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    ARTICLE

    Thiol-yne Reaction of Alkyne-d erivatized Fatty Acids: Thiol-Reactive Linear Polyurethane

    Rodolfo J. González-Paz, Gerard Lligadas*, Juan C. Ronda, Marina Galià, Virginia Cádiz

    Journal of Renewable Materials, Vol.1, No.3, pp. 187-194, 2013, DOI:10.7569/JRM.2013.634114

    Abstract A thiol-reactive linear polyurethane was synthesized from a vinyl-sulphide-containing diol and a commercial diisocyanate. The diol was obtained from 10-undecynol, an alkyne-derivatized fatty compound, using hydrothiolation as a key reaction step. 10-Undecynol was prepared by reduction of 10-undecinoic acid methyl ester, which was prepared by successive bromation, dehydrobromination of the corresponding alkenic fatty acid. Solution and surface polymer modifi cation with a fl uorescent thiol was successful. More >

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