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  • Open Access

    ARTICLE

    Removal of Dye Using Lignin-Based Biochar/Poly(ester amide urethane) Nanocomposites from Contaminated Wastewater

    Annesha Kar1, Niranjan Karak1,2,*

    Journal of Renewable Materials, Vol.12, No.9, pp. 1507-1540, 2024, DOI:10.32604/jrm.2024.052220 - 25 September 2024

    Abstract The pursuit of incorporating eco-friendly reinforcing agents in polymer composites has accentuated the exploration of various natural biomass-derived materials. The burgeoning environmental crisis spurred by the discharge of synthetic dyes into wastewater has catalyzed the search for effective and sustainable treatment technologies. Among the various sorbent materials explored, biochar, being renewable, has gained prominence due to its excellent adsorption properties and environmental sustainability. It has also emerged as a focal point for its potential to replace other conventional reinforcing agents, viz., fumed silica, aluminum oxide, treated clays, etc. This study introduces a novel class of… More > Graphic Abstract

    Removal of Dye Using Lignin-Based Biochar/Poly(ester amide urethane) Nanocomposites from Contaminated Wastewater

  • Open Access

    ARTICLE

    Conversion of Lignin into Porous Carbons for High-Performance Supercapacitors via Spray Drying and KOH Activation: Structure-Properties Relationship and Reaction Mechanism

    Shihao Feng1,2,3, Qin Ouyang1,2,*, Jing Huang1,2, Xilin Zhang3, Zhongjun Ma4, Kun Liang1,2, Qing Huang1,2,*

    Journal of Renewable Materials, Vol.12, No.7, pp. 1207-1218, 2024, DOI:10.32604/jrm.2024.052579 - 21 August 2024

    Abstract Lignin-derived porous carbons have emerged as promising electrode materials for supercapacitors. However, the challenge remains in designing and controlling their structure to achieve ideal electrochemical performance due to the complex molecular structure of lignin and its intricate chemical reactions during the activation process. In this study, three porous carbons were synthesized from lignin by spray drying and chemical activation with varying KOH ratios. The specific surface area and structural order of the prepared porous carbon continued to increase with the increase of the KOH ratio. Thermogravimetric-mass spectrometry (TG-MS) was employed to track the molecular fragments More > Graphic Abstract

    Conversion of Lignin into Porous Carbons for High-Performance Supercapacitors via Spray Drying and KOH Activation: Structure-Properties Relationship and Reaction Mechanism

  • Open Access

    ARTICLE

    Thermo-Mechanical, Physico-Chemical, Morphological, and Fire Characteristics of Eco-Friendly Particleboard Manufactured with Phosphorylated Lignin Addition

    Apri Heri Iswanto1,*, Harisyah Manurung1, Asma Sohail2, Lee Seng Hua3,9, Petar Antov4, Deded Sarip Nawawi5, Sarah Latifah5, Dewi Shafa Kayla5,6, Sukma Surya Kusumah6, Muhammad Adly Rahandi Lubis6, Linda Makovická Osvaldová7, Mohd. Hazwan Hussin8, Rangabhashiyam Selvasembian9, Lum Wei Chen10, Puji Rahmawati Nurcahyani6, Nam Hun Kim11, Widya Fatriasari6

    Journal of Renewable Materials, Vol.12, No.7, pp. 1311-1341, 2024, DOI:10.32604/jrm.2024.052172 - 21 August 2024

    Abstract Lignin, lignosulfonate, and synthesized phosphorylated lignosulfonate were introduced as green fillers in citric acid-sucrose adhesives for bonding particleboard fabricated from areca leaf sheath (ALS). The characteristics of particleboards were compared to that of ultralow emitting formaldehyde (ULEF-UF). The fillers derived from Eucalyptus spp. kraft-lignin were added for flame retardancy enhancement. 10% of each lignin and modified lignin was added into the ULEF-UF and citric acid-sucrose bonded particleboards. Analyses applied to particleboards included thermal characteristics, X-ray diffraction analysis (XRD), morphological properties, Fourier transform infrared spectroscopy (FTIR), as well as physical, mechanical, and fire resistance characteristics of the… More > Graphic Abstract

    Thermo-Mechanical, Physico-Chemical, Morphological, and Fire Characteristics of Eco-Friendly Particleboard Manufactured with Phosphorylated Lignin Addition

  • Open Access

    ARTICLE

    Adhesion of Technical Lignin-Based Non-Isocyanate Polyurethane Adhesives for Wood Bonding

    Jaewook Lee1, Byung-Dae Park1,*, Qinglin Wu2

    Journal of Renewable Materials, Vol.12, No.7, pp. 1187-1205, 2024, DOI:10.32604/jrm.2024.049948 - 21 August 2024

    Abstract Lignin is the most abundant aromatic natural polymer, and receiving great attention in replacing various petroleum-based polymers. The aim of this study is to investigate the feasibility of technical lignin as a polyol for the synthesis of non-isocyanate polyurethane (NIPU) adhesives to substitute current polyurethane (PU) adhesives that have been synthesized with toxic isocyanate and polyols. Crude hardwood kraft lignin (C-HKL) was extracted from black liquor from a pulp mill followed by acetone fractionation to obtain acetone soluble-HKL (AS-HKL). Then, C-HKL, AS-HKL, and softwood sodium lignosulfonate (LS) were used for the synthesis of technical lignin-based… More > Graphic Abstract

    Adhesion of Technical Lignin-Based Non-Isocyanate Polyurethane Adhesives for Wood Bonding

  • Open Access

    ARTICLE

    One-Step to Prepare Lignin Based Fluorescent Nanoparticles with Excellent Radical Scavenging Activity

    Xujing Zhang1, Hatem Abushammala2, Debora Puglia3, Binbao Lu1, Pengwu Xu1, Weijun Yang1,*, Piming Ma1

    Journal of Renewable Materials, Vol.12, No.5, pp. 895-908, 2024, DOI:10.32604/jrm.2024.049810 - 17 July 2024

    Abstract Fluorescent nanomaterials have attracted much attention, due to their unique luminescent properties and promising applications in biomedical areas. In this study, lignin based fluorescent nanoparticles (LFNP) with high yield (up to 32.4%) were prepared from lignin nanoparticles (LNP) by one-pot hydrothermal method with ethylenediamine (EDA) and citric acid. Morphology and chemical structure of LFNP were investigated by SEM, FT-IR, and zeta potential, and it was found that the structure of LFNP changed with the increase of citric acid addition. LFNP showed the highest fluorescence intensity under UV excitation at wavelengths of 375–385 nm, with emission More > Graphic Abstract

    One-Step to Prepare Lignin Based Fluorescent Nanoparticles with Excellent Radical Scavenging Activity

  • Open Access

    REVIEW

    Wood By-Products as UV Protection: A Consequence Review

    Naglaa Salem El‑Sayed, Mohamed Hasanin, Samir Kamel*

    Journal of Renewable Materials, Vol.12, No.4, pp. 699-720, 2024, DOI:10.32604/jrm.2024.049118 - 12 June 2024

    Abstract In recent decades, the ozone layer has suffered considerable damage, increasing the entry of ultraviolet (UV) light into the atmosphere and reaching the earth’s surface, negatively affecting life. Accordingly, researchers aimed to solve this problem by synthesizing advanced UV-shielding materials. On the other hand, developing an easy and green strategy to prepare functional materials with outstanding properties based on naturally abundant and environmentally friendly raw materials is highly desirable for sustainable development. Because biomass-derived materials are sustainable and biodegradable, they present a promising substitute for petroleum-based polymers. The three main structural constituents of the plant More > Graphic Abstract

    Wood By-Products as UV Protection: A Consequence Review

  • Open Access

    ARTICLE

    Properties of Bark Particleboard Bonded with Demethylated Lignin Adhesives Derived from Leucaena leucocephala Bark

    Rafidah Md Salim1,2,*, Jahimin Asik2, Mohd Sani Sarjadi2

    Journal of Renewable Materials, Vol.12, No.4, pp. 737-769, 2024, DOI:10.32604/jrm.2024.045695 - 12 June 2024

    Abstract Lignin extraction from bark can maximize the utilization of biomass waste, offer cost-effectiveness, and promote environmental friendliness when employed as an adhesive material in bark particleboard production. Particles of fine (0.2 to 1.0 mm), medium (1.0 to 2.5 mm), and coarse (2.5 to 12.0 mm) sizes, derived from the bark of Leucaena leucocephala, were hot-pressed using a heating plate at 175°C for 7 min to create single-layer particleboards measuring 320 mm × 320 mm × 10 mm, targeting a density of 700 kg/m. Subsequently, the samples were trimmed and conditioned at 20°C and 65% relative humidity.… More > Graphic Abstract

    Properties of Bark Particleboard Bonded with Demethylated Lignin Adhesives Derived from <i>Leucaena leucocephala</i> Bark

  • Open Access

    ARTICLE

    Color and Gloss Changes of a Lignin-Based Polyurethane Coating under Accelerated Weathering

    Fatemeh Hassani Khorshidi1, Saeed Kazemi Najafi1, Farhood Najafi2,*, Antonio Pizzi3,*, Dick Sandberg4, Rabi Behrooz1

    Journal of Renewable Materials, Vol.12, No.2, pp. 305-323, 2024, DOI:10.32604/jrm.2023.043953 - 11 March 2024

    Abstract The purpose of this research study was to investigate the properties of polyurethane coatings based on lignin nano-particles. For this purpose, the prepared coatings were applied to pine wood surfaces and weathered artificially. Subsequently, color and gloss of the coatings were measured before and after the weathering test. Field emission scanning electron microscopy (FE-SEM) micrographs prepared from the coatings showed that the average size of nano-particles in the polyurethane substrate was approximately 500 nm. Nuclear magnetic resonance (13C-NMR) spectroscopy showed that strong urethane bonds were formed in the nano-lignin-based polyurethane. Differential calorimetric analysis (DSC) test revealed… More > Graphic Abstract

    Color and Gloss Changes of a Lignin-Based Polyurethane Coating under Accelerated Weathering

  • Open Access

    ARTICLE

    Enhancing Hydrocarbon-Rich Bio-Oil Production via Catalytic Pyrolysis Fortified with Microorganism Pretreatment

    Jiapeng Wang1, Bo Zhang1,*, Haoqiang Cheng1, Zhixiang Xu2

    Journal of Renewable Materials, Vol.11, No.10, pp. 3595-3612, 2023, DOI:10.32604/jrm.2023.030005 - 10 August 2023

    Abstract A new method of pretreatment of corn straw with Phanerochaete chrysosporium combined with pyrolysis was proposed to improve the quality of bio-oil. The characterization results demonstrated that microbial pretreatment was an effective method to decrease the lignin, which can achieve a maximum removal rate of 44.19%. Due to the destruction of biomass structure, the content of alkali metal and alkaline earth metal is reduced. Meanwhile, the depolymerized biomass structure created better pyrolysis conditions to promote the pyrolysis efficiency, increase the average decomposition rate of pyrolysis and reduce the residue. In fast pyrolysis, because of the enrichment… More > Graphic Abstract

    Enhancing Hydrocarbon-Rich Bio-Oil Production via Catalytic Pyrolysis Fortified with Microorganism Pretreatment

  • Open Access

    ARTICLE

    Effects of Filler-Asphalt Ratio on the Properties of Lignin and Polyester Fiber Reinforced SMPU/SBS Modified Asphalt Mortar

    Wenjing Xia1,*, JinHui Wang1, Tao Xu1, Nan Jiang2

    Journal of Renewable Materials, Vol.11, No.8, pp. 3387-3402, 2023, DOI:10.32604/jrm.2023.026971 - 26 June 2023

    Abstract To understand the effects of filler-asphalt ratio on different properties of lignin and polyester fiber reinforced shape memory polyurethane (SMPU)/styrene butadiene styrene (SBS) composite modified asphalt mortar (PSAM), as well as to reveal the reinforcing and toughening mechanisms of lignin and polyester fibers on PSAM, SMPU, SBS and mineral powder were first utilized to prepare PSAM. Then the conventional, rheological and anticracking properties of lignin fiber reinforced PSAM (LFAM) and polyester fiber reinforced PSAM (PFAM) at different filler-asphalt ratios were characterized. Test results indicate that the shear strength, deformation resistance and viscosity are increased after… More > Graphic Abstract

    Effects of Filler-Asphalt Ratio on the Properties of Lignin and Polyester Fiber Reinforced SMPU/SBS Modified Asphalt Mortar

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