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  • Open Access

    REVIEW

    Overview of Jute Fibre as Thermoplastic Matrix Polymer Reinforcement

    Tezara Cionita1,*, Mohammad Hazim Mohamad Hamdan2, Januar Parlaungan Siregar3,4,*, Deni Fajar Fitriyana5, Ramli Junid6, Wong Ling Shing7, Jamiluddin Jaafar8, Agustinus Purna Irawan9, Teuku Rihayat10, Rifky Ismail11, Athanasius Priharyoto Bayuseno11, Emilianus Jehadus12

    Journal of Renewable Materials, Vol.12, No.3, pp. 457-483, 2024, DOI:10.32604/jrm.2024.045814

    Abstract Recent decades have seen a substantial increase in interest in research on natural fibres that is aligned with sustainable development goals (SDGs). Due to their renewable resources and biodegradability, natural fiber-reinforced composites have been investigated as a sustainable alternative to synthetic materials to reduce the usage of hazardous waste and environmental pollution. Among the natural fibre, jute fibre obtained from a bast plant has an increasing trend in the application, especially as a reinforcement material. Numerous research works have been performed on jute fibre with regard to reinforced thermoset and thermoplastic composites. Nevertheless, current demands on sustainable materials have required… More >

  • Open Access

    ARTICLE

    Performance Evaluation of Nucleating Agents in Polypropylene Homopolymer

    RAVI KUMAR, VISHWA PRATAP SINGH, MADHUKAR PRAJAPATI, ASHWITH, PRIYANKA SINGH, SATYAJIT SAMANTA, SAIKAT BANERJEE*

    Journal of Polymer Materials, Vol.36, No.4, pp. 323-335, 2019, DOI:10.32381/JPM.2019.36.04.3

    Abstract Types of nucleating agents and their dosage level play an important role on the crystallinity of the polymer which controls the final properties like optical clarity, stiffness and reduced cycle time during molding. In this study, the efficiency of two different types of commercially available nucleating agents, phosphate ester and dicarboxylic acid based, have been studied. Both the nucleating agents were compounded with molding grade polypropylene homopolymer having melt flow index (MFI) of 12 g/10min at 2.16 Kg and 230°C, in a co-rotating twin screw extruder at two different dosage level, i.e. 300 ppm and 600 ppm. The effectiveness of… More >

  • Open Access

    ARTICLE

    Chitosan Modification by New Chromophore 4-(3-(4- nitrophenyl) thioureido) benzoic acid: Synthesis, Characterization and Evaluation

    KAZIM SHAMIM RIZVI, P. K. DUTTA

    Journal of Polymer Materials, Vol.36, No.3, pp. 217-228, 2019, DOI:10.32381/JPM.2019.36.03.2

    Abstract In this investigation we have shown the preparation of carboxylic acid containing new chromophore : 4-(3-(4-nitrophenyl) thioureido) benzoic acid and its use.The chemical modification of chitosan, e.g., chitosan- acid salt complexes is done under mild conditions. The synthesis of chromophore was carried out by conventional methods and the novel polymer complex was soluble in most of the organic solvents. The modified chitosan was analyzed by various techniques like optical properties by UV and SHG spectroscopy which showed red shift. The antibacterial activity showed obvious effect against food pathogenic bacteria. More >

  • Open Access

    ARTICLE

    Synthesis and Characterization of New Chromophore 4-2-(2-hydroxy-5-(4 nitrophenyl) diazenyl) benzylidene) hydrazinyl) Benzoic Acid and its use in Chitosan Modification

    KAZIM SHAMIM RIZVI, P.K.DUTTA*

    Journal of Polymer Materials, Vol.36, No.1, pp. 75-85, 2019, DOI:10.32381/JPM.2019.36.01.6

    Abstract The present investigation deals with the preparation of carboxylic acid containing new chromophore : 4-2-(2-hydroxy-5-(4-nitrophenyl) diazenyl) benzylidene) hydrazinyl) benzoic acid and its use for chemical modification of chitosan, e.g., chitosan-acid salt complexes under mild conditions. Optical properties of chitosan acid complexes were evaluated by UV and SHG spectroscopy which showed red shift. Antibacterial activity of prepared chitosan acid complexes showed obvious effect against food pathogenic bacteria. The novel polymer complex was soluble in most of the organic solvents. More >

  • Open Access

    ARTICLE

    Synthesis and Characterization of Poly(N-(3- (hexylamino)-N-(3-(isopropylamino)-3- oxopropyl)acrylamide) Homopolymer

    ARCHANA KUMARI, KHEYANATH MITRA, SAMBHAV VISHWAKARMA, SOUROV MONDAL, SHIKHA SINGH, RAJSHREE SINGH, JAYDEEP SINGH, BISWAJIT MAITI, SUSANTA KUMAR SEN GUPTA, BISWAJIT RAY*

    Journal of Polymer Materials, Vol.37, No.3-4, pp. 143-164, 2020, DOI:10.32381/JPM.2020.37.3-4.3

    Abstract A new acrylamide monomer N-(3-(hexylamino)-N-(3-(isopropylamino)-3-oxopropyl) acrylamide (HA-NIPAM-AM) and a new RAFT agent O-propionyl-2-(N,N-diphenylcarbamothioylthio) propanoate have successfully been synthesized and used for the synthesis of poly(HA-NIPAM-AM) homopolymers via RAFT polymerization. The formed homopolymers have been characterized by GPC, 1 H NMR, FTIR, contact angle measurement, TG-DTA, DSC, and PXRD. Numberaveragemolar masses of the prepared polymers are in the range of 2,500 – 11,500 g/mol. Selfassembly of homopolymer has been studied viacmc determination in water using pyrene as fluorescence probe, HRTEM and DLS. Polymeris thermally stable up to 300 °C and has a glass transition temperature at 85.3 °C. XRD study reveals… More >

  • Open Access

    ARTICLE

    Acrylic Finished Leather Upgraded with Thermoplastic Polyurethane Filament using 3D Printing – A New Generation Hybrid Leather of Synthetic and Natural Polymer

    SIVARAJ SUDHAHARa,f, UMAMAHESWARI Gb, JAYA PRAKASH ALLAc, RAGHAVA RAO JONNALAGADDAd, SUGUNA LAKSHMIe, SANJEEV GUPTAf,*

    Journal of Polymer Materials, Vol.40, No.1-2, pp. 33-45, 2023, DOI:10.32381/JPM.2023.40.1-2.3

    Abstract Leather manufacturing process involves a lot of waste disposal which pollutes environment, some of the processes are inevitable. In the present investigation, 3D printing technology was used to reduce the wastage and to cover defective regions in leather. The present study focuses on synthesis of acrylic binder using emulsion polymerization technique. These binders were analysed for solid content for better optimisation of the amount of binder to be utilised for finishing operation. The experimental binder was prepared with 26% solids. Particle size and thermogravimetric analyses were carried out to understand the size and shape of the particles and their thermal… More >

  • Open Access

    ARTICLE

    ADVANCES IN THERMODIFFUSION AND THERMOPHORESIS (SORET EFFECT) IN LIQUID MIXTURES

    Morteza Eslamian*

    Frontiers in Heat and Mass Transfer, Vol.2, No.4, pp. 1-20, 2011, DOI:10.5098/hmt.v2.4.3001

    Abstract Recent advances in thermodiffusion (Soret effect) in binary and higher multicomponent liquid mixtures are reviewed. The mixtures studied include the hydrocarbon, associating, molten metal and semiconductor, polymer, and DNA mixtures. The emphasis is placed on the theoretical works, particularly models based on the nonequilibrium thermodynamics, although other approaches such as the statistical, kinetic and hydrodynamic approaches are discussed as well. For each mixture, the major theoretical and experimental works are discussed and the research trends and challenges are addressed. Some of the challenges include a need for combining various methods to develop a comprehensive theoretical model or at least to… More >

  • Open Access

    ARTICLE

    Application of Polygonum minus Extract in Enhancing Drought Tolerance in Maize by Regulating Osmotic and Antioxidant System

    Mingzhao Han1, Susilawati Kasim1,*, Zhongming Yang2, Xi Deng2, Md Kamal Uddin1, Noor Baity Saidi3, Effyanti Mohd Shuib1

    Phyton-International Journal of Experimental Botany, Vol.93, No.2, pp. 213-226, 2024, DOI:10.32604/phyton.2024.047150

    Abstract Drought stress is a major factor affecting plant growth and crop yield production. Plant extracts as natural biostimulants hold great potential to strengthen plants to overcome drought impacts. To explore the effect of Polygonum minus extract (PME) in enhancing drought tolerance in plants, a study was set up in a glasshouse environment using 10 different treatment combinations. PME foliar application were designed in CRD and effects were closely observed related to the growth, physiology, and antioxidant system changes in maize (Zea mays L.) under well-watered and drought conditions. The seaweed extract (SWE) was used as a comparison. Plants subjected to… More >

  • Open Access

    ARTICLE

    Heterophilic Graph Neural Network Based on Spatial and Frequency Domain Adaptive Embedding Mechanism

    Lanze Zhang, Yijun Gu*, Jingjie Peng

    CMES-Computer Modeling in Engineering & Sciences, Vol.139, No.2, pp. 1701-1731, 2024, DOI:10.32604/cmes.2023.045129

    Abstract Graph Neural Networks (GNNs) play a significant role in tasks related to homophilic graphs. Traditional GNNs, based on the assumption of homophily, employ low-pass filters for neighboring nodes to achieve information aggregation and embedding. However, in heterophilic graphs, nodes from different categories often establish connections, while nodes of the same category are located further apart in the graph topology. This characteristic poses challenges to traditional GNNs, leading to issues of “distant node modeling deficiency” and “failure of the homophily assumption”. In response, this paper introduces the Spatial-Frequency domain Adaptive Heterophilic Graph Neural Networks (SFA-HGNN), which integrates adaptive embedding mechanisms for… More >

  • Open Access

    ARTICLE

    Influence of Brownian Motion, Thermophoresis and Magnetic Effects on a Fluid Containing Nanoparticles Flowing over a Stretchable Cylinder

    Aaqib Majeed1,*, Ahmad Zeeshan2

    FDMP-Fluid Dynamics & Materials Processing, Vol.20, No.3, pp. 525-536, 2024, DOI:10.32604/fdmp.2023.028716

    Abstract The influence of Brownian motion and thermophoresis on a fluid containing nanoparticles flowing over a stretchable cylinder is examined. The classical Navier-Stokes equations are considered in a porous frame. In addition, the Lorentz force is taken into account. The controlling coupled nonlinear partial differential equations are transformed into a system of first order ordinary differential equations by means of a similarity transformation. The resulting system of equations is solved by employing a shooting approach properly implemented in MATLAB. The evolution of the boundary layer and the growing velocity is shown graphically together with the related profiles of concentration and temperature.… More >

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