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    ARTICLE

    Schiff’s base of Fe3O4 @chitosan with 4,4'- diselenobisbenzaldehyde: Preparation, characterization and its catalytic activity for oxidation of sulphides

    RAFAT SABA*, MOHD. KASHIF AZIZ, GHULAM MUSTAFA, ARPIT SRIVASTAVA, SHEKHAR SRIVASTAVA*

    Journal of Polymer Materials, Vol.38, No.1-2, pp. 153-166, 2021, DOI:10.32381/JPM.2021.38.1-2.12

    Abstract We have synthesized Schiff’s base of Fe3 O4 @chitosan with 4,4'-diselenobisbenzaldehyde (Fe3O4 @CSSe) composite and used it as acatalyst for the oxidation of sulfides, having some advantageous properties such as eco-friendly, cost-effective and highly efficient magnetic biocatalyst of selenium. The synthesized schiff’s base was characterized by different physical characterization techniques such as Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), Vibrating sample magnetometer (VSM)and Dynamic light scattering (DLS). Further, we used the resulting schiff’s base as a catalyst in the presence of a green oxidant (H2 O2 ) to oxidize sulfides to corresponding sulfoxides at room temperature. It More >

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