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  • Open Access

    ARTICLE

    Thermosensitive and Wound-Healing Gelatin-Alginate Biopolymer Hydrogels Modified with Humic Acids

    Denis Miroshnichenko1, Vladimir Lebedev2, Katerina Lebedeva2, Аnna Cherkashina2, Sergey Petrushenko3,4,*, Olena Bogoyavlenska1, Аnzhela Olkhovska5, Ihor Hrubnyk6, Liudmyla Maloshtan6, Natalja Klochko7

    Journal of Renewable Materials, Vol.12, No.10, pp. 1691-1713, 2024, DOI:10.32604/jrm.2024.054769 - 23 October 2024

    Abstract The main goal of the article is the creation and study of thermosensitive and wound-healing gelatin-alginate biopolymer hydrogels modified with humic acids. Their rheological properties, swelling and contraction behavior were experimentally investigated, elucidated using Fourier transform infrared spectroscopy and used to achieve the physiological melting point, which is necessary for successful drug delivery. It has been shown that in the gelatin-alginate-humic acid biopolymer hydrogels systems, it is possible to obtain a gel-sol transition temperature close to the physiological temperature of 37°C, which is important for drug delivery in the treatment of wounds. By changing the… More >

  • Open Access

    ARTICLE

    Enhancing the Shelf Life of Edible Musa Acuminate with Biopolymer Coating

    Manivasagam Vishwa Rohini1,#, Sathish Kiruba1, Danniel Santhanaraj1, Prakash Priyanka Nair1, P. Sudhakara2,*, Jujhar Singh3, Balamurugan Rathinam4,*, Vanaraj Ramkumar5,6,#

    Journal of Polymer Materials, Vol.41, No.3, pp. 159-178, 2024, DOI:10.32604/jpm.2024.054801 - 30 September 2024

    Abstract The Cavendish banana, Musa acuminata, is a climacteric fruit that ripens quickly after harvest. Due to their high perishability and susceptibility to disease, bananas have substantial postharvest losses. After harvesting, it is important to extend the bananas’ shelf life. Unique coating gel solutions based on glycerol and ascorbic acid were developed to accomplish this. Chitosan mixed with glacial acetic acid, lactic acid, and sodium alginate were among the gel solutions in these combinations. The goal was to improve banana preservation while maintaining freshness and quality by implementing innovative formulations and techniques. The fruits are hand-dried and… More >

  • Open Access

    ARTICLE

    Color and Gloss Changes of a Lignin-Based Polyurethane Coating under Accelerated Weathering

    Fatemeh Hassani Khorshidi1, Saeed Kazemi Najafi1, Farhood Najafi2,*, Antonio Pizzi3,*, Dick Sandberg4, Rabi Behrooz1

    Journal of Renewable Materials, Vol.12, No.2, pp. 305-323, 2024, DOI:10.32604/jrm.2023.043953 - 11 March 2024

    Abstract The purpose of this research study was to investigate the properties of polyurethane coatings based on lignin nano-particles. For this purpose, the prepared coatings were applied to pine wood surfaces and weathered artificially. Subsequently, color and gloss of the coatings were measured before and after the weathering test. Field emission scanning electron microscopy (FE-SEM) micrographs prepared from the coatings showed that the average size of nano-particles in the polyurethane substrate was approximately 500 nm. Nuclear magnetic resonance (13C-NMR) spectroscopy showed that strong urethane bonds were formed in the nano-lignin-based polyurethane. Differential calorimetric analysis (DSC) test revealed… More > Graphic Abstract

    Color and Gloss Changes of a Lignin-Based Polyurethane Coating under Accelerated Weathering

  • Open Access

    ARTICLE

    Rheological Study on Blend Solutions of Non-mulberry Silk Fibroin and Gelatin Biopolymers

    PRITI1,*, RADHA SACHAN2, ROLI PURWAR3

    Journal of Polymer Materials, Vol.40, No.3-4, pp. 205-214, 2023, DOI:10.32381/JPM.2023.40.3-4.6

    Abstract In current research work, we have studied the blending effect of non-mulberry silk fibroin (10% weight/volume basis) and gelatin (20% weight/volume basis) in formic acid. Several blends as SF10G0, SF2G8, SF3G7, SF5G5 and SF0G10 have been made and their rheological behaviour was investigated. The blend solutions were subjected to a steady shear rheological study in the variety of range of shear rates, namely 0.01–500 sec-1 and the viscosities of blend solutions were noticed to decrease in comparison to pure silk solution. The frequency sweep was employed in dynamic rheological tests to determine complex viscosity of More >

  • Open Access

    ARTICLE

    Bioactivity of Nanohybrid: Comprising of Metallosalen Incorporated into Lacunary Polyoxometalate and Encapsulated with Chitosan Biopolymer

    SHIVA ARUNa, VINAY KUMAR SINGHa,#, PRABHA BHARTIYAb, PRADIP KUMAR DUTTAc,*

    Journal of Polymer Materials, Vol.40, No.1-2, pp. 19-31, 2023, DOI:10.32381/JPM.2023.40.1-2.2

    Abstract Biocompatible polymer chitosan has note-worthy applications in biomedical science. Nanohybrids synthesized by using chitosan as an encapsulating unit for polyoxometalates (POMs) and study of its biomedical applications is a fast-emerging field. In this research work, a lacunary polyoxometalate (α-K8SiW11O39) has been synthesized and then alkylsilane has been inserted into its lacunary position. It has been then reacted with 2-hydroxy-1-naphtaldehyde followed by copper metalation and finally encapsulated into chitosan by using the ionotropic gelation technique, in which the chitosan and the POM served as cation and anion, respectively. The bands in UV-Vis spectra at characteristic wavelength indicate… More >

  • Open Access

    ARTICLE

    Cross-Linking of Sago Starch with Furan and Bismaleimide via the Diels-Alder Reaction

    Henky Muljana*, Ivana Hasjem, Merianawati Sinatra, Dicky Joshua Pesireron, Michael Wilbert Puradisastra, Ryan Hartono, Kevin Yovan Hermanto, Tony Handoko

    Journal of Renewable Materials, Vol.11, No.12, pp. 4039-4060, 2023, DOI:10.32604/jrm.2023.031261 - 10 November 2023

    Abstract This research paper describes the synthesis of thermo-reversible cross-linking of sago starch by grafting a furan pendant group (methyl 2-furoate) onto the starch backbone, followed by a Diels-Alder (DA) reaction of the furan functional group with 1,1′-(methylenedi-4,1-phenylene) bismaleimide (BM). The proof of principles was provided by FTIR and 1H-NMR analyses. The relevant FTIR peaks are the carbonyl peak (υ C=O sym) at 1721 cm−1 ; the two peaks appeared after DA cross-linking, i.e., at 1510 cm−1 (corresponding to υ CH=CH BM aromatic rings, stretching vibrations), and at 1173 cm−1 (assigned to cycloadduct (C-O-C, δ DA ring)) while More > Graphic Abstract

    Cross-Linking of Sago Starch with Furan and Bismaleimide via the Diels-Alder Reaction

  • Open Access

    ARTICLE

    Extraction and Characterization of Litopenaeus vannamei’s Shell as Potential Sources of Chitosan Biopolymers

    Che Engku Noramalina Che Engku Chik1, Amyra Suryatie Kamaruzzan1, Ahmad Ideris Abdul Rahim1, Fathurrahman Lananan2,3, Azizah Endut4, Siti Aslamyah5, Nor Azman Kasan1,*

    Journal of Renewable Materials, Vol.11, No.3, pp. 1181-1197, 2023, DOI:10.32604/jrm.2023.022755 - 31 October 2022

    Abstract Chitin is the second most abundant polysaccharide, produced mainly as an industrial waste stream during crustacean processing. Chitin can be derived into chitosan through the deacetylation process. Conversion of shrimp waste into chitosan via the deacetylation process could be considered a practical approach for shell waste remediation. In this study, chitosan’s physicochemical characteristics extracted from two types of Pacific white leg shrimp, L. vannamei’s shell (i.e., rough and smooth), were compared with commercial chitosan. The yield, moisture, ash, solubility, water and fat binding capacity were measured. The degree of deacetylation (DDA) was calculated using FTIR, and… More > Graphic Abstract

    Extraction and Characterization of <i>Litopenaeus vannamei</i>’s Shell as Potential Sources of Chitosan Biopolymers

  • Open Access

    ARTICLE

    Utilization of Bitter Orange Seed as a Novel Pectin Source: Compositional and Rheological Characterization

    Diako Khodaei1, Mohammad Nejatian2,*, Hassan Ahmadi Gavlighi2, Farhad Garavand3,*, Ilaria Cacciotti4

    Journal of Renewable Materials, Vol.10, No.11, pp. 2805-2817, 2022, DOI:10.32604/jrm.2022.021752 - 29 June 2022

    Abstract The seeds from bitter orange, the by-product of juice making units, hold the potential to facilitate novel, easy yet high-quality pectin extraction. To test this hypothesis, orange seed pectin (OSP) was extracted by distilled water and its compositional parameters and rheological behavior were then evaluated. Results showed that galacturonic acid was the major component of OSP (∼425 mg/g) confirming the purity of the extracted pectin, followed by glucose and some minor neutral sugars. The Mw (weight-average molar mass), Rn (number average molar mass), and Rz (z-average molar mass) values for the OSP were 4511.8 kDa,… More > Graphic Abstract

    Utilization of Bitter Orange Seed as a Novel Pectin Source: Compositional and Rheological Characterization

  • Open Access

    REVIEW

    A Literature Review on Sustainability of Bio-Based and Biodegradable Plastics: Challenges and Opportunities

    Taofeeq D. Moshood, Gusman Nawanir, Fatimah Mahmud*, Fazeeda Mohamad, Mohd Hanafiah Ahmad, Airin AbdulGhani

    Energy Engineering, Vol.119, No.4, pp. 1611-1647, 2022, DOI:10.32604/ee.2022.019028 - 23 May 2022

    Abstract This study examines the literature on bio-based and biodegradable plastics published between 2000 and 2021 and provides insights and research suggestions for the future. The study gathers data from the Scopus and ISI Web of Science databases, then picks 1042 publications objectively and analyses their metadata. Furthermore, 144 papers from the Web of Science are analysed to present insights and classifications of the literature based on content analyses, including assessment/evaluation of the sustainability of bio-based and biodegradable Plastics, sustainability of biodegradable Plastics, and factors driving the uptake of biodegradable plastics. The study finds that most… More >

  • Open Access

    ARTICLE

    Study on Performance Regulation and Mechanism of Quicklime and Biopolymer on Hemihydrate Phosphogypsum

    Zaibo Zhou1, Juanhong Liu1,2,3,*, Kun Luo1, Aixiang Wu1,3, Hongjiang Wang1,3

    Journal of Renewable Materials, Vol.10, No.2, pp. 373-384, 2022, DOI:10.32604/jrm.2022.016380 - 30 August 2021

    Abstract In order to reduce the influence of impurities in hemihydrate phosphogypsum(HPG) on the environment and improve the workability of HPG, the effects of the content of quicklime and types of biopolymer (hydroxypropyl methylcellulose, xanthan gum, sodium polyacrylate(PAANa)) on the compressive strength, softening coefficient and ultrasonic velocity of HPG were evaluated. When the content of quicklime was 1.5% and the content of PAANa was 0.2%, HPG had the best mechanical properties and workability, its water retention rate can be increased by 5.8%, and unconfined compressive strength of 3 days increased by 10.3% and 7 days increased More > Graphic Abstract

    Study on Performance Regulation and Mechanism of Quicklime and Biopolymer on Hemihydrate Phosphogypsum

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