Qingran Meng^1,2, Wenwen Xu², Zuobing Xiao², Qinfei Ke^1,2,*, Xingran Kou^1,2,*

Journal of Renewable Materials, Vol.12, No.4, pp. 629-641, 2024, DOI:10.32604/jrm.2023.029182 - 12 June 2024

Abstract Bio-based cyclodextrins (CDs) are a common research object in supramolecular chemistry. The special cavity structure of CDs can form supramolecular self-assemblies such as vesicles and microcrystals through weak interaction with guest molecules. The different forms of supramolecular self-assemblies can be transformed into each other under certain conditions. The regulation of supramolecular self-assembly is not only helpful to understand the self-assembly principle, but also beneficial to its application. In the present study, the self-assembly behavior of epoxy-β-cyclodextrin (EP-β-CD) and mixed anionic and cationic surfactant system (sodium dodecyl sulfate/dodecyltrimethylammonium bromide, SDS/DTAB) in aqueous solution was studied. Morphological… More > Graphic Abstract

Yonghong Liu¹, Muhammad Waheed², Umair Saleem³, Muhammad Kamran Jamil^4,*, Muhammad Naveed⁵, Mohammad Reza Farahani⁶

CMES-Computer Modeling in Engineering & Sciences, Vol.136, No.2, pp. 1899-1916, 2023, DOI:10.32604/cmes.2023.025071 - 06 February 2023

Abstract L-valine is a glycogen-type amino acid regarded among the necessary mammalian amino acids. This is an amino acid that is essential for protein synthesis. N-salicylidene-L-valine is gaining a lot of attention because of its unique structure and increased catalytic and cytotoxic activity. We explore the chain of supramolecular dialkyltin N-salicylidene-L-valine complexes 2, 3, and 4 to learn more about this structure and its features regarding topological indices. We computed the first and second Randić index, harmonic index, sum-connectivity index, atom-bond-connectivity index, geometric arithmetic index and reduced reciprocal Randić index of Supramolecular Chain of Different Complexes More >

Ruyu Yan^1,2,3,4, Jian Fang^1,*, Xiaohua Yang^2,3,4,5,6, Na Yao^2,3,4,5,6, Mei Li^2,3,4,5,6, Yuan Nie^2,3,4,5,6, Tianxiang Deng^2,3,4,5,6, Haiyang Ding^2,3,4,5,6, Lina Xu^2,3,4,5,6, Shouhai Li^2,3,4,5,6,*

Journal of Renewable Materials, Vol.11, No.4, pp. 1937-1950, 2023, DOI:10.32604/jrm.2023.025126 - 01 December 2022

Abstract Ethyl cellulose (EC), an important biomass-based material, has excellent film-forming properties. Nevertheless, the high interchain hydrogen bond interaction leads to a high glass transition temperature of EC, which makes it too brittle to be used widely. The hydroxyl group on EC can form a supramolecular system in the form of a non-covalent bond with an effective plasticizer. In this study, an important vegetable-oil-based derivative named dimer fatty acid was used to prepare a novel special plasticizer for EC. Dimer-fatty-acid-based thioether polyol (DATP) was synthesized and used to modify ethyl cellulose films. The supramolecular composite films… More > Graphic Abstract

JUAN CARLOS STOCKERT^1,2,*, ALFONSO BLÁZQUEZ-CASTRO³

BIOCELL, Vol.46, No.6, pp. 1391-1415, 2022, DOI:10.32604/biocell.2022.019493 - 07 February 2022

Abstract

Melanins represent one of the most ancient and important group of natural macromolecular pigments. They have multiple biological roles in almost all organisms across the Phyla, examples being photoprotection, anti-oxidative action, radical scavenger activity, and heavy metal removal. From the biomedical point of view, melanocytes are involved in the origin of melanoma tumors, and the main therapeutic advances for their treatment have been revised in Part 1 of this review. The chemical structure of eumelanin is a biological concern of great importance, and therefore, exploring theoretical molecular models and synthesis mechanisms will be here described, as

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J. P. Shri Tharanyaa^1,*, D. Sharmila², R. Saravana Kumar³

CMC-Computers, Materials & Continua, Vol.71, No.2, pp. 2667-2681, 2022, DOI:10.32604/cmc.2022.019889 - 07 December 2021

Abstract With the emergence of the Internet of things (IoT), embedded systems have now changed its dimensionality and it is applied in various domains such as healthcare, home automation and mainly Industry 4.0. These Embedded IoT devices are mostly battery-driven. It has been analyzed that usage of Dynamic Random-Access Memory (DRAM) centered core memory is considered the most significant source of high energy utility in Embedded IoT devices. For achieving the low power consumption in these devices, Non-volatile memory (NVM) devices such as Parameter Random Access Memory (PRAM) and Spin-Transfer Torque Magnetic Random-Access Memory (STT-RAM) are… More >

Poonam Trivedi¹, Jens Schaller², Jan Gustafsson¹, Pedro Fardim^1,3*

Journal of Renewable Materials, Vol.5, No.5, pp. 400-409, 2017, DOI:10.7569/JRM.2017.634143

Abstract In the present study, we report the supramolecular design of cellulose-sulfonate hydrogel beads by blending water soluble sodium cellulose ethyl sulfonate (CES) with the pretreated cellulose in sodium hydroxide-ureawater solvent system at −6 °C followed by coagulation in the 2M sulfuric acid system. The increasing of CES amount from 10% to 90% had a substantial effect on the viscosity and storage (G′) and loss (G″) moduli of the blended solutions. The CES concentration up to 50% in blends led to the formation of physically stable hydrogels after coagulation in acidic medium at pH-1 and showed… More >