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  • Open Access

    ARTICLE

    Engineering and Tuning of Absorber Layer Properties for High-Efficiency SnS-Based Solar Cells: A SCAPS-1D Simulation Study

    Abla Guechi1, Djohra Dekhil2, Abdelhak Nouri2,*

    Chalcogenide Letters, Vol.23, No.1, 2026, DOI:10.32604/cl.2026.076586 - 26 January 2026

    Abstract This work uses numerical modeling in SCAPS-1D to examine the efficiency analysis of a solar cell based on SnS. The power conversion efficiency (PCE) is limited to 24.5% because of incomplete photon absorption in the absorber layer (SnS) and carrier recombination. To increase the absorption window, facilitate charge mobility, and suppress bulk recombination at the rear contact, the absorbent film was divided up into three sublayers with graded band gaps of 1.1 eV, 1.2 eV, and 1.3 eV. Furthermore, the sublayers’ linear gradient doping improved charge collection while simultaneously lowering recombination at the interface. A… More >

  • Open Access

    ARTICLE

    Impact of Window Layers on Selenium Distribution and Photovoltaic Performance in CdSexTe1−x/CdTe Solar Cells

    Junyan Tian1, Qingyuan Zhang1, Lili Wu1,2,*, Xia Hao1,2, Guanggen Zeng1, Wenwu Wang1, Jingquan Zhang1,2

    Chalcogenide Letters, Vol.23, No.1, 2026, DOI:10.32604/cl.2026.076362 - 26 January 2026

    Abstract The incorporation of the Se element in CdTe solar cells is critical, while the low bandgap CdSexTe1−x, formed by the interdiffusion of CdTe and CdSe during device preparation, can promote the carrier lifetime. Different window layers formed by CdSe w/o MZO or CdS have different Se distributions. This paper systematically evaluates the influence of four types of window layers (CdSe, CdS/CdSe, MZO/CdSe and MZO/CdS/CdSe) on the performance of CdTe solar cells, and focuses on the correlation between the window layers and the Se distribution characteristic, carrier recombination mechanism, and device efficiency. The results show that CdSe… More >

  • Open Access

    ARTICLE

    Synthesis and Photoresponse of Quinary Zinc-Blende Cu3FeInSnS6 Nanoplates

    Dehui Li1,#, Yiming Guo1,#, Tao He1, Binbin Zhang1, Haixia Yu2,*, Lingkun Meng1,*

    Chalcogenide Letters, Vol.23, No.1, 2026, DOI:10.32604/cl.2026.075922 - 26 January 2026

    Abstract Quinary Cu3FeInSnS6 (CFITS) nanoplates were synthesized through a synergistic dual-cation substitution strategy using a hot-injection method, where oleylamine and 1-dodecanethiol served as coordinating ligands to guide two-dimensional growth. The nanocrystals were characterized by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, and absorption spectroscopy. Structural analysis confirms that the CFITS nanoplates crystallize in a phase-pure cubic zinc-blende structure (space group F-43 m) without detectable secondary phases. Optical measurements reveal that the nanoplates exhibit broad and intense visible-light absorption with a direct bandgap of 1.51 ± 0.03 eV, suitable for photovoltaic applications. Under standard AM 1.5 G… More >

  • Open Access

    ARTICLE

    Structural, Morphological and Optical Comparison of In-S Films Deposited by CBD and Ultrasonic Pyrolytic Spraying, as a Buffer Layer in CIGS Solar Cells

    A. Ledesma-Juárez1, J. F. Quintero-Guerrero2, A. M. Fernández1,*

    Chalcogenide Letters, Vol.22, No.12, pp. 1009-1018, 2025, DOI:10.15251/CL.2025.2212.1009 - 06 December 2025

    Abstract Indium sulphide (In2S3) has positioned itself as an environmentally friendly and efficient option compared to traditional CdS, used as a buffer layer in thin-film solar cells that use Cu(In,Ga)Se2 (CIGS) as an absorbent material. This study provides a comparative analysis of two techniques for depositing thin films of In2S3: chemical bath deposition (CBD) and ultrasonic pyrolytic spraying. Their structural, morphological, compositional, and optical properties were evaluated. The films obtained by pyrolytic spraying, showed adequate crystallinity and uniformity. On the other hand, the films deposited by CBD had better stoichiometry (In2:S3 ≈ 40:60% at.) and higher bandgap values More >

  • Open Access

    ARTICLE

    Enhanced performance of tin sulfide thin-film solar cells via silicon substrate integration: a combined experimental and simulation study

    O. Mekhbia, K. Kamlib,*, Z. Hadefb, O. Kamlic, M. Bouatrousd, N. Houaidjie, L. Zighedh

    Chalcogenide Letters, Vol.22, No.4, pp. 331-339, 2025, DOI:10.15251/CL.2025.224.331

    Abstract This work presents a hybrid study that employs Ultrasonic Spray method for the deposition of SnS absorber films and SCAPS-1D simulation method for the analysis of various solar cell topologies. Different deposition times have been employed to optimize structural, optics, and electrical properties. To evaluate their potential as absorber layers for solar cells, the films were analyzed by using X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), and tested for electrical performance. Complementary numerical simulations were carried out with SCAPS-1D in modeling ZnO:Al/i-ZnO/SnS2/SnS solar cell structures. Results showed that optimized SnS thickness of 2.5 µm and high carrier More >

  • Open Access

    ARTICLE

    Quaternary chalcogenides as transport layers in solid-state DSSC: a feasibility study

    M. H. Ibrahim*, M. R. Salim, M. Y. Mohd Nor, A. S. Abdullah, A. I. Azmi

    Chalcogenide Letters, Vol.22, No.6, pp. 551-560, 2025, DOI:10.15251/CL.2025.226.551

    Abstract Four chalcogenide compounds: copper zinc germanium sulfide (CZGS), copper zinc germanium selenide (CZGSe), copper barium tin sulfide (CBTS), and copper manganese tin sulfide (CMTS) were proposed as hole transport layer (HTL) in dye-sensitized solar cell (DSSC). The DSSC structure comprises fluorine-doped tin oxide (FTO) as the top electrode, zinc oxysulfide (ZnOS) as the electron transport layer (ETL), N719 dye as the light absorber, chalcogenides as the HTL, and gold (Au) as the back electrode. By utilizing the SCAPS 1- D simulator, the optimal thicknesses for ZnOS, HTL candidates and N719 dye were determined to be More >

  • Open Access

    ARTICLE

    Modeling and optimization of a CZT(S,Se)-based tandem solar cell

    B. Yassine, B. Tahar*, G. Fathi, B. Meriem, B. Ibtissem

    Chalcogenide Letters, Vol.22, No.7, pp. 637-648, 2025, DOI:10.15251/CL.2025.227.637 - 17 December 2025

    Abstract In this paper, we designed a two-junction (tandem) solar cell model (tandem solar cell), consisting of an top and bottom subcell with absorber layers of Cu2SnZnS4 (CZTS) and Cu2SnZnSe4 (CZTSe) materials, respectively, for each subcell with a ZnS buffer layer and a ZnO window layer. This model was validated using the SCAPS-1D numerical simulation program. We also optimized the performance of the tandem cell as a whole using the simulation by studying the effect of the thickness of the absorber layer of the top subcell and the thickness of the absorber layer of the bottom subcell More >

  • Open Access

    ARTICLE

    Boosting power efficiency in polycrystalline silicon solar cells: antimony selenide sputter coating with advanced optical, electrical, and thermal insights

    R. M. Reddya, S. Chiragb, T. Anuc, A. R. Venkataramanand, S. Karthikeyane,*, D. Palaniswamyf, E. Venugopal Gouda, N. Dineshbabug, T. Thirugnanasambandhamh

    Chalcogenide Letters, Vol.22, No.7, pp. 615-624, 2025, DOI:10.15251/CL.2025.227.615

    Abstract Solar cells can transform light energy into electrical energy, possibly removing the need for fossil fuel energy resources. Reflection loss in solar cells is a factor contributing to diminished power conversion efficiency, which can be solved through using antireflective coatings on the cell surface. The present research primarily focuses on the development and application of antireflection coatings on the top surface of silicon solar cells. Sb2Se3 was deposited over multi-crystalline Si cells with different durations from 15 to 60 minutes. The influence of thin film Sb2Se3 coated cells was investigated through optical, current, voltage and thermal… More >

  • Open Access

    ARTICLE

    Structural, optical and electrical properties of NiO thin films for hole transport layer in chalcogenide and perovskite materials based solar cells

    M. Abbasa, M. Haseeb-u-Rehmana, M. Sohailb, G. H. Tariqa,*

    Chalcogenide Letters, Vol.22, No.7, pp. 561-577, 2025, DOI:10.15251/CL.2025.227.561

    Abstract This work presents the fabrication of NiO thin films via versatile sol-gel spin coating method and investigation of annealing effects on their physical properties. After the deposition process, the NiO thin films underwent annealing process at different values of temperatures ranging from 200°C to 350°C for one hour duration. XRD patterns confirmed the polycrystalline nature, along the preferred orientations (110) and (101) planes. Nanoparticles in NiO thin films demonstrated an increase in crystallite size with rising annealing temperatures, reaching a maximum size of 49 nm at annealing temperature 300°C. FTIR patterns revealed Ni-O bands at… More >

  • Open Access

    ARTICLE

    Sonochemically synthesised nitrogen-doped CdS nanoparticles for photovoltaic applications

    S. R. Ahmeda,*, M. V. V. K. Srinivas Prasadb, K. Keerthivasanc

    Chalcogenide Letters, Vol.22, No.8, pp. 679-691, 2025, DOI:10.15251/CL.2025.228.679

    Abstract This work used a sonication-aided approach to make Cadmium sulfide nanoparticles and Nitrogen-doped CdS nanoparticles. Doping Nitrogen into CdS NPs enhances the material's electrical, chemical, and structural properties by altering its surface area and functional sites. XRD, FTIR, SEM/EDX, TGA, UV-Vis, and PSA are used to evaluate the characteristic features of CdS NPs. The photovoltaic responses of the prepared CdS and CdS-N NPs were evaluated by electrochemical impedance and IV analysis. The obtained XRD data confirms that nitrogen doping significantly changes the crystal size of CdS NPs. The XPS spectrum depicts the presence of trace More >

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