.12, No.2, pp. 203-214, 2024, DOI:10.32604/jrm.2023.043549 - 11 March 2024

Abstract Nipa palm is one of the non-wood plants rich in lignocellulosic content. In this study, palm fronds were converted into activated carbon, and their physical, chemical, and morphological properties were characterized. The resulting activated carbon was then applied as an adsorbent of Fe metal in peat water. The carbonization process was carried out for 60 min, followed by sintering at 400°C for 5 h with a particle size of 200 mesh. KOH and H₃PO₄ were used in the chemical activation process for 24 h. KOH-activated carbon contained 6.13% of moisture, 4.55% of ash, 17.02% of volatile… More > Graphic Abstract