LIJUN CHEN*, ZHEQING GONG, ZHENGRONG FU
Journal of Polymer Materials, Vol.40, No.3-4, pp. 157-164, 2023, DOI:10.32381/JPM.2023.40.3-4.3
Abstract The organic fluorine modified/containing cationic acrylic resin is prepared via solution
polymerization technique using hexafluorobutyl methacrylate (HFMA) along with butyl acrylate
(BA), methyl methacrylate (MMA), styrene (St), dimethylaminoethyl methacrylate (DMAEMA)
and hydroxy propyl methacrylate (HPMA) as the comonomers, proprylene glycol monomethyl
ether (PGME) as the solvent, and 2, 2-Azo-bis-iso-butyronitrile (AIBN) as the initiator. The
synthesized resin in which fluorine atom is introduced into the polymer chains. The cathodic
electrodeposition (CED) coatings were prepared by mixing the synthesized resin and blocked
isocyanate. The influence of the amount of organic fluorine on the resin and the resultant More >