Henky Muljana^*, Ivana Hasjem, Merianawati Sinatra, Dicky Joshua Pesireron, Michael Wilbert Puradisastra, Ryan Hartono, Kevin Yovan Hermanto, Tony Handoko

Journal of Renewable Materials, Vol.11, No.12, pp. 4039-4060, 2023, DOI:10.32604/jrm.2023.031261 - 10 November 2023

Abstract This research paper describes the synthesis of thermo-reversible cross-linking of sago starch by grafting a furan pendant group (methyl 2-furoate) onto the starch backbone, followed by a Diels-Alder (DA) reaction of the furan functional group with 1,1′-(methylenedi-4,1-phenylene) bismaleimide (BM). The proof of principles was provided by FTIR and ¹H-NMR analyses. The relevant FTIR peaks are the carbonyl peak (υ C=O sym) at 1721 cm⁻¹ ; the two peaks appeared after DA cross-linking, i.e., at 1510 cm⁻¹ (corresponding to υ CH=CH BM aromatic rings, stretching vibrations), and at 1173 cm⁻¹ (assigned to cycloadduct (C-O-C, δ DA ring)) while More > Graphic Abstract

Zicheng Zhao^1,2, Zhihong Xiao², Xudong Liu², Desheng Kang³, Wenzheng Dong¹, Qiquan Lin^1,*, Aihua Zhang^2,*

Journal of Renewable Materials, Vol.11, No.4, pp. 1661-1686, 2023, DOI:10.32604/jrm.2023.023669 - 01 December 2022

Abstract Tung oil (TO)/ultraviolet (UV) photo-composite curing material possesses the characteristics of low curing temperature, low material shrinkage and low environmental pollution. Accordingly, this material must be developed and utilized with the conjugated double bonds contained in the long chain of the main structure (α-tung acid) molecules in the refined TO. The aforementioned material can be chemically modified using a variety of chemical methods to develop a new TO-based UV photocurable material due to its unique chemical properties. This work reviews the research progress of TO/UV photo-composite curing materials in recent years. Firstly, the chemical structure More >

Junlong Yao^1,2, Wei Nie¹, Zhengguang Sun², Huan Yang^1,3,*, Yu Guan¹, Lin Gao⁴, Xueliang Jiang¹, Mujie Guo¹, Chuanxi Xiong^5,*

Journal of Renewable Materials, Vol.10, No.9, pp. 2355-2364, 2022, DOI:10.32604/jrm.2022.019339 - 30 May 2022

Abstract In general, self-healing dielectric composites are mainly composed of polar hydrogen bonds, which have high hydrophilicity and are unsuitable for humid environment. Dielectric composite with Diels-Alder (D-A) bond contains covalent bonds, it can be adopted as an efficient self-healing material. Here, we construct self-healing barium titanate (BT)/polyurethane (PU) dielectric composites by adopting PU with D-A bond as matrix (BT/ PU-DA). The prepared 10% BT/PU-DA composite exhibits superior self-healing ability than that of PU-DA. Moreover, its dielectric constant can reach 9.3 with a loss of only 0.04 at 1000 Hz and maintain 93% repair effi- ciency More >

Talita M. Lacerda^1,2,*, Alessandro Gandini^1,2

Journal of Renewable Materials, Vol.2, No.1, pp. 2-12, 2014, DOI:10.7569/JRM.2013.634127

Abstract The inevitable future scarcity of fossil resources, coupled with sustainability considerations, have stimulated the use of renewable resources for material synthesis, and highly effi cient polymerization methods that meet the requirements of green chemistry have drawn attention to fatty acid-based polymers. Additionally, the polymerization of furan monomers and the exploitation of some of the chemical peculiarities of the furan heterocycle have generated a wide diversity of macromolecular materials. A novel approach is reviewed here, calling upon the combined use of both vegetable oils and their derivatives together with furans, as a promising technique to obtain More >