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    ARTICLE

    Synthesis of Photoactive Compounds from Tall Oil Fatty Acids

    Beatrise Sture1,*, Mikelis Kirpluks1, Sergejs Gaidukovs2, Edgars Vanags1

    Journal of Renewable Materials, Vol.8, No.9, pp. 1077-1089, 2020, DOI:10.32604/jrm.2020.09294 - 03 August 2020

    Abstract Photocurable systems are more effective, faster and require less energy than conventional thermal curing methods. To facilitate the ongoing transition toward a biobased economy, photoactive compounds were synthesized from tall oil fatty acids (TOFA) which is a by-product from wood pulping. In this study, photoactive monomers were synthesized by two different chemical pathways using oleic acid and TOFA as raw materials. Firstly, double bonds present in TOFA were epoxidized, followed by epoxy ring-opening with acrylic acid which introduced photoactive functional groups into the fatty acid backbone. Intermediates and final products were analysed using titration methods More >

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