Indra Mamad Gandidi^1,2,*, Sukarni Sukarni^3,4, Avita Ayu Permanasari³, Purnami Purnami⁵, Tuan Amran Tuan Abdullah⁶, Anwar Johari⁶, Nugroho Agung Pambudi^7,*

Energy Engineering, Vol.121, No.12, pp. 3635-3648, 2024, DOI:10.32604/ee.2024.054943 - 22 November 2024

Abstract The use of catalysts has significantly enhanced the yield and quality of in-situ pyrolysis products. However, there is a lack of understanding regarding pyrolysis approaches that utilize several low-cost natural catalysts (LCC) and their placement within the reactor. Therefore, this study aims to examine the effects of various LCC on the in-situ pyrolysis of spirulina platensis microalgae (SPM) and investigate the impact of different types of catalysts. We employed LCC such as zeolite, dolomite, kaolin, and activated carbon, with both layered and uniformly mixed LCC-SPM placements. Each experiment was conducted at a constant temperature of 500°C… More > Graphic Abstract

Sheng Guo^1,2,*, Mengmeng Yang¹, Yao Huang², Xizi Gao¹, Chao Cai^3,*, Kun Zhou^4,5,*

The International Conference on Computational & Experimental Engineering and Sciences, Vol.30, No.4, pp. 1-1, 2024, DOI:10.32604/icces.2024.012655

Abstract 3D printing technology has demonstrated considerable potential in wastewater remediation. Zero-valent metal (ZVM) has been recognized as an efficient catalyst facilitating the organic pollutant degradation in water. However, owing to its inclination toward oxidation and aggregation, the practical utilization of ZVM remains a challenge. Herein, we have employed 3D printing techniques to fabricate hierarchically porous ZVM, such as zero-valent copper and zero-valent iron, which exhibit a high level of printing precision and commendable resistance to compression. These 3D-ZVM catalysts can effectively activate peroxymonosulfate (PMS), thereby degrading various organic pollutants, including tetracycline, ciprofloxacin, rhodamine B, and… More >

Sujeet Kesharvani¹, Sakhi Katre¹, Suyasha Pandey¹, Gaurav Dwivedi^1,*, Tikendra Nath Verma², Prashant Baredar¹

Energy Engineering, Vol.121, No.9, pp. 2363-2388, 2024, DOI:10.32604/ee.2024.052523 - 19 August 2024

Abstract This study delves into biodiesel synthesis from non-edible oils and algae oil sources using Response Surface Methodology (RSM) and an Artificial Neural Network (ANN) model to optimize biodiesel yield. Blend of C. vulgaris and Karanja oils is utilized, aiming to reduce free fatty acid content to 1% through single-step transesterification. Optimization reveals peak biodiesel yield conditions: 1% catalyst quantity, 91.47 min reaction time, 56.86°C reaction temperature, and 8.46:1 methanol to oil molar ratio. The ANN model outperforms RSM in yield prediction accuracy. Environmental impact assessment yields an E-factor of 0.0251 at maximum yield, indicating responsible production… More >

Abhishek Kumar Patel, Ashlesha P. Kawale, Neeru Sharma, Nishant Shekhar, Subhash Banerjee^*, Arti Srivastava^*

Journal of Polymer Materials, Vol.41, No.2, pp. 69-86, 2024, DOI:10.32604/jpm.2024.052695 - 09 August 2024

Abstract This study aims to synthesize, characterize, and evaluate the photocatalytic efficiency of carboxymethyl cellulose (CMC) wrapped ZnONPs for the degradation of methylene blue (MB) dye under sunlight and also focuses on the effect of varying calcination temperatures on crystallite size of the synthesized ZnONPs@CMC. It focuses on developing biopolymer (CMC) wrapped ZnO nanoparticles (ZnONPs@CMC) at different calcination temperatures. ZnONPs@CMC are synthesized using zinc acetate dihydrate as a precursor under alkaline conditions, followed by adding capping agent CMC at various calcination temperatures ranging from 250°C to 650°C. The nanomaterials are characterized by UV-Vis, FTIR, and powder… More >

Medta Boupan^1,2, Kanyapak Prompang¹, Achiraya Chompunuch¹, Piwat Boonma¹, Arthit Neramittagapong^1,2,3,4, Somnuk Theerakulpisut⁵, Sutasinee Neramittagapong^1,2,3,*

Journal of Renewable Materials, Vol.11, No.7, pp. 2985-3000, 2023, DOI:10.32604/jrm.2023.026397 - 05 June 2023

Abstract Isosorbide is a multi-purpose chemical that can be produced from renewable resources. Specifically, it has been investigated as a replacement for toxic bisphenol A (BPA) in the production of polycarbonate (PC). In this study, the synthesis of isosorbide by sorbitol dehydration using a cerium-based catalyst derived from calcined cerium (IV) sulfate (300°C, 400°C, 450°C, 500°C, and 650°C) was investigated. The reaction occurred in a high-pressure reactor containing nitrogen gas. Advanced instrumental techniques were applied to analyze the characteristics of the calcined catalyst. The results showed that the calcined catalysts demonstrated different crystalline structures and sulfate More > Graphic Abstract

Yihua Gao¹, Fuping Qian^2,*, Yi Sun², Yue Wu², Shenghua Wu², Jinli Lu¹, Yunlong Han¹, Naijin Huang³

FDMP-Fluid Dynamics & Materials Processing, Vol.19, No.8, pp. 1997-2011, 2023, DOI:10.32604/fdmp.2023.026373 - 04 April 2023

Abstract Selective catalytic reduction (SCR) is a technology by which nitrogen oxides are converted with the aid of a catalyst into diatomic nitrogen and water. It is known that the catalyst can be easily eroded if a cement kiln with a high-dust content is considered. To understand this process, numerical simulations have been carried out considering a single catalyst channel in order to study the collision and erosion of fly ash and catalysts at meso scale. Based on a response surface methodology, the effects of five factors on the erosion rate have been studied, namely, the More > Graphic Abstract

Yizhang Wang¹, Zhaoyang Yu¹, Jinbo Hu^1,2,*, Shanshan Chang¹, Yuan Liu¹, Ting Li², Gonggang Liu^1,*, Xiaodong (Alice) Wang³

Journal of Renewable Materials, Vol.11, No.1, pp. 147-165, 2023, DOI:10.32604/jrm.2023.021306 - 10 August 2022

Abstract In this paper, the residue from bamboo factory has been used to design photo-Fenton catalyst, which has the advantages of low cost and magnetic recycling. The photo-Fenton catalytic performance of the biocarbon-based catalyst was excellent and its optimal preparation process was also explored by response surface methodology. First, bamboo-carbon fiber was selected as the photo-Fenton catalyst carrier. Subsequently, the surface of the carbon fiber was modified, with which dopamine, nano-Fe₃O₄ and nano-TiO₂ were successively loaded by hydrothermal method. After examined single factor tests, four factors including dopamine concentration, ferric chloride mass, P25 titanium dioxide mass and… More > Graphic Abstract

Stefanos Tzelepis^*, Kosmas A. Kavadias

Energy Engineering, Vol.119, No.5, pp. 1745-1769, 2022, DOI:10.32604/ee.2022.020984 - 21 July 2022

Abstract

The constant increase in energy demand and related environmental issues have made fuel cells an attractive technology as an alternative to conventional energy technologies. Like any technology, fuel cells face drawbacks that scientific society has been focused on to improve and optimize the overall technology. Thus, the cost is the main inhibitor for this technology due to the significantly high cost of the materials used in catalyst layers. The current discussion mainly focuses on the fundamental electrochemical half-cell reaction of hydrogen oxidation reaction (HOR) and oxygen reduction reaction (ORR) that are taking place in the

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Lujiang Xu, Geliang Xie, Xianjun Zhou, Yucheng Liu, Zhen Fang^*

Journal of Renewable Materials, Vol.10, No.12, pp. 3107-3118, 2022, DOI:10.32604/jrm.2022.020691 - 14 July 2022

Abstract In this paper, CaO/bio-char was synthesized by directly co-pyrolysis of Ca(OH)₂ and rice straw, and used as catalyst to catalytic pyrolysis of soybean oil to produce high quality biofuel. In this co-pyrolysis process, CaO particles has been successfully embedded on the bio-char surface. During the catalytic pyrolysis process, CaO/bio-char showed a good catalytic performance on the deoxygenation of soybean oil. Pyrolysis temperature affected the pyrolysis reactions and pyrolytic products distributions dramatically, higher pyrolysis temperature lead to seriously cracking reactions, lower bio-oil yield and higher gases yield, and lower pyrolysis temperature lead to higher bio-oil yield with More > Graphic Abstract

Sumari Sumari^*, Mega Murti, Aman Santoso, Muhammad Roy Asrori

Journal of Renewable Materials, Vol.10, No.12, pp. 3659-3670, 2022, DOI:10.32604/jrm.2022.022995 - 14 July 2022

Abstract Kapok seed oil is an environmentally friendly biodiesel feedstock. The problem of the best catalyst for transesterification of Kapok seed oil still continues today. The research developed a base-heterogeneous catalyst with the effect of ultrasonic waves during transesterification. So, the study aims: (1) to determine the type of natural zeolite used, (2) to determine the characteristics of the synthesized CaO:BaO/ANZ catalyst, and (3) to determine the effectiveness of the CaO:BaO/ANZ catalyst in the biodiesel production process through sono-transesterification of kapok seed oil. The research stages consisted of: (1) activation of natural zeolite and its characterization,… More > Graphic Abstract