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  • Open Access

    ARTICLE

    Curing Kinetics of Tannin and Lignin Biobased Adhesives Determined by DSC and ABES

    Jaša Saražin1, Ida Poljanšek1, Antonio Pizzi2, Milan Šernek1,*

    Journal of Renewable Materials, Vol.10, No.8, pp. 2117-2131, 2022, DOI:10.32604/jrm.2022.019602 - 25 April 2022

    Abstract The curing process of two biobased adhesives: pine tanninhexamine (TH) and organosolv lignin non-isocyanate polyurethane (NIPU), suitable for interior nonstructural use, were compared with commercial urea-formaldehyde (UF) adhesive. Changes in chemical structure before and after the curing process were observed with Fouriertransform infrared spectroscopy (FTIR). The process of adhesive curing was monitored with differential scanning calorimetry (DSC) and the automated bonding evaluation system (ABES). Both DSC and ABES measurements confirmed UF as the fastest and NIPU as the slowest curing adhesive observed. Taking into account the ABES results, the optimal pressing parameters for the TH… More >

  • Open Access

    ARTICLE

    Calcium chloride linked camel milk derived casein nanoparticles for the delivery of sorafenib in hepatocarcinoma cells

    AASTHA MITTAL1, NEELAM MAHALA1, KOWTHAVARAPU VENKATA KRISHNA2, UMA S. DUBEY1,*, SUNIL KUMAR DUBEY2,3,*

    BIOCELL, Vol.46, No.1, pp. 127-136, 2022, DOI:10.32604/biocell.2021.015932 - 29 September 2021

    Abstract Sorafenib, a multikinase inhibitor used for the treatment of hepatocellular carcinoma, is limited by its low oral bioavailability. To overcome this drawback, we have developed novel camel milk casein-derived nanoparticles as a drug delivery system. Camel milk casein is not only biocompatible on oral administration but is actually a dietary protein of pharmaceutical relevance. Casein is used because of its amphiphilic nature, self-assembling property, ability to show sustained release, and capability of encapsulating both hydrophilic and hydrophobic drugs. In this study, camel milk casein nanoparticles loaded with sorafenib were developed and characterized. Characterization of casein… More >

  • Open Access

    ARTICLE

    Biochemical and Thermal Analysis of Spirulina Biomass through FTIR, TGA, CHN

    Ruma Arora Soni1,*, K. Sudhakar1,3,4,*, R. S. Rana2

    Energy Engineering, Vol.118, No.4, pp. 1045-1056, 2021, DOI:10.32604/EE.2021.016082 - 31 May 2021

    Abstract Spirulina is a sort of algae that grows in both fresh and seawater. It is considered the Earth’s most nutritionally dense food. Certain claims about Spirulina’s beneficial health properties are attributed to the relatively high protein content of the cells. Spirulina’s lipid, fatty acid profile, and biochemical composition have received little attention. The purpose of this study is to investigate the nature and decomposition of spirulina biomass at various temperatures. In the present investigation, Fourier transforms infrared spectroscopy, thermogravimetric analysis, and elemental analysis were used to study spirulina biomass biochemical characteristics. The optimal content of… More >

  • Open Access

    ARTICLE

    Organosolv Lignin for Non-Isocyanate Based Polyurethanes (NIPU) as Wood Adhesive

    Jaša Saražin1, Antonio Pizzi2, Siham Amirou2, Detlef Schmiedl3, Milan Šernek1,*

    Journal of Renewable Materials, Vol.9, No.5, pp. 881-907, 2021, DOI:10.32604/jrm.2021.015047 - 20 February 2021

    Abstract A non-isocyanate-based polyurethane (NIPU) wood adhesive was produced from organosolv lignin, which is a bio-sourced raw material, available in large quantities and produced as a by-product of the paper industry. The formulation of this new lignin-based NIPU adhesive, which is presented, was chemically characterised by Matrix-Assisted Laser Desorption Ionization Time of Flight (MALDI ToF) mass spectrometry and by Fourier Transform Infra-Red (FTIR) spectrometry analyses. The oligomers formed were determined and showed that the three species involved in the NIPU adhesive preparation were formed by the co-reaction of the three reagents used: lignin, dimethyl carbonate, and… More >

  • Open Access

    ARTICLE

    Synthesis of Green Adhesive with Tannin Extracted from Eucalyptus Bark for Potential Use in Wood Composites

    Medjda Amari1, Kamel Khimeche1,*, Abdelkader Hima2 , Redouane Chebout3, Abderahmane Mezroua1

    Journal of Renewable Materials, Vol.9, No.3, pp. 463-475, 2021, DOI:10.32604/jrm.2021.013680 - 14 January 2021

    Abstract Recently, the exploitation of renewable plant resources in the formulation of adhesives is very promising for their availability at low coast, as well as their richness in biomolecules such as polyphenols. In this way, many research studies tannins extracted from different sources such as mimosa, quebracho, and pine have been the subject of very satisfactory recent studies. In this paper, a new complete characterization of the tannins extracted from the bark of eucalyptus globulus harvested from two regions in Algeria was achieved. The structural characterization enabled us to confirm the richness in condensed tannins, particularly in procyanidin More >

  • Open Access

    ARTICLE

    Analysis of the Mechanism and Effectiveness of Lignin in Improving the High-Temperature Thermal Stability of Asphalt

    Cheng Cheng1,2,*, Weiwei Sun2, Bo Hu3, Guixiang Tao2, Chao Peng2, Yanjuan Tian4, Shujuan Wu4,5

    Journal of Renewable Materials, Vol.8, No.10, pp. 1243-1255, 2020, DOI:10.32604/jrm.2020.012054 - 31 August 2020

    Abstract The use of lignin, which is a by-product of the pulp and paper industry, in the development of asphalt binders would contribute to waste reduction, providing environmental, economic, and social benefits. In this study, samples of lignin-modified asphalt binder samples with different content of lignin (3%, 6%, 9%, 12%, and 15%) and unmodified asphalt (control) were tested using Fourier transform infrared spectroscopy (FTIR), dynamic shear rheometer (DSR), and thermogravimetry. The mechanism and effectiveness of lignin in improving the thermal stability of asphalt at high temperatures were analyzed. The FTIR analysis shows that no new characteristic… More >

  • Open Access

    ARTICLE

    Application of the Principles of “Green Chemistry” for the Synthesis of 10-Undecylenic Aliphatic Esters with Antimicrobial Activity

    Dragomir Vassilev1,*, Nadezhda Petkova2, Yulian Tumbarski3, Milena Koleva1, Panteley Denev2

    Journal of Renewable Materials, Vol.8, No.6, pp. 675-686, 2020, DOI:10.32604/jrm.2020.09279 - 12 May 2020

    Abstract Undenicylic acid (10:1) is known as an antifungal agent and an active ingredient of many topical medicines [1–6]. The present research investigates the preparation of aliphatic esters of 10-undecylic acid with butanol and i-amyl alcohol by the conventional and ultrasound-assisted syntheses as well as the structural elucidation of the resulting compounds, by FTIR and NMR spectroscopy. The antimicrobial properties of the obtained 10-undecylenic esters were tested against Gram-positive bacteria (Staphylococcus aureus; Enterococcus faecalis; Listeria monocytogenes), Gram-negative bacteria (Escherichia coli; Salmonella sp.) and filamentous fungi (Penicillium sp.; Aspergillus niger; Fusarium moniliforme) using the conventional agar-well diffusion assay. The results demonstrated that all More >

  • Open Access

    ARTICLE

    Physicochemical Characterization and Antimicrobial Properties of Inulin Acetate Obtained by Microwave-Assisted Synthesis

    Nadezhda Petkova1,*, Radka Arabadzhieva1, Dragomir Vassilev2, Gergana Gencheva1, Yulian Tumbarski3, Tsveteslava Ignatova-Ivanova4, Sevginar Ibryamova4, Mina Todorova1, Milena Koleva2, Panteley Denev1

    Journal of Renewable Materials, Vol.8, No.4, pp. 365-381, 2020, DOI:10.32604/jrm.2020.09292 - 24 April 2020

    Abstract Microwave-assisted irradiation was performed for esterification of chicory inulin with high degree of polymerization with acetic anhydride without a solvent only with a catalyst. The resulting esters were characterized by melting point, hydrophilic-lipophilic balance, thin-layer chromatography, ultraviolet spectroscopy, Fourier transform infrared spectroscopy (FTIR) and nuclear magnetic resonance (NMR) spectroscopy. Inulin acetate demonstrated a high degree of acetylation (2.5–3.0) and presented a white, water-insoluble substance with bitter taste. The FTIR and NMR spectra confirmed esterification and demonstrated the incorporation of hydrophobic residue to the water soluble inulin backbone. Swelling capacity, water holding, oil-holding capacities, the foamability,… More >

  • Open Access

    ARTICLE

    Energy Conversion and Utilization System of Municipal Solid Waste

    Qin Liu*, Ruliang Zhang

    Energy Engineering, Vol.117, No.2, pp. 89-98, 2020, DOI:10.32604/EE.2020.010373 - 23 April 2020

    Abstract With the development of urbanization in China, the problem of garbage disposal has become increasingly serious. Among the existing waste treatment technologies, pyrolysis is an emerging treatment technology, which has obvious advantages in terms of reduction and secondary pollution. It has good development prospects. This article first compares the advantages and disadvantages of various existing waste treatment technologies, and proposes an organization method that combines thermogravimetric analysis, kinetic analysis, tube furnace experiments, and domestic waste pyrolysis and low-calorie heat the decomposed gases burn together. Urban garbage is one of the main pollution sources of modern… More >

  • Open Access

    ARTICLE

    Waveband Selection with Equivalent Prediction Performance for FTIR/ATR Spectroscopic Analysis of COD in Sugar Refinery Waste Water

    Jun Xie1, Dapeng Sun1, Jiaxiang Cai2, Fuhong Cai1,*

    CMC-Computers, Materials & Continua, Vol.59, No.2, pp. 687-695, 2019, DOI:10.32604/cmc.2019.03658

    Abstract The level of chemical oxygen demand (COD) is an important index to evaluate whether sewage meets the discharge requirements, so corresponding tests should be carried out before discharge. Fourier transform infrared spectroscopy (FTIR) and attenuated total reflectance (ATR) can detect COD in sewage effectively, which has advantages over conventional chemical analysis methods. And the selection of characteristic bands was one of the key links in the application of FTIR/ATR spectroscopy. In this work, based on the moving window partial least-squares (MWPLS) regression to select a characteristic wavelength, a method of equivalent wavelength selection was proposed More >

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