Maha L. Shrestha1, 2,*, Mihail Ionescu1, Xianmei Wan1, Zoran S. Petrović1
Journal of Renewable Materials, Vol.6, No.5, pp. 504-516, 2018, DOI:10.7569/JRM.2017.634187
Abstract Biobased aromatic-aliphatic polyols were previously synthesized from a thermal thiol-ene reaction of propoxylated cardanol with 2-mercaptoethanol (ME) in the presence of azobisisobutyronitrile (AIBN) as a radical initiator. Cardanol used for this purpose was obtained as a dark-brown liquid (Gardner Color Reference ∼18). The photochemical thiol-ene reaction can also be used to prepare aromatic-aliphatic polyols by employing cardanol. Via the photochemical thiol-ene reaction, 2-mercaptoethanol was added successfully to C=C double bond of cardanol, suggesting that phenolic group may not play an inhibitory role in the radical thiol-ene reaction. However, we preferred to alkoxylate the phenolic hydroxyl More >
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