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  • Open Access

    ARTICLE

    Structural Elucidation of the Polymeric Condensed Tannins of Acacia nilotica Subspecies by 13C NMR, MALDI-TOF and TMA as Sources of Bioadhesives

    Zeinab Osman1,2,3,*, Antonio Pizzi2,*, Bertrand Charrier3

    Journal of Renewable Materials, Vol.12, No.7, pp. 1291-1310, 2024, DOI:10.32604/jrm.2024.051619 - 21 August 2024

    Abstract Tannin was extracted from different subspecies of Acacia nilotica, Acacia nilotica nilotica (Ann), Acacia nilotica tomentosa (Ant) and Acacia nilotica adansonii (Ana). The aim was to elucidate their structure and evaluate their reactivity as bioadhesives in the wood industry. The extracts were prepared by hot water extraction (90°C temperature). Their gel time with paraformaldehyde was used at first to compare their reactivity. The tannin contents and the percentage of total polyphenolic materials in different solutions of the extracts spray dried powder were determined by the hide powder method. Concentrated solutions (47%) were tested by both MALDI ToF, CNMR.… More > Graphic Abstract

    Structural Elucidation of the Polymeric Condensed Tannins of <i>Acacia nilotica</i> Subspecies by <sup>13</sup>C NMR, MALDI-TOF and TMA as Sources of Bioadhesives

  • Open Access

    ARTICLE

    Matrix Assisted Laser Desorption Ionization Time of Flight (MALDI-TOF)-Mass Spectrometry and 13C-NMR-Identified New Compounds in Paraberlinia bifoliolata (Ekop-Beli) Bark Tannins

    Liliane Nga1, Benoit Ndiwe1,2, Achille Bernard Biwolé1, Antonio Pizzi3,*, Jean Jalin Eyinga Biwole1, Joseph Zobo Mfomo1

    Journal of Renewable Materials, Vol.12, No.3, pp. 553-568, 2024, DOI:10.32604/jrm.2023.046568 - 11 April 2024

    Abstract Extracts of plant origin, particularly tannins, are attracting growing interest for the sustainable development of materials in the industrial sector. The discovery of new tannins is therefore necessary. The aim of this work was to contribute to the understanding of the properties of Paraberlinia bifoliolata tannin by Matrix Assisted Laser Desorption Ionization Time of Flight Mass Spectroscopy MALDI-TOF/MS and Carbon 13 Nuclear Magnetic Resonance (13C NMR). The chemical composition of tannin extracted from Paraberlinia bifoliolata bark was determined, as was the mechanical strength of the resin hardened with Acacia nilotica extracts. Yield by successive water extraction was 35%. MALDI-TOF/MS… More >

  • Open Access

    ARTICLE

    Synthesis and Characterization of Bisphenol-C Epoxy Crotonate and Its Fiber-Reinforced Composites

    PARSOTAM H. PARSANIA1,*, JIGNESH V. PATEL2, JIGNESH P. PATEL3

    Journal of Polymer Materials, Vol.40, No.3-4, pp. 271-284, 2023, DOI:10.32381/JPM.2023.40.3-4.9

    Abstract Bisphenol-C epoxy crotonate resin was synthesized by reacting 8.09g epoxy resin of bisphenolC, and 2.15g crotonic acid using 25 mL 1,4-dioxane as a solvent, and 1 mL triethylamine as a catalyst at reflux temperature for 1-6 h. Solid epoxy crotonate (ECCR) is highly soluble in common organic solvents. ECCR was characterized by its acid (24.5-1.5 mg KOH/g) and hydroxyl (504.5-678.4 mg KOH/g) values. The structure of ECCR is supported by FTIR and 1 HNMR spectroscopic methods. A DSC endothermic transition at 229o C indicated melting followed by thermal polymerization of ECCR. ECCR is thermally stable… More >

  • Open Access

    ARTICLE

    Self-Cross-Linked Tannin-Aminated Tannin Surface Coatings for Particleboard

    Bengang Zhang1,*, Antonio Pizzi2,*, Mathieu Petrissans1, Anelie Petrissans1, Colin Baptiste1

    Journal of Renewable Materials, Vol.11, No.12, pp. 4097-4121, 2023, DOI:10.32604/jrm.2023.029761 - 10 November 2023

    Abstract Aminated tannins were prepared by reacting mimosa condensed tannin extract with ammonia yielding the substitution of many, if not all of the tannin hydroxyl groups with –NH2 groups. A tannin-aminated tannin (ATT) particleboard coating was then prepared by reacting raw tannin extract with aminated tannin extract and thus cross-liking the two by substituting tannin’s hydroxyl groups with the –NH2 groups on the aminated tannin to form –NH-bridges between the two. The resulting particleboard coating gave encouraging results when pressed at 180°C for 3 min. Conversely, the system in which tannin was reacted/cross-liked with urea (ATU) by… More >

  • Open Access

    PROCEEDINGS

    Water Occurrence and Its Influencing Factors in Tight Gas Reservoirs

    Mianmo Meng1,*, Wenming Ji2

    The International Conference on Computational & Experimental Engineering and Sciences, Vol.26, No.4, pp. 1-1, 2023, DOI:10.32604/icces.2023.09159

    Abstract Tight reservoirs hold a vast natural gas in Ordos Basin, and efficient development of these resources can offset the energy shortage. Due to the low-porosity and low-permeability, hydraulic fracturing becomes necessary to tap its resources. After fracturing, a large amount of fracturing fluid fills pore space near hydraulic fracture, which will influence the gas production. This study focused on the water occurrence of tight gas reservoirs and its influencing factors. Samples were selected from Upper Paleozoic Taiyuan and Shihezi Formations from Ordos Basin. The main experiments include porosity, permeability, mineral composition, nitrogen adsorption (NA), mercury… More >

  • Open Access

    ARTICLE

    Experimental Evaluation of Compressive Strength and Gas Permeability of Glass-Powder-Containing Mortar

    Yue Liang, Wenxuan Dai, Wei Chen*

    FDMP-Fluid Dynamics & Materials Processing, Vol.19, No.10, pp. 2639-2659, 2023, DOI:10.32604/fdmp.2023.027622 - 25 June 2023

    Abstract Glass powder of various particle sizes (2, 5, 10 and 15 μm) has been assessed as a possible cement substitute for mortars. Different replacement rates of cement (5%, 10%, 15%, and 20%) have been considered for all particle sizes. The accessible porosity, compressive strength, gas permeability and microstructure have been investigated accordingly. The results have shown that adding glass powder up to 20% has a significantly negative effect on the porosity and compressive strength of mortar. The compressive strength initially rises with a 5% replacement and then decreases. Similarly, the gas permeability of the mortar displays… More >

  • Open Access

    ARTICLE

    Hydrolysable Chestnut Tannin Extract Chemical Complexity in Its Reactions for Non-Isocyanate Polyurethanes (NIPU) Foams

    Elham Azadeh1, Antonio Pizzi1,2,*, Christine Gerardin-Charbonnier1,*, Philippe Gerardin1

    Journal of Renewable Materials, Vol.11, No.6, pp. 2823-2848, 2023, DOI:10.32604/jrm.2023.027651 - 27 April 2023

    Abstract Non-isocyanate polyurethane (NIPU) foams from a commercial hydrolysable tannin extract, chestnut wood tannin extract, have been prepared to determine what chemical species and products are taking part in the reactions involved. This method is based on two main steps: the reaction with dimethyl carbonate and the formation of urethane bonds by further reaction of the carbonated tannin with a diamine-like hexamethylene diamine. The hydroxyl groups on the tannin polyphenols and on the carbohydrates intimately linked with it and part of a hydrolysable tannin are the groups involved in these reactions. The carbohydrate skeleton of the… More > Graphic Abstract

    Hydrolysable Chestnut Tannin Extract Chemical Complexity in Its  Reactions for Non-Isocyanate Polyurethanes (NIPU) Foams

  • Open Access

    ARTICLE

    A Novel Method to Enhance the Inversion Speed and Precision of the NMR T2 Spectrum by the TSVD Based Linearized Bregman Iteration

    Yiguo Chen1,2,3,*, Congjun Feng1,2, Yonghong He3, Zhijun Chen3, Xiaowei Fan3, Chao Wang3, Xinmin Ge4

    CMES-Computer Modeling in Engineering & Sciences, Vol.136, No.3, pp. 2451-2463, 2023, DOI:10.32604/cmes.2023.021145 - 09 March 2023

    Abstract The low-field nuclear magnetic resonance (NMR) technique has been used to probe the pore size distribution and the fluid composition in geophysical prospecting and related fields. However, the speed and accuracy of the existing numerical inversion methods are still challenging due to the ill-posed nature of the first kind Fredholm integral equation and the contamination of the noises. This paper proposes a novel inversion algorithm to accelerate the convergence and enhance the precision using empirical truncated singular value decompositions (TSVD) and the linearized Bregman iteration. The L1 penalty term is applied to construct the objective More > Graphic Abstract

    A Novel Method to Enhance the Inversion Speed and Precision of the NMR T<sub>2</sub> Spectrum by the TSVD Based Linearized Bregman Iteration

  • Open Access

    ARTICLE

    The Effect of Different Freeze-Thaw Cycles on Mortar Gas Permeability and Pore Structure

    Wei Chen1,*, Ao Xu1, Hejun Zhang1, Mingquan Sheng1, Yue Liang1, Frederic Skoczylas2

    FDMP-Fluid Dynamics & Materials Processing, Vol.19, No.6, pp. 1623-1636, 2023, DOI:10.32604/fdmp.2023.025083 - 30 January 2023

    Abstract Two different freeze-thaw cycles (FTC) are considered in this study to assess the related impact on gas permeability and micro-pore structure of a mortar. These are the water-freezing/water-thawing (WF-WT) and the air-freezing/air-thawing (AF-AT) cycles. The problem is addressed experimentally through an advanced nuclear magnetic resonance (NMR) technique able to provide meaningful information on the relationships among gas permeability, pore structure, mechanical properties, and the number of cycles. It is shown that the mortar gas permeability increases with the number of FTCs, the increase factor being 20 and 12.83 after 40 cycles for the WF-WT and More >

  • Open Access

    ARTICLE

    Effect of Natural Zeolite on Pore Structure of Cemented Uranium Tailings Backfill

    Fulin Wang*, Xinyang Geng, Zhengping Yuan, Shijiao Yang*

    Journal of Renewable Materials, Vol.11, No.3, pp. 1469-1484, 2023, DOI:10.32604/jrm.2022.024994 - 31 October 2022

    Abstract The use of some environmental functional minerals as backfill-modified materials may improve the leaching resistance of cemented uranium tailings backfill created from alkali-activated slag (CUTB), but these materials may participate in the hydration reaction of the cementitious materials, which could have a certain impact on the pore structure of the CUTB, thus affecting its mechanical properties and leaching resistance. In this paper, natural zeolite is selected as the backfill-modified material, and it is added to alkali-activated slag paste (AASP) and CUTB in cementitious material proportions of 4%, 8%, 12%, and 16% to prepare AASP mixtures… More >

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