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  • Open Access

    ARTICLE

    Rheological Investigation on a Polypropylene/Low Density Polyethylene Blending Melt

    Huayong Liao1,2,3,*, Jing Gao1,2,3, Chunlin Liu1,2,3, Guoliang Tao1,2,3

    Journal of Polymer Materials, Vol.41, No.1, pp. 45-54, 2024, DOI:10.32604/jpm.2024.053021

    Abstract Polymer blending with co-continuous morphology has garnered the interest of many researchers, but corresponding rheological models are rarely presented. In this study, the dynamic rheological behavior of a blend of polypropylene (PP) and low-density polyethylene (LDPE) in the ratio of 50/50 wt% is investigated, and a rheological model suggested by Yu et al. is used to fit the dynamic modulus. The rheological measurement shows that at low frequency, pure PP has higher complex viscosity and dynamic modulus than LDPE. SEM images reveal that the morphology among the 40/60 and 60/40 blends is non-dispersive. The fitting… More >

  • Open Access

    ARTICLE

    Fabrication of Core-Shell Hydrogel Bead Based on Sodium Alginate and Chitosan for Methylene Blue Adsorption

    Xiaoyu Chen*

    Journal of Renewable Materials, Vol.12, No.4, pp. 815-826, 2024, DOI:10.32604/jrm.2024.048470

    Abstract A novel core-shell hydrogel bead was fabricated for effective removal of methylene blue dye from aqueous solutions. The core, made of sodium alginate-g-polyacrylamide and attapulgite nanofibers, was cross-linked by Calcium ions (Ca). The shell, composed of a chitosan/activated carbon mixture, was then coated onto the core. Fourier transform infrared spectroscopy confirmed the grafting polymerization of acrylamide onto sodium alginate. Scanning electron microscopy images showed the core-shell structure. The core exhibited a high water uptake ratio, facilitating the diffusion of methylene blue into the core. During the diffusion process, the methylene blue was first adsorbed by More > Graphic Abstract

    Fabrication of Core-Shell Hydrogel Bead Based on Sodium Alginate and Chitosan for Methylene Blue Adsorption

  • Open Access

    ARTICLE

    miR-92a Inhibits Proliferation and Induces Apoptosis by Regulating Methylenetetrahydrofolate Dehydrogenase 2 (MTHFD2) Expression in Acute Myeloid Leukemia

    Yueli Gu*, Jinchun Si, Xichun Xiao*, Ying Tian*, Shuo Yang*

    Oncology Research, Vol.25, No.7, pp. 1069-1079, 2017, DOI:10.3727/096504016X14829256525028

    Abstract Aberrant expression of microRNA-92a (miR-92a) has been investigated in various cancers. However, the function and mechanism of miR-92a in acute myeloid leukemia (AML) remain to be elucidated. Our data showed that miR-92a was evidently downregulated and methylenetetrahydrofolate dehydrogenase 2 (MTHFD2) was remarkably upregulated in AML cell lines HL-60 and THP-1. Dual luciferase reporter assay revealed that MTHFD2 was a direct target of miR-92a. Gain- and loss-of-function analysis demonstrated that MTHFD2 knockdown or miR-92a overexpression notably inhibited proliferation and promoted apoptosis of AML cell lines. Restoration of MTHFD2 expression reversed proliferation inhibition and apoptosis induction of More >

  • Open Access

    ARTICLE

    Synthesis and Characterization of Phenyl Camellia oleifera Seed Oil Ester Plasticizing PVC

    Wenqing Xiao1,#, Yuhang Liu2,#, Yuxin He1, Qiaoguang Li1,*, Yongquan Li3,*

    Journal of Renewable Materials, Vol.12, No.3, pp. 615-628, 2024, DOI:10.32604/jrm.2023.046780

    Abstract Plasticizers are essential additives in the processing of polyvinyl chloride (PVC), with phthalate plasticizers being widely used. However, these conventional plasticizers have been shown to be harmful to human health and environmentally unfriendly, necessitating the exploration of eco-friendly bio-based alternatives. In this study, Camellia oleifera seed oil, a specialty resource in China, was utilized as a raw material and reacted with 4,4′-Methylenebis(N,N-diglycidylaniline) (AG-80) to synthesize Phenyl Camellia seed Oil Ester (PCSOE). PCSOE was employed as a plasticizer to prepare modified PVC films with varying concentrations, with the conventional plasticizer dioctyl phthalate (DOP) serving as a control.… More >

  • Open Access

    ARTICLE

    An Experimental Study and Analysis of Different Dielectrics in Electrical Discharge Machining of Al 6063 Alloy

    B. MOULIPRASANTHA, P. HARIHARANB

    Journal of Polymer Materials, Vol.36, No.4, pp. 351-369, 2019, DOI:10.32381/JPM.2019.36.04.5

    Abstract Electrical discharge machining is a non-traditional machining processes in which it is based upon thermal and electrical energy source as an interval energy pulse discharge in-between the work piece and tool electrode so as to remove the material. A systematical investigation of melting and vaporising of aluminium to find the output responses such as Material removal rate (MRR), Electrode wear rate (Ra), and Surface finish (EWR) in EDM using two different dielectrics was conducted as experimental work. The working fluids are Polyethylene glycol (PEG 600) and kerosene. It is the hour of need to get the More >

  • Open Access

    ARTICLE

    CuBr2/Me6 TREN Mediated ARGET ATRP of Methyl acrylate in Polyethylene Glycol

    XIANRONG SHEN1,*, DENGZHOU XIA1, YIXIN XIANG1, JIANGANG GAO1

    Journal of Polymer Materials, Vol.36, No.3, pp. 229-241, 2019, DOI:10.32381/JPM.2019.36.03.3

    Abstract ARGET ATRP of methyl acrylate (MA) with low concentration of air stable-CuBr2 catalyst was successfully carried out in green solvent polyethylene glycol (PEG) without any external reducing agent.The polymerizations of MA proceeded in a well-controlled manner as evidenced by kinetic studies, chain extension results, a linear increase of the molecular weights with the increasing of monomer conversion. and narrow molecular weight distribution (Mw/Mn =1.1). Interestingly, we found that the PEG has the reduction ability to CuBr2 and could play as supplement reducing agent cooperation with Me6 TREN to mediate ARGET ATRP. Reduction of Cu(II)Br2 to Cu(I)Br by different More >

  • Open Access

    ARTICLE

    Plasticized Polyethylene/Chitosan Blend Films and Study of the Effect of Plasticizers on their various Properties and Biodegradabilty

    HULYA SEMA KOKER1, HÜLYA YAVUZ ERSAN1, AYSE AYTAC2,3,*

    Journal of Polymer Materials, Vol.37, No.3-4, pp. 165-177, 2020, DOI:10.32381/JPM.2020.37.3-4.4

    Abstract Chitosan (CH) and low-density polyethylene (PE) blend films were produced by a twin-screw extruder and heat press with different plasticizers glycerol (GLY), sorbitol (SOR) and polyethylene glycol (PEG). The tensile strength decreased and elongation at break increased with the incorporation of plasticizer for blends with 10 wt% of CH. The thermal stability of the films was slightly higher for films containing GLY and PEG as compared to SOR. Contact angles reduced from CH-PE film to the films containing PEG, SOR and GLY in decreasing order, respectively. Fourier transform infrared spectroscopy revealed no interactions between CH More >

  • Open Access

    ARTICLE

    Preparation of Oil Shale Ash Filled High Density Polyethylene Composite Materials and their Characterization

    RAID BANAT1,*, MANAL AL-RAWASHDEH1, HEBA ALKHLAIFAT1

    Journal of Polymer Materials, Vol.38, No.1-2, pp. 137-151, 2021, DOI:10.32381/JPM.2021.38.1-2.11

    Abstract Composite of oil Shale ash (OSA) filler and high density polyethylene (HDPE) matrix was formulated and studied. OSA mainly composed of Ca, Si, and Fe most of which in oxide forms. OSA-HDPE composite with 0, 5, 10, 15, 20, and 25 wt. % OSA were produced using extrusion and hot press. Mechanical, morphological, and water uptake properties of the composite are discussed herein. While the tensile stress at yield, 47 MPa, restored its value close to the neat HDPE, an increase in the mean values of the tensile stress at rapture from 19 to 33… More >

  • Open Access

    ARTICLE

    Investigation of Polypyrrole and Polypyrrolepolyethyleneimine as Adsorbents for Methyl Orange Dye Adsorption

    NORHABIBAH MOHAMAD1,*, NOORDINI M. SALLEH1,2, HABIBUN NABI MUHAMMAD EKRAMUL MAHMUD1

    Journal of Polymer Materials, Vol.40, No.3-4, pp. 165-189, 2023, DOI:10.32381/JPM.2023.40.3-4.4

    Abstract The present study has explored the adsorption properties of polypyrrole-based adsorbents (polypyrrole and polypyrrole-polyethyleneimine composite) as novel conducting polymers in adsorbing methyl orange (MO) (an anionic dye) effectively from aqueous solution. The adsorption characteristics of the prepared polymer-based adsorbents were characterized by BET, FTIR, FESEM, and XRD methods. The effectiveness of PPy-based adsorbents for MO dye adsorption was examined using the batch adsorption method. Different parameters were changed during the adsorption process, including contact time, solution pH, and adsorbent dosage. The highest BET surface area of the PPy-PEI composite was found to be 11.85 m2 /g,… More >

  • Open Access

    ARTICLE

    SiRAP2-12, a Positive Regulatory Factor, Effectively Improves the Waterlogging Tolerance of Foxtail Millet (Setaria italica)

    Xueyan Xia1,#, Xiaohong Fu2,#, Yu Zhao1, Jihan Cui1, Nuoya Xiao1, Jingxin Wang1, Yiwei Lu1, Meihong Huang1, Cheng Chu1, Jia Zhang2, Mengxin Yang2, Shunguo Li1,*, Jianfeng Liu2,*

    Phyton-International Journal of Experimental Botany, Vol.93, No.3, pp. 445-465, 2024, DOI:10.32604/phyton.2024.048273

    Abstract Foxtail millet (Setaria italica) growth was inhibited because of waterlogging stress, which has caused yield reduction. ERF family plays an important role to plant adversity tolerance. In our study, we obtained 19,819 differential expressed genes (DEGs) between the two treatments based on the RNA-seq sequencing of foxtail millet of waterlogging stress. Furthermore, a total of 28 ERF family members were obtained, which have a complete open reading frame. We studied the evolution and function of SiERF family and how they affected the waterlogging tolerance. It was found that SiERF1A/B/C (GenBank ID: OR775217, OR775219, OR775218) and SiRAP2-12 (GenBank… More >

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