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    ARTICLE

    Study on Organic Fluorine Modified Cationic Acrylic Resin and its Application in Cathodic Electrodeposition Coatings

    LIJUN CHEN*, ZHEQING GONG, ZHENGRONG FU

    Journal of Polymer Materials, Vol.40, No.3-4, pp. 157-164, 2023, DOI:10.32381/JPM.2023.40.3-4.3

    Abstract The organic fluorine modified/containing cationic acrylic resin is prepared via solution polymerization technique using hexafluorobutyl methacrylate (HFMA) along with butyl acrylate (BA), methyl methacrylate (MMA), styrene (St), dimethylaminoethyl methacrylate (DMAEMA) and hydroxy propyl methacrylate (HPMA) as the comonomers, proprylene glycol monomethyl ether (PGME) as the solvent, and 2, 2-Azo-bis-iso-butyronitrile (AIBN) as the initiator. The synthesized resin in which fluorine atom is introduced into the polymer chains. The cathodic electrodeposition (CED) coatings were prepared by mixing the synthesized resin and blocked isocyanate. The influence of the amount of organic fluorine on the resin and the resultant More >

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