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    ARTICLE

    Comparative Study on Properties of PBAT/PBSA Film Modified by a Multi-Functional Epoxide Chain Extender or Benzoyl Peroxide

    Yanfeng Zhu1, Huidong Shi1, Qing Ju1, Dong Zhao1, Yucai Shen1,2,*, Tingwei Wang1,2,*

    Journal of Renewable Materials, Vol.11, No.3, pp. 1303-1319, 2023, DOI:10.32604/jrm.2022.023129

    Abstract Poly(butylene adipate-co-terephthalate) (PBAT) and poly(butylene succinate-co-adipate) (PBSA) blend films were prepared with different contents of a multifunctional epoxide chain extender Joncryl ADR-4468 (ADR) or benzoyl peroxide (BPO). The long-chain-branching (LCB) introduced by ADR and branched/crosslinked entanglement induced by BPO increased melt elasticity, viscosity and compatibility, as indicated by thermal properties, rheological and morphological analyses. It was found that the elongation at break and the tensile strength were significantly improved, due to the enhancement of compatibility and the interfacial adhesion by the incorporation of ADR or BPO. The best mechanical properties were obtained in PBAT/PBSA/ADR (60/40/0.3) (A4T6A0.3) and PBAT/PBSA/BPO (60/40/0.9) (A4T6B0.9)… More > Graphic Abstract

    Comparative Study on Properties of PBAT/PBSA Film Modified by a Multi-Functional Epoxide Chain Extender or Benzoyl Peroxide

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