P. Kaushik^a,*, A. Devi^b, H. Singh^a

Chalcogenide Letters, Vol.22, No.3, pp. 197-204, 2025, DOI:10.15251/CL.2025.223.197

Abstract The structural properties of bulk as well as thin films of nanostructured Bi₁Te₁₅Se_84-x Pb_x (0 ≤ x ≤ 8) glassy alloys has been studied in this paper. Conventional melt quenching method is employed to prepare the samples of Bi₁Te₁₅Se_84-x Pb_x (0 ≤ x ≤ 8) alloys. Thin films with thickness of approximately 158nm of the obtained bulk compositions were deposited on dry cleaned glass substrates by thermal evaporation technique. The structural characterization was carried out using XRD and SEM. Energy dispersive X-ray spectroscopy (EDX) indicates that samples are nearly stoichiometric. X-ray diffraction patterns indicate that they are More >

H. R. Shakir^a, O. A. Chichan^b, M. S. Sada^c,*, S. A. Hussein^d, S. S. Chiad^e, N. F. Habubi^f, Y. H. Kadhim^g, M. Jadan^h,i

Chalcogenide Letters, Vol.22, No.1, pp. 77-89, 2025, DOI:10.15251/CL.2025.221.77

Abstract CdS, and CdS: Al were grown onto glass bases via Chemical spray pyrolysis (CSP). XRD analysis of CdS films indicates a polycrystalline hexagonal structure with a predominant orientation of the (101) plane. The strain decreased from 28.55 to 25.66, and the grain size of undoped CdS films was around (13.51–12.14) nm as Al content rose. According to the results of AFM, CdS, CdS:2% Al, and CdS:4% Al all exhibit smooth surfaces with decreasing particle size in the range of (78.46), (69.75), and (42.20) nm, respectively. The root-mean-square roughness values for CdS and CdS:4% Al were… More >

A. M. Abdel-Daiem^a, M. Ahmed^a,, E. R. Shaaban^b,

Chalcogenide Letters, Vol.22, No.2, pp. 131-142, 2025, DOI:10.15251/CL.2025.222.131

Abstract This paper investigates the impact of reduced graphene oxide (rGO) addition on the structural and optical properties of ZnS nanocomposites. The study began with the synthesis of graphene oxide (GO) through the oxidation of natural graphite powder. This process involved using potassium permanganate in a mixture of sulfuric and phosphoric acids, maintained at 50°C for 48 hours. The reaction was terminated using hydrogen peroxide, followed by purification and drying, yielding 1.5 grams of GO. The preparation of ZnS/GO nanocomposites involved dissolving zinc acetate and varying quantities of GO in water, adjusting the pH, and incorporating… More >

D. M. A. Latiff, B. A. Ahmed, S. M. Ali, K. A. Jasim^*

Chalcogenide Letters, Vol.22, No.6, pp. 521-528, 2025, DOI:10.15251/CL.2025.226.521

Abstract In this paper, the effect of sulfur substitution by arsenic on the structural, optical properties of thin films of the trivalent chalcogenide Se₆₆S_44-xAs_x at different concentrations (where x = 0, 8, 16, and 24 at %) was studied. Thin films with a thickness of (300±10 nm) were prepared using thermal evaporation of bulk samples. Structural examinations were performed using XRD and AFM techniques. All the studied film samples were amorphous in structure and the intensity of the crystalline parts was high in the range of 10-40. Also, in Atomic Force Microscopy (AFM). It was found that… More >

M. Jabeen^a, N. Ali^b,*, Z. Ali^c, H. Ali^b, A. A. A. Bahajjaj^d, B. Haq^e, S. H. Kim^e

Chalcogenide Letters, Vol.21, No.2, pp. 125-133, 2024, DOI:10.15251/CL.2024.212.125

Abstract In this study, Tin selenide (SnSe) was prepared via thermal evaporation from tin ingots and selenium powder followed by annealing at 250°C in an inert atmosphere of Argon gas. Two samples were used for characterization purposes, as-deposited and annealed. The structural parameters including particle size, strain, dislocation density, and number of crystallites per unit area were calculated from XRD while the optical properties including band gap were extracted from UV-visible spectroscopy. Four probe techniques were used to measure the electrical properties. More >

A. B. Alwany^a,*, A. Alnakhlani^a,b, B. Hassan^a,b, M. A. Algradee^a, R. A. Fouad^b, A. A. Alfaqeer^c

Chalcogenide Letters, Vol.21, No.1, pp. 99-112, 2024, DOI:10.15251/CL.2024.211.99

Abstract Thermal evaporation technique was used to prepare Cu₁₃Se₅₂Bi₃₅ thin films. The asdeposited and annealed samples were investigated by using the X-ray diffraction (XRD), scanning electron microscopy (SEM) and optical transmission and reflection. The XRD showed that the as-deposited film is crystalline in nature, and the crystalline size of samples increased with increasing the annealing temperature. SEM images showed that the morphology of the sample changes with the annealing temperature. The direct transition of the optical band gap (E_g) of Cu₁₃Se₅₂Bi₃₅ films was observed and the values of E_g decreased with increasing the annealing temperature. Other optical parameters More >

A. A. Ahmed^a, G. G. Ali^b,*, N. A. Daham^a

Chalcogenide Letters, Vol.21, No.1, pp. 81-97, 2024, DOI:10.15251/CL.2024.211.81

Abstract In this work, copper sulfide (CuS) nanostructure was deposited on a porous silicon wafer for the visible light by spray pyrolysis method. Through this, a series of devices were suggested as a part of the deposit concentration of CuS on n-type porous silicon. Simultaneously, the physical features of the attained film were illustrated. FESEM exhibited that the average nanoparticle diameter increased with the concentration of CuS at orientation (100) and was found to be 47.84 nm, 56.36nm and 71.32nm, while the average diameter at (111) orientation was found to be 37.64 nm, 41.46nm, 55.22 nm… More >

F. B. ohammed Ameen^a, M. H. Younus^b, G. G. Ali^c,*

Chalcogenide Letters, Vol.21, No.4, pp. 343-354, 2024, DOI:10.15251/CL.2024.214.343

Abstract In this work, the gas sensing properties of ZnS/Porous silicon heterostructures have been investigated. . Zinc sulfide(ZnS) with high gas sensing performance is successfully synthesized over the Porous silicon substrate by the spray pyrolysis method. The properties of the as-prepared samples were characterized X-ray diffraction (XRD), scanning electron microscope (SEM), Fourier transform spectrum (FTIR) and optical properties. The results reveal that the properties of the ZnS/Porous silicon heterostructures enhanced when the when the ZnS concentration is increased. The performance ZnS/Porous silicon as a gas-sensing show that the maximum sensitivity is found to be 5.11 at More >

H. K. Mahmood^*, B. H. Hussein

Chalcogenide Letters, Vol.21, No.9, pp. 687-694, 2024, DOI:10.15251/CL.2024.219.687

Abstract ZnIn₂(Se_1-xTe_x)₄ (ZIST) chalcopyrite semiconductor thin films at various contents (x = 0.0, 0.2, and 0.4) are deposited on glass and p type silicon (111) substrate to produce heterojunction solar cell by using the thermal evaporation technique at RT where the thickness of 500 nm with a vacuum of 1×10^-5 mbar and a deposited rates of 5.1 nm/s. This study focuses on how differing x content effect on the factors affecting the solar cell characteristics of ZIST thin film and n-ZIST/p-Si heterojunction. X-ray diffraction XRD investigation shows that this structure of ZIST film is polycrystalline and tetragonal,… More >

Abhishek Kumar Patel, Ashlesha P. Kawale, Neeru Sharma, Nishant Shekhar, Subhash Banerjee^*, Arti Srivastava^*

Journal of Polymer Materials, Vol.41, No.2, pp. 69-86, 2024, DOI:10.32604/jpm.2024.052695 - 09 August 2024

Abstract This study aims to synthesize, characterize, and evaluate the photocatalytic efficiency of carboxymethyl cellulose (CMC) wrapped ZnONPs for the degradation of methylene blue (MB) dye under sunlight and also focuses on the effect of varying calcination temperatures on crystallite size of the synthesized ZnONPs@CMC. It focuses on developing biopolymer (CMC) wrapped ZnO nanoparticles (ZnONPs@CMC) at different calcination temperatures. ZnONPs@CMC are synthesized using zinc acetate dihydrate as a precursor under alkaline conditions, followed by adding capping agent CMC at various calcination temperatures ranging from 250°C to 650°C. The nanomaterials are characterized by UV-Vis, FTIR, and powder… More >