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  • Open Access

    ARTICLE

    N-Doped rGO-Like Carbon Prepared from Coconut Shell: Structure and Specific Capacitance

    Imam Khambali1,2,*, Budhi Priyanto1,2, Retno Asih1, Malik Anjelh Baqiya1, Muhammad Mahyiddin Ramli3, Nurul Huda Osman4, Sarayut Tunmee5, Hideki Nakajima5, Triwikantoro1, Mochamad Zainuri1, Darminto1,*

    Journal of Renewable Materials, Vol.11, No.4, pp. 1823-1833, 2023, DOI:10.32604/jrm.2023.025026

    Abstract An rGO−like carbon compound has been synthesized from biomass, i.e., old coconut shell, by a carbonization process followed by heating at 400°C for 5 h. The nitrogen doping was achieved by adding the urea (CH4N2O) and stirring at 70°C for 14 h. The morphology and structure of the rGO-like carbon were investigated by electron microscopies and Raman spectroscopy. The presence of C-N functional groups was analyzed by Fourier transform infrared and synchrotron X-ray photoemission spectroscopy, while the particle and the specific capacitance were measured by particle sizer and cyclic voltammetry. The highest specific capacitance of 72.78 F/g is achieved by… More > Graphic Abstract

    N-Doped rGO-Like Carbon Prepared from Coconut Shell: Structure and Specific Capacitance

  • Open Access

    ARTICLE

    Study on Preparation of Nitrogen-Doped Hierarchically Porous and High-Performance Carbon Materials from Seaweed Biomass

    Kaihan Xie1, Yamin Hu1,*, Stephen Afonaa-Mensah2, Chuan Yuan1, Bin Cao1, Shuang Wang1,*, Qian Wang1

    Journal of Renewable Materials, Vol.10, No.2, pp. 541-560, 2022, DOI:10.32604/jrm.2022.017911

    Abstract Use Enteromorpha clathrate as a carbon and nitrogen precursor could obtain the N-doped porous carbon materials by two-step pyrolysis. In this paper, the exogenous nitrogen (urea, melamine) and activating agents (KOH, ZnCl2) were employed for the production of higher-performance carbon materials from seaweed biomass. SEM, BET, FTIR, XRD, XPS, Raman and ultimate analyses were carried out to investigate the morpho-structural and elemental peculiarities of the carbonaceous materials. Moreover, cyclic voltammetry (CV) , galvanostatic charge-discharge (GCD) and cyclic charge-discharge tests were carried out to examine the electrochemical properties of the samples. The results showed that electrochemical performance of the carbonaceous materials… More > Graphic Abstract

    Study on Preparation of Nitrogen-Doped Hierarchically Porous and High-Performance Carbon Materials from Seaweed Biomass

  • Open Access

    ABSTRACT

    Comparative Study on Dry Reforming of Methane Over Co-M (M=Ce, Fe, Zr) Catalysts Supported on N-Doped Activated Carbon

    Yinghui Sun1, Guojie Zhang1,2,*

    The International Conference on Computational & Experimental Engineering and Sciences, Vol.22, No.1, pp. 105-105, 2019, DOI:10.32604/icces.2019.05173

    Abstract A series of Co-M (M = Ce, Fe, Zr) binary oxides supported on N-doped catalysts were prepared by impregnation methods and tested for DRM reaction. Moreover, the influence of Co and Ce atomic contents in the catalysts on DRM performance was investigated. Significant enhancement of activity performance over Ce promoted 3Co-1Ce/AC-N catalyst was observed. Compared with Fe and Zr, the catalyst with 1/4 mol% of Ce showed the highest activity and was higher than the supported Co catalyst. The calcined and spent catalysts were characterized by XPS, H2-TPR, TEM and EDX mapping studies. The characterization results demonstrated that the improved… More >

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